Zhiheng Ren1,2,3, Muhammad Naeem Younis3, Hui Zhao3, Chunshan Li3,4,5, Xiangui Yang1,2, Erqiang Wang6, Gongying Wang1,2
Zhiheng Ren1,2,3, Muhammad Naeem Younis3, Hui Zhao3, Chunshan Li3,4,5, Xiangui Yang1,2, Erqiang Wang6, Gongying Wang1,2
|  J. Goldemberg, Ethanol for a sustainable energy future, Science 315(2007) 808-810.
 M. Balat, H. Balat, Recent trends in global production and utilization of bio-ethanol fuel, Appl. Energy 86(2009) 2273-2282.
 A. Rattanapan, S. Limtong, M. Phisalaphong, Ethanol production by repeated batch and continuous fermentations of blackstrap molasses using immobilized yeast cells on thin-shell silk cocoons, Appl. Energy 88(2011) 4400-4404.
 M. Usman, D. Li, R. Razzap, M. Yaseen, C. Li, S. Zhang, Novel MoP/HY catalyst for the selective conversion of naphthalene to tetralin, J. Ind. Eng. Chem. 23(2015) 21-26.
 M. Yaseen, Y. Lu, C. Shen, C. Li, Dibenzothiophene hydrodesulfurization over Ru promoted alumina based catalysts using in situ generated hydrogen, Energ, Convers. Manage. 52(2011) 1364-1370.
 M. Yaseen, C. Li, Dibenzothiophene hydrodesulfurizaiton using in situ generated hydrogen over Pd promoted alumina-based catalysts, Fuel Process. Technol. 92(2011) 624-630.
 S. Wang, W. Guo, H. Wang, L. Zhu, S. Yin, K. Qiu, Effect of the Cu/SBA-15 catalyst preparation method on methyl acetate hydrogenation for ethanol production, New J. Chem. 38(2014) 2792-2800.
 D.S. Brands, E.K. Poels, A. Bliek, Ester hydrogenolysis over promoted Cu/SiO2 catalysts, Appl. Catal. A, Gen. 184(1999) 279-289.
 Y. Wang, Y. Shen, Y. Zhao, J. Lv, S. Wang, X. Ma, Insight into the balancing effect of active cu species for hydrogenation of carbon-oxygen bonds, ACS Catal. 5(2015) 6200-6208.
 L.R. Zehner, R.W. Lenton, Process for the preparation of ethylene glycol, US Pat., 4112245, 1978.
 F. Poppelsdorf, Process for the preparation of ethylene glycol, EP. Pat., 0060787, 1982.
 S. Tahara, K. Fujii, K. Nishihira, M. Matsuda, K. Mizutare, Process for continuously preparing ethylene glycol, US Pat., 4453026, 1984.
 K. Hirai, T. Uda, Y. Nakamura, Catalyst composition for producing ethylene glycol and process for producing the catalyst composition, US Pat., 4614728, 1986.
 H. Miyazaki, T. Uda, K. Hirai, Y. Nakamura, H. Ikezawa, T. Tsuchie, Process for producing ethylene glycol and/or glycolic acid ester, catalyst composition used therefor, and process for production thereof, US Pat., 4585890, 1986.
 Y. Choia, K. Futagamia, T. Fujitani, J. Nakamura, The role of ZnO in Cu/ZnO methanol synthesis catalysts-Morphology effect or active site model, Appl. Catal. A, Gen. 208(2001) 163-167.
 X. Wang, K. Ma, L. Guo, T. Ye, Q. Cheng, X. Bai, J. Huang, T. Ding, X. Li, Cu/ZnO/SiO2 catalyst synthesized by reduction of ZnO-modified copper phyllosilicate for dimethyl ether steam reforming, Appl. Catal. A, Gen. 540(2017) 37-46.
 Y. Zhao, B. Shan, Y. Wang, J. Zhou, S. Wang, X. Ma, An effective CuZn-SiO2 bimetallic catalyst prepared by hydrolysis precipitation method for the hydrogenation of methyl acetate to ethanol, Ind. Eng. Chem. Res. 57(2018) 4526-4534.
 H. Liu, Z. Huang, H. Kang, X. Li, C. Xia, J. Chen, H. Liu, Efficient bimetallic NiCu-SiO2 catalysts for selective hydrogenolysis of xylitol to ethylene glycol and propylene glycol, Appl. Catal. B 220(2018) 251-263.
