Junqi Tian1, Yanqin Li1, Xia Zhou1, Yongbin Yao1, Denghao Wang1, Jianming Dan1, Bin Dai1, Qiang Wang2, Feng Yu1,3
Junqi Tian1, Yanqin Li1, Xia Zhou1, Yongbin Yao1, Denghao Wang1, Jianming Dan1, Bin Dai1, Qiang Wang2, Feng Yu1,3
|  M. Fu, C. Li, P. Lu, L. Qu, M. Zhang, Y. Zhou, M. Yu, Y. Fang, A review on selective catalytic reduction of NOx by supported catalysts at 100-300℃-Catalysts, mechanism, kinetics, Catal. Sci. Technol. 4(2014) 14-25.
 D.A. Pena, B.S. Uphade, P.G. Smirniotis, TiO2-supported metal oxide catalysts for low-temperature selective catalytic reduction of NO with NH3:I. Evaluation and characterization of first row transition metals, J. Catal. 221(2004) 421-431.
 W.S. Kijlstra, D.S. Brands, E.K. Poels, A. Bliek, Mechanism of the selective catalytic reduction of NO by NH3 over MnOx/Al2O3. 1. Adsorption and desorption of the single reaction components, J. Catal. 171(1997) 208-218.
 X. Tang, J. Hao, H. Yi, J. Li, Low-temperatureSCR of NO with NH3 over AC/C supported manganese-based monolithic catalysts, Catal. Today 126(2007) 406-411.
 X. Sun, R.T. Guo, J. Liu, Z.T. Fu, S.W. Liu, W.G. Pan, X. Shi, H. Qin, Z.Y. Wang, X.Y. Liu, The enhanced SCR performance of Mn/TiO2 catalyst by Mo modification:Identification of the promotion mechanism, Int. J. Hydrog. Energy 43(2018) 16038-16048.
 D. Fang, F. He, D. Mei, Z. Zhang, J. Xie, H. Hu, Thermodynamic calculation for the activity and mechanism of Mn/TiO2 catalyst doped transition metals for SCR at low temperature, Catal. Commun. 52(2014) 45-48.
 S. Luo, W. Zhou, A. Xie, F. Wu, C. Yao, X. Li, S. Zuo, T. Liu, Effect of MnO2 polymorphs structure on the selective catalytic reduction of NOx with NH3 over TiO2-Palygorskite, Chem. Eng. J. 286(2016) 291-299.
 M. Cheng, B. Jiang, S. Yao, J. Han, S. Zhao, X. Tang, J. Zhang, T. Wang, Mechanism of NH3-SCR reaction for NOx removal from diesel engine exhaust and hydrothermal stability of Cu-Mn/zeolite catalysts, J. Phys. Chem. C 122(2018) 455-464.
 Q. Yan, S. Chen, L. Qiu, Y. Gao, D. O'Hare, Q. Wang, The synthesis of CuyMnzAl1-zOx mixed oxide as a low-temperature NH3-SCR catalyst with enhanced catalytic performance, Dalton Trans. 47(2018) 2992-3004.
 S.C. Ma, J. Yao, X. Ma, L. Gao, M. Guo, Removal of SO2 and NOx using microwave swing adsorption over activated carbon carried catalyst, Chem. Eng. Technol. 36(2013) 1217-1224.
 S.M. Mousavi, A. Niaei, D. Salari, P.N. Panahi, M. Samandari, Modelling and optimization of Mn/activate carbon nanocatalysts for NO reduction:comparison of RSM and ANN techniques, Environ. Technol. 34(2013) 1377-1384.
 B. Shen, T. Liu, N. Zhao, X. Yang, L. Deng, Iron-dopedMn-Ce/TiO2 catalyst for low temperature selective catalytic reduction of NO with NH3, J. Environ. Sci. 22(2010) 1447-1454.
 L. Qu, C. Li, G. Zeng, M. Zhang, M. Fu, J. Ma, F. Zhan, D. Luo, Support modification for improving the performance of MnOx-CeOy/γ-Al2O3 in selective catalytic reduction of NO by NH3, Chem. Eng. J. 242(2014) 76-85.
 J. Zuo, Z. Chen, F. Wang, Y. Yu, L. Wang, X. Li, Low-temperature selective catalytic reduction of NOx with NH3 over novel Mn-Zr mixed oxide catalysts, Ind. Eng. Chem. Res. 53(2014) 2647-2655.
