Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

doi:10.1016/j.cjche.2024.04.008

Chinese Journal of Chemical Engineering ›› 2024, Vol. 71 ›› Issue (7): 203-216.DOI: 10.1016/j.cjche.2024.04.008

Previous Articles Next Articles

Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

Bingning Wang^1,2, Xianzhe Wang³, Song Yang^2,3, Chao Yang⁴, Huiling Fan¹, Ju Shangguan¹

1. State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China;
2. Shanxi Engineering Center of Civil Clean Fuel, Taiyuan University of Technology, Taiyuan 030024, China;
3. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
4. College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received:2023-11-30 Revised:2024-04-12 Online:2024-08-30 Published:2024-07-28
Contact: Song Yang,E-mail:yangsong@tyut.edu.cn;Ju Shangguan,E-mail:shangguanju@tyut.edu.cn
Supported by:
This work was supported by Fundamental Research Program of Shanxi Province, China (202203021212245), the Science and Technology Achievement Transformation Guidance Special Program of Shanxi Province, China (202104021301052) and the Patent Transformation Program of Shanxi Province, China (202306013).

Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

Bingning Wang^1,2, Xianzhe Wang³, Song Yang^2,3, Chao Yang⁴, Huiling Fan¹, Ju Shangguan¹

1. State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China;
2. Shanxi Engineering Center of Civil Clean Fuel, Taiyuan University of Technology, Taiyuan 030024, China;
3. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
4. College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

通讯作者: Song Yang,E-mail:yangsong@tyut.edu.cn;Ju Shangguan,E-mail:shangguanju@tyut.edu.cn
基金资助:
This work was supported by Fundamental Research Program of Shanxi Province, China (202203021212245), the Science and Technology Achievement Transformation Guidance Special Program of Shanxi Province, China (202104021301052) and the Patent Transformation Program of Shanxi Province, China (202306013).

Abstract

Abstract: The removal of organic sulfur through catalytic hydrolysis is a significant area of research in the field of desulfurization. This review provides an overview of recent advancements in catalytic hydrolysis technology of organic sulfur, including the activity, stability, and atmosphere effects of hydrolysis catalysts. The emphasis is on strategies for enhancing hydrolysis activity and anti-oxygen poisoning property of catalysts. Surface modification, metal doping and nitrogen doping have been found to improve the activity of catalysts. Alkaline components modification is the most commonly used method, the formation of oxygen vacancies through metal doping and creation of nitrogen basic sites through nitrogen doping also contribute to the hydrolysis of organic sulfur. The strategies for anti-oxygen poisoning are discussed in a systematic manner. The structural regulation of catalysts is beneficial for the desorption and diffusion of hydrogen sulfide (H₂S), thereby effectively inhibiting its oxidation. Nitrogen doping and the addition of electronic promoters such as transition metals can protect active sites and decrease the number of active oxygen species. These methods have been proven to enhance the anti-poisoning performance of catalysts. Additionally, this article summarizes how different atmospheres affect the activity of hydrolysis catalysts. The objective of this review is to pave the way for the development of efficient, stable and widely used catalysts for organic sulfur hydrolysis.

Key words: Organic sulfur, Hydrolysis, Catalysts, Activity, Stability

摘要： The removal of organic sulfur through catalytic hydrolysis is a significant area of research in the field of desulfurization. This review provides an overview of recent advancements in catalytic hydrolysis technology of organic sulfur, including the activity, stability, and atmosphere effects of hydrolysis catalysts. The emphasis is on strategies for enhancing hydrolysis activity and anti-oxygen poisoning property of catalysts. Surface modification, metal doping and nitrogen doping have been found to improve the activity of catalysts. Alkaline components modification is the most commonly used method, the formation of oxygen vacancies through metal doping and creation of nitrogen basic sites through nitrogen doping also contribute to the hydrolysis of organic sulfur. The strategies for anti-oxygen poisoning are discussed in a systematic manner. The structural regulation of catalysts is beneficial for the desorption and diffusion of hydrogen sulfide (H₂S), thereby effectively inhibiting its oxidation. Nitrogen doping and the addition of electronic promoters such as transition metals can protect active sites and decrease the number of active oxygen species. These methods have been proven to enhance the anti-poisoning performance of catalysts. Additionally, this article summarizes how different atmospheres affect the activity of hydrolysis catalysts. The objective of this review is to pave the way for the development of efficient, stable and widely used catalysts for organic sulfur hydrolysis.

关键词: Organic sulfur, Hydrolysis, Catalysts, Activity, Stability

Bingning Wang, Xianzhe Wang, Song Yang, Chao Yang, Huiling Fan, Ju Shangguan. Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability[J]. Chinese Journal of Chemical Engineering, 2024, 71(7): 203-216.

References

[1] C. Yang, Y.S. Wang, H.L. Fan, G. de Falco, S. Yang, J. Shangguan, T.J. Bandosz, Bifunctional ZnO-MgO/activated carbon adsorbents boost H₂S room temperature adsorption and catalytic oxidation, Appl. Catal. B Environ. 266 (2020) 118674.
[2] Y.S. Wang, C. Yang, C.N. Zhang, M.X. Duan, H. Wang, H.L. Fan, Y.K. Li, J. Shangguan, J.Y. Lin, Effect of hierarchical porous MOF-199 regulated