 C. Ye, C. Guo, J. Zhang, Highly active and stable CeO2-SiO2 supported Cu catalysts for the hydrogenation of methyl acetate to ethanol, Fuel Processing Technol. 143(2016) 219-224.
 Li H., Zhang Y., Zhang H., Qin X., Xu Y., Wu R., Jiang Z., Zhao Y. The nature of the deactivation of hydrothermally stable Ni/SiO2-Al2O3 catalyst in long-time aqueous phase hydrogenation of crude 1,4-butanediol, Chin.J.Chem.Eng, 27(12)(2019)2960-2967.
 Z. He, H. Lin, P. He, Y. Yuan, Effect of boric oxide doping on the stability and activity of a Cu-SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol, J. Catal. 277(2011) 54-63.
 X. Zheng, H. Lin, J. Zheng, X. Duan, Y. Yuan, Lanthanum oxide-modified Cu/SiO2 as a high-performance catalyst for chemoselective hydrogenation of dimethyl oxalate to ethylene glycol, ACS Catal. 3(2013) 2738-2749.
 Y. Huang, H. Ariga, X. Zheng, X. Duan, S. Takakusagi, K. Asakura, Y. Yuan, Silvermodulated SiO2-supported copper catalysts for selective hydrogenation of dimethyl oxalate to ethylene glycol, J. Catal. 307(2013) 74-83.
 Y. Wang, X. Duan, J. Zheng, H. Lin, Y. Yuan, H. Ariga, S. Takakusagi, K. Asakura, Remarkable enhancement of Cu catalyst activity in hydrogenation of dimethyl oxalate to ethylene glycol using gold, Catal. Sci. Technol. 2(2012) 1637-1639.
 M. Yaseen, H.U. Rashid, S. Subhan, A.U. Rahman, M. Sahibzada, Z. Tong, Boosting the hydrodesulfurization of dibenzothiophene efficiency of Mn decorated (Co/Ni)-Mo/Al2O3 catalysts at mild temperature and pressure by coupling with phosphonium based ionic liquids, Chem. Eng. J. 375(2019) 121957-121968.
 F. Dai, M. Yaseen, X. Gong, C. Li, Z. Li, S. Zhang, Low-temperature and low-pressure fuel hydrodesulfurization by solid catalyst coupling with ionic liquids, Fuel 134(2014) 74-80.
 M. Yaseen, M. Shakirullah, I. Ahmad, A.U. Rahman, F.U. Rahman, M. Usman, R. Razzaq, Simultaneous operation of dibenzothiophene hydrodesulfurization and methanol reforming reactions over Pd promoted alumina based catalysts, J. Fuel Chem. Technol. 40(2012) 714-720.
 M. Yaseen, A.U. Rahman, H.U. Rahid, M. Sahibzada, S. Subhan, Z. Tong, Hydrodesulfurizaiton of dibenzothiophene using Pd-promoted Co-Mo/Al2O3 and Ni-Mo/Al2O3 catalysts coupled with ionic liquids at ambient operating conditions, RSC Adv. 9(2019) 10371-10385.
 J. Zhou, L. Guo, X. Guo, J. Mao, S. Zhang, Selective hydrogenolysis of glycerol to propanediols on supported Cu-containing bimetallic catalysts, Green Chem. 12(2010) 1835-1843.
 L. Zhang, J. Mao, S. Li, J. Yin, X. Sun, X. Guo, C. Song, J. Zhou, Hydrogenation of levulinic acid into gamma-valerolactone over in situ reduced CuAg bimetallic catalyst:Strategy and mechanism of preventing Cu leaching, Appl. Catal. B 232(2018) 1-10.
 Z. Wang, Z. Xu, S. Peng, M. Zhang, G. Lu, Q. Chen, Y. Chen, G. Guo, High-performance and long-lived cu/SiO2 Nanocatalyst for CO2 hydrogenation, ACS Catal. 5(2015) 4255-4259.
 Z. Wang, Z. Xu, M. Zhang, Q. Chen, Y. Chen, G. Guo, Insight into composition evolution in the synthesis of high-performance Cu/SiO2 catalysts for CO2 hydrogenation, RSC Adv. 6(2016) 25185-25190.
 T. Toupance, M. Kermarec, J.F. Lambert, C. Louis, Conditions of formation of copper phyllosilicates in silica-supported copper catalysts prepared by selective adsorption, J. Phys. Chem. B 106(2002) 2277-2286.