 X. Yao, T. Kong, L. Chen, S. Ding, F. Yang, L. Dong, Enhanced low-temperature NH3-SCR performance of MnOx/CeO2 catalysts by optimal solvent effect, Appl. Surf. Sci. 420(2017) 407-415.
 K. Zhang, F. Yu, M. Zhu, J. Dan, X. Wang, J. Zhang, B. Dai, Enhanced low temperature NO reduction performance via MnOx-Fe2O3/vermiculite monolithic honeycomb catalysts, Catalysts 8(2018) 100.
 Z. Fan, J.W. Shi, C. Gao, G. Gao, B. Wang, C. Niu, Rationally designed porous MnOx-FeOx nanoneedles for low-temperature selective catalytic reduction of NOx by NH3, ACS Appl. Mater. Inter. 9(2017) 16117-16127.
 F. Cao, J. Xiang, S. Su, P. Wang, L. Sun, S. Hu, S. Lei, The activity and characterization of MnOx-CeO2-ZrO2/γ-Al2O3 catalysts for low temperature selective catalytic reduction of NO with NH3, Chem. Eng. J. 243(2014) 347-354.
 Q. Shen, L. Zhang, N. Sun, H. Wang, L. Zhong, C. He, W. Wei, Y. Sun, Hollow MnOxCeO2 mixed oxides as highly efficient catalysts in NO oxidation, Chem. Eng. J. 322(2017) 46-55.
 G. Qi, R.T. Yang, R. Chang, MnOx-CeO2 mixed oxides prepared by co-precipitation for selective catalytic reduction of NO with NH3 at low temperatures, Appl. Catal., B 51(2004) 93-106.
 F. Gao, X. Tang, H. Yi, S. Zhao, J. Wang, Y. Shi, X. Meng, Novel Co-or Ni-Mn binary oxide catalysts with hydroxyl groups for NH3-SCR of NOx at low temperature, Appl. Surf. Sci. 443(2018) 103-113.
 K.B. Nam, D.W. Kwon, S.C. Hong, DRIFT study on promotion effects of tungstenmodified Mn/Ce/Ti catalysts for the SCR reaction at low-temperature, Appl. Catal. A 542(2017) 55-62.
 C. Wang, F. Yu, M. Zhu, X. Wang, J. Dan, J. Zhang, P. Cao, B. Dai, Microspherical MnO2-CeO2-Al2O3 mixed oxide for monolithic honeycomb catalyst and application in selective catalytic reduction of NOx with NH3 at 50-150℃, Chem. Eng. J. 346(2018) 182-192.
 C. Gennequin, T. Barakat, H. Tidahy, R. Cousin, J.F. Lamonier, A. Aboukaïs, S. Siffert, Use and observation of the hydrotalcite "memory effect" for VOC oxidation, Catal. Today 157(2010) 191-197.
 Y. Zhao, X. Jia, G. Chen, L. Shang, G.I. Waterhouse, L.Z. Wu, C.H. Tung, D. O'Hare, T. Zhang, Ultrafine NiO nanosheets stabilized by TiO2 from monolayer NiTi-LDH precursors:an active water oxidation electrocatalyst, J. Am. Chem. Soc. 138(2016) 6517-6524.
 P. Li, P.P. Huang, F.F. Wei, Y.B. Sun, C.Y. Cao, W.G. Song, Monodispersed Pd clusters generated in situ by their own reductive support for high activity and stability in cross-coupling reactions, J. Mater. Chem. A 2(2014) 12739-12745.
 M. Zhang, F. Yu, J. Li, K. Chen, Y. Yao, P. Li, M. Zhu, Y. Shi, Q. Wang, X. Guo, High CO methanation performance of two-dimensional Ni/MgAl layered double oxide with enhanced oxygen vacancies via flash nanoprecipitation, Catalysts 8(2018) 363.
 C. Li, M. Wei, D.G. Evans, X. Duan, Layered double hydroxide-based nanomaterials as highly efficient catalysts and adsorbents, Small 10(2014) 4469-4486.
 C. Chen, P. Gunawan, X.W. Lou, R. Xu, Silver nanoparticles deposited layered double hydroxide nanoporous coatings with excellent antimicrobial activities, Adv. Funct. Mater. 22(2012) 780-787.
 Q. Song, W. Liu, C.D. Bohn, R.N. Harper, E. Sivaniah, S.A. Scott, J.S. Dennis, A high performance oxygen storage material for chemical looping processes with CO2 capture, Energy Environ. Sci. 6(2013) 288-298.
 F. Song, X. Hu, Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis, Nat. Commun. 5(2014) 4477.
 P. Vialat, C. Mousty, C. Taviot-Gueho, G. Renaudin, H. Martinez, J.C. Dupin, E. Elkaim, F. Leroux, High-performing monometallic cobalt layered double hydroxide supercapacitor with defined local structure, Adv. Funct. Mater. 24(2014) 4831-4842.
 O. Pavel, R. Bîrjega, M. Che, G. Costentin, E. Angelescu, S. Şerban, The activity of Mg/Al reconstructed hydrotalcites by "memory effect" in the cyanoethylation reaction, Catal. Commun. 9(2008) 1974-1978.
 P. Li, Y. Yu, P.P. Huang, H. Liu, C.Y. Cao, W.-G. Song, Core-shell structured MgAlLDO@Al-MS hexagonal nanocomposite:an all inorganic acid-base bifunctional nanoreactor for one-pot cascade reactions, J. Mater. Chem. A 2(2014) 339-344.
 Y. Li, Y. Li, P. Wang, W. Hu, S. Zhang, Q. Shi, S. Zhan, Low-temperature selective catalytic reduction of NOx with NH3 over MnFeOx nanorods, Chem. Eng. J. 330(2017) 213-222.
 L.J. France, Q. Yang, W. Li, Z. Chen, J. Guang, D. Guo, L. Wang, X. Li, Ceria modified FeMnO x-Enhanced performance and sulphur resistance for low-temperatureSCR of NOx, Appl. Catal., B 206(2017) 203-215.
 L. Qiu, J. Meng, D. Pang, C. Zhang, F. Ouyang, Reaction and characterization of Co and Ce doped Mn/TiO2 catalysts for low-temperatureSCR of NO with NH3, Catal. Lett. 145(2015) 1500-1509.
 Q. Yan, S. Chen, C. Zhang, D. O'Hare, Q. Wang, Synthesis of Cu0.5Mg1.5Mn0.5Al0.5Ox mixed oxide from layered double hydroxide precursor as highly efficient catalyst for low-temperature selective catalytic reduction of NOx with NH3, J. Colloid Interface Sci. 526(2018) 63-74.
 X. Tang, J. Li, L. Sun, J. Hao, Origination of N2O from NO reduction by NH3 over β-MnO2 and α-Mn2O3, Appl. Catal. B 99(2010) 156-162.
 Y. Wu, Y. Lu, C. Song, Z. Ma, S. Xing, Y. Gao, A novel redox-precipitation method for the preparation of α-MnO2 with a high surface Mn4+ concentration and its activity toward complete catalytic oxidation of oxylene, Catal. Today 201(2013) 32-39.
 S.S.R. Putluru, L. Schill, A.D. Jensen, B. Siret, F. Tabaries, R. Fehrmann, Mn/TiO2 and Mn-Fe/TiO2 catalysts synthesized by deposition precipitation-Promising for selective catalytic reduction of NO with NH3 at low temperatures, Appl. Catal., B 165(2015) 628-635.
 Q.L. Chen, R.T. Guo, Q.S. Wang, W.G. Pan, W.H. Wang, N.Z. Yang, C.Z. Lu, S.X. Wang, The catalytic performance of Mn/TiWOx catalyst for selective catalytic reduction of NOx with NH3, Fuel 181(2016) 852-858.
 F. Liu, H. He, Y. Ding, C. Zhang, Effect of manganese substitution on the structure and activity of iron titanate catalyst for the selective catalytic reduction of NO with NH3, Appl. Catal., B 93(2009) 194-204.
 P.R. Ettireddy, N. Ettireddy, T. Boningari, R. Pardemann, P.G. Smirniotis, Investigation of the selective catalytic reduction of nitric oxide with ammonia over Mn/TiO2 catalysts through transient isotopic labeling and in situ FT-IR studies, J. Catal. 292(2012) 53-63.
 L. Chen, J. Li, M. Ge, The poisoning effect of alkali metals doping over nano V2O5-WO3/TiO2 catalysts on selective catalytic reduction of NOx by NH3, Chem. Eng. J. 170(2011) 531-537.
 Q. Li, H. Yang, F. Qiu, X. Zhang, Promotional effects of carbon nanotubes on V2O5/TiO2 for NOx removal, J. Hazard. Mater. 192(2011) 915-921.