 J.J.F. Scholten, J.A. Konvalinka, F.W. Beekman, Reaction of nitrous oxide and oxygen with silver surfaces and application to the determination of free-silver surface areas of catalysts, J. Catal. 28(1973) 209-220.
 L. Chen, P. Guo, M. Qiao, Y. Run, H. Li, W. Shen, H. Xu, K. Fan, Cu/SiO2 catalysts prepared by the ammonia-evaporation method:Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol, J. Catal. 257(2008) 172-180.
 X. Dong, X. Ma, H. Xu, Q. Ge, Comparative study of silica-supported copper catalysts prepared by different methods:Formation and transition of copper phyllosilicate, Catal. Sci. Technol. 6(2016) 4151-4158.
 Y. Zhao, S. Li, Y. Wang, B. Shan, J. Zhang, S. Wang, X. Ma, Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol, Chem. Eng. J. 313(2017) 759-768.
 T. Toupance, M. Kermarec, C. Louis, Metal particle size in silica-supported copper catalysts:Influence of the conditions of preparation and of thermal pretreatments, J. Phys. Chem. B 104(2000) 965-972.
 C.J.G. Van Der Grift, A.F.H. Wielers, B.P.J. Jogh, J. Van Beumun, M. De Boer, M. Versluijs-Helder, J.W. Geus, Effect of the reduction treatment on the structure and reactivity of silica-supported copper particles, J. Catal. 131(1991) 178-189.
 A.J. Marchi, J.L.G. Fierro, J. Santamaría, A. Monzon, Dehydrogenation of isopropylic alcohol on a Cu/SiO2 catalyst:a study of the activity evolution and reactivation of the catalyst, Appl. Catal. A 142(1996) 375-386.
 C.J.G. Van Der Grift, A. Wielere, A. Mulder, J.W. Geus, The reduction behavior of silica-supported copper catalysts prepared by deposition precipitation, Thermochim. Acta 171(1990) 95-113.
 X. Xi, S. Ma, J. Chen, Y. Zhang, Promotional effects of Ce, Mn and Fe oxides on CuO/SiO2 catalysts for CO oxidation, J. Environ. Chem. Eng. 2(2014) 1011-1017.
 X. Dong, H. Hang, G. In, Y. Yuan, K.R. Tsai, Highly active CNT-promotedCu-ZnO-Al2O3 catalyst for methanol synthesis from H2/CO/CO2, Catal. Lett. 85(2003) 237-246.
 J. Gong, H. Yue, Y. Zhao, S. Zhao, L. Zhao, J. Lv, S. Wang, X. Ma, Synthesis of ethanol via syngas on Cu/SiO2 catalysts with balanced Cu0-Cu+ sites, J. Am. Chem. Soc. 134(2012) 13922-13925.
 F. Rochet, G. Dufour, H. Roulet, N. Motta, A. Sgarlata, M.N. Piancastelli, M.D. Crescenzi, Copper phthalocyanine on Si(111)-7×7 and Si(001)-2×1:an XPS/AES and STM study, Surf. Sci. 319(1994) 10-20.
 H. Liu, Z. Huang, Z. Han, K. Ding, H. Liu, C. Xia, J. Chen, Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts, Green Chem. 17(2015) 4281-4290.
 J. Ding, T. Popa, J. Tang, A.M. Khaled, M. Gasem, Q. Zhong Fan, Highly selective and stable Cu/SiO2 catalysts prepared with a green method for hydrogenation of diethyl oxalate into ethylene glycol, Appl. Catal. B 209(2017) 530-542.
 M.G. Méndezmedrano, E. Kowalska, A. Lehoux, A. Herissan, B. Ohtani, D. Bahena, V. Briois, C. Colbeaujustin, J.L. Rodríguezlópez, H. Remita, Surface modification of TiO2 with Ag nanoparticles and CuO nanoclusters for application in photocatalysis, J. Phys. Chem. C 120(2016) 5143-5154.
 Y. Liu, J. Ding, J. Yang, J. Bi, K. Liu, J. Chen, Stabilization of copper catalysts for hydrogenation of dimethyl oxalate by deposition of Ag clusters on Cu nanoparticles, Catal. Commun. 98(2017) 43-46.
 H. Zhou, W. Zhu, L. Shi, H. Liu, S. Liu, Y. Ni, Y. Liu, Y. He, S. Xu, L. Li, Z. Liu, In situ DRIFT study of dimethyl ether carbonylation to methyl acetate on H-Mordenite, J. Mol. Catal. A 417(2016) 1-9.