 W. Mu, J. Zhu, S. Zhang, Y. Guo, L. Su, X. Li, Z. Li, Novel proposition on mechanism aspects over Fe-Mn/ZSM-5 catalyst for NH3-SCR of NOx at low temperature:Rate and direction of multifunctional electron-transfer-bridge and in situ DRIFTs analysis, Catal. Sci. Technol. 6(2016) 7532-7548.
 P.G. Smirniotis, D.A. Peña, B.S. Uphade, Low-temperature selective catalytic reduction (SCR) of NO with NH3 by using Mn, Cr, and cu oxides supported on hombikat TiO2, Angew. Chem. Int. Ed. 40(2001) 2479-2482.
 Z. Chen, F. Wang, H. Li, Q. Yang, L. Wang, X. Li, Low-temperature selective catalytic reduction of NOx with NH3 over Fe-Mn mixed-oxide catalysts containing Fe3Mn3O8 phase, Ind. Eng. Chem. Res. 51(2011) 202-212.
 D. Meng, W. Zhan, Y. Guo, Y. Guo, L. Wang, G. Lu, A highly effective catalyst of SmMnOx for the NH3-SCR of NOx at low temperature:promotional role of Sm and its catalytic performance, ACS Catal. 5(2015) 5973-5983.
 Z. Qin, J. Ren, M. Miao, Z. Li, J. Lin, K. Xie, The catalytic methanation of coke oven gas over Ni-Ce/Al2O3 catalysts prepared by microwave heating:Effect of amorphous NiO formation, Appl. Catal., B 164(2015) 18-30.
 X. Yao, Q. Yu, Z. Ji, Y. Lv, Y. Cao, C. Tang, F. Gao, L. Dong, Y. Chen, A comparative study of different doped metal cations on the reduction, adsorption and activity of CuO/Ce0.67M0.33O2(M=Zr4+, Sn4+, Ti4+) catalysts for NO+ CO reaction, Appl. Catal., B 130(2013) 293-304.
 Y. Sun, S. Gao, F. Lei, C. Xiao, Y. Xie, Ultrathin two-dimensional inorganic materials:New opportunities for solid state nanochemistry, Accounts Chem. Res. 48(2014) 3-12.
 H. Li, J. Wu, Z. Yin, H. Zhang, Preparation and applications of mechanically exfoliated single-layer and multilayer MoS2 and WSe2 nanosheets, Accounts Chem. Res. 47(2014) 1067-1075.
 F. Kapteijn, A.D. Vanlangeveld, J.A. Moulijn, A. Andreini, M.A. Vuurman, A.M. Turek, J. M. Jehng, I.E. Wachs, Alumina-supported manganese oxide catalysts:I. Characterization:Effect of precursor and loading, J. Catal. 150(1994) 94-104.
 S.S. Kim, S.C. Hong, Improving the activity of Mn/TiO2 catalysts through control of the pH and valence state of Mn during their preparation, J. Air Waste Manage. Assoc. 62(2012) 362-369.
 D. Yuan, X. Li, Q. Zhao, J. Zhao, M. Tadé, S. Liu, A novel CuTi-containing catalyst derived from hydrotalcite-like compounds for selective catalytic reduction of NO with C3H6 under lean-burn conditions, J. Catal. 309(2014) 268-279.
 D. Yuan, X. Li, Q. Zhao, J. Zhao, S. Liu, M. Tadé, Effect of surface Lewis acidity on selective catalytic reduction of NO by C3H6 over calcined hydrotalcite, Appl. Catal. A 451(2013) 176-183.
 J. Zhu, F. Gao, L. Dong, W. Yu, L. Qi, Z. Wang, L. Dong, Y. Chen, Studies on surface structure of M xOy/MoO3/CeO2 system (M=Ni, Cu, Fe) and its influence on SCR of NO by NH3, Appl. Catal. B, 95(2010) 144-152.
 J. Tian, C. Wang, F. Yu, X. Zhou, J. Zhang, S. Yang, J. Dan, P. Cao, B. Dai, Q. Wang, MnCe-Fe-Al mixed oxide nanoparticles via a high shear mixer facilitated coprecipitation method for low temperature selective catalytic reduction of NO with NH3, Appl. Catal. A 586(2019) 117237.
 C.P. Cho, Y.D. Pyo, J.Y. Jang, G.C. Kim, Y.J. Shin, NOx reduction and N2O emissions in a diesel engine exhaust using Fe-zeolite and vanadium based SCR catalysts, Appl. Therm. Eng. 110(2017) 18-24.
 G. Li, B. Wang, Z. Wang, Z. Li, Q. Sun, W.Q. Xu, Y. Li, Reaction mechanism of low-temperature selective catalytic reduction of NOx over Fe-Mn oxides supported on flyash-derived SBA-15 molecular sieves:Structure-activity relationships and in situ DRIFT analysis, J. Phys. Chem. C 122(2018) 20210-20231.
 F. Kapteijn, L. Singoredjo, A. Andreini, J. Moulijn, Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia, Appl. Catal., B 3(1994) 173-189.
 Z. Huang, Z. Zhu, Z. Liu, Combined effect of H2O and SO2 on V2O5/AC catalysts for NO reduction with ammonia at lower temperatures, Appl. Catal., B 39(2002) 361-368.
 J. Tian, K. Zhang, W. Wang, F. Wang, J. Dan, S. Yang, J. Zhang, B. Dai, F. Yu, Enhanced selective catalytic reduction of NO with NH3 via porous micro-spherical aggregates of Mn-Ce-Fe-Ti mixed oxide nanoparticles, Green Energy Environ. 4(2019) 311-321.
 Z. Liu, J. Zhu, J. Li, L. Ma, S.I. Woo, Novel Mn-Ce-Ti mixed-oxide catalyst for the selective catalytic reduction of NOx with NH3, ACS Appl. Mater. Inter. 6(2014) 14500-14508.
 F. Holzer, U. Roland, F.-D. Kopinke, Combination of non-thermal plasma and heterogeneous catalysis for oxidation of volatile organic compounds:Part 1. Accessibility of the intra-particle volume, Appl. Catal., B 38(2002) 163-181.
 B. Shen, X. Zhang, H. Ma, Y. Yao, T. Liu, A comparative study of Mn/CeO2, Mn/ZrO2 and Mn/Ce-ZrO2 for low temperature selective catalytic reduction of NO with NH3 in the presence of SO2 and H2O, J. Environ. Sci. 25(2013) 791-800.
|||Huawang Zhao, Xiaomin Wu, Zhiwei Huang, Ziyi Chen, Guohua Jing. A comparative study of the thermal and hydrothermal aging effect on Cu-SSZ-13 for the selective catalytic reduction of NOx with NH3 [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 68-77.|
|||Pengnan Ma, Jiankang Wang, Hanxiao Meng, Laiquan Lv, Hao Fang, Kefa Cen, Hao Zhou. Influence of coke rate on thermal treatment of waste selective catalytic reduction (SCR) catalyst during iron ore sintering [J]. Chinese Journal of Chemical Engineering, 2022, 42(2): 415-423.|
|||Ben Liu, Nangui Lv, Chan Wang, Hongwei Zhang, Yuanyuan Yue, Jingdong Xu, Xiaotao Bi, Xiaojun Bao. Redistributing Cu species in Cu-SSZ-13 zeolite as NH3-SCR catalyst via a simple ion-exchange [J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 329-341.|
|||Shuai Fan, Huiyuan Cheng, Manman Feng, Xuemei Wu, Zihao Fan, Dongwei Pan, Gaohong He. Catalytic hydrogenation performance of ZIF-8 carbide for electrochemical reduction of carbon dioxide [J]. Chinese Journal of Chemical Engineering, 2021, 39(11): 144-153.|
|||Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen. Research progress in the SO2 resistance of the catalysts for selective catalytic reduction of NOx [J]. Chin.J.Chem.Eng., 2017, 25(12): 1695-1705.|
|||Shuli Bai, Shengtao Jiang, Huanying Li, Yujiang Guan. Carbon nanotubes loaded with vanadium oxide for reduction NO with NH3 at low temperature [J]. , 2015, 23(3): 516-519.|
|||DAI Chengna, LEI Zhigang, WANG Yuli, ZHANG Runduo, CHEN Biaohua. Transfer and Reaction Performances of Selective Catalytic Reduction of N2O with CO over Monolith Catalysts [J]. Chin.J.Chem.Eng., 2013, 21(8): 835-843.|
|||GAO Yan, LUAN Tao, LV Tao, CHENG Kai, XU Hongming. Performance of V2O5-WO3-MoO3/TiO2 Catalyst for Selective Catalytic Reduction of NOx by NH3 [J]. Chin.J.Chem.Eng., 2013, 21(1): 1-7.|
|||LEI Zhigang, LONG Aibin, JIA Meiru, LIU Xueyi. Experimental and Kinetic Study of Selective Catalytic Reduction of NO with NH3 over CuO/Al2O3/Cordierite Catalyst [J]. , 2010, 18(5): 721-729.|