 E. Kukulska-Zajac, K. Gora-Marek, J. Datka, IR and TPD studies of the reaction of acetic acid in zeolites NaHY, Micropor. Mesopor. Mat. 96(2006) 216-221.
 C. Wen, Y. Cui, W. Dai, S. Xie, K. Fan, Solvent feedstock effect:the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol, Chem. Commun. 49(2013) 5195-5197.
 H. Chen, J. Tan, J. Cui, X. Yang, H. Zheng, Y. Zhu, Y. Li, Promoting effect of boron oxide on Ag/SiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate, Molecular Catalysis 433(2017) 346-353.
|||Zewen Chen, Yongjun Wu, Jian Wang, Peicheng Luo. Study on the solid–liquid suspension behavior in a tank stirred by the long-short blades impeller [J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 79-88.|
|||Jiandong Zhang, Rui Dong, Xiaoxiao Yang, Lili Gao, Chaofeng Zhang, Fan Ren, Jing Li, Honghong Chang. Characterization of four diol dehydrogenases for enantioselective synthesis of chiral vicinal diols [J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 145-154.|
|||Junru Liu, Rui Hu, Xinlei Liu, Qunfeng Zhang, Guanghua Ye, Zhijun Sui, Xinggui Zhou. Modeling of propane dehydrogenation combined with chemical looping combustion of hydrogen in a fixed bed reactor [J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 165-173.|
|||Hualiang An, Rui Wang, Wenhao Wang, Daolai Sun, Xinqiang Zhao, Yanji Wang. A core–shell Ni/SiO2@TiO2 catalyst for highly selective one-step synthesis of 2-propylheptanol from n-pentanal [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 104-112.|
|||Siyue Ren, Xiao Feng. Emergy evaluation of aromatics production from methanol and naphtha [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 134-141.|
|||Xiangjun Li, Shujun Li, Xiaoping Wang, Muhammad Asif Nawaz, Dianhua Liu. Polyoxymethylene dimethyl ethers synthesis from methanol and formaldehyde solution over one-pot synthesized spherical mesoporous sulfated zirconia [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 161-172.|
|||Qunhong Liu, Jiangtao Yang, Hongwei Zhang, Hongming Sun, Shuzheng Wu, Bingqing Ge, Rong Wang, Pei Yuan. Tuning the properties of Ni-based catalyst via La incorporation for efficient hydrogenation of petroleum resin [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 41-50.|
|||Lijuan He, Cuimei Zhi, Lixia Ling, Riguang Zhang, Baojun Wang. Syngas to ethanol on MoCu(2 1 1) surface: Effect of promoter Mo on C—O bond breaking and C—C bond formation [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 78-89.|
|||Ning Liu, Xingping Liu, Fumin Wang, Feng Xin, Mingshuai Sun, Yi Zhai, Xubin Zhang. CFD simulation study of the effect of baffles on the fluidized bed for hydrogenation of silicon tetrachloride [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 219-228.|
|||Yue Liang, Wenjuan Wang, Yan Sun, Xiaoyan Dong. Insights into the cross-amyloid aggregation of Aβ40 and its N-terminal truncated peptide Aβ11-40 affected by epigallocatechin gallate [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 284-293.|
|||Chunhua Zhang, Zhengyan Qu, Hong Jiang, Rizhi Chen, Weihong Xing. Nb2O5 promoted Pd/AC catalyst for selective phenol hydrogenation to cyclohexanone [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 87-93.|
|||Danlong Li, Yannan Liang, Hainan Wang, Ruoqian Zhou, Xiaokang Yan, Lijun Wang, Haijun Zhang. Investigation on the effects of fluid intensification based preconditioning process on the decarburization enhancement of fly ash [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 275-283.|
|||Mingxia Tian, Aili Wang, Hengbo Yin. Evolution of copper nanowires through coalescing of copper nanoparticles induced by aliphatic amines and their electrical conductivities in polyester films [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 284-291.|
|||N. M'hanni, T. Anik, R. Touir, M. Galai, M. Ebn Touhami, E.H. Rifi, Z. Asfari, S. Bakkali. Effect of additives on nickel-phosphorus deposition obtained by electroless plating: Characterization and corrosion resistance in 3%(mass) sodium chloride medium [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 341-350.|
|||Ling Xu, Ji Li, Wenbin Zeng, Kai Liu, Yibing Ma, Liping Fang, Chenlu Shi. Surfactant-assisted removal of 2,4-dichlorophenol from soil by zero-valent Fe/Cu activated persulfate [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 447-455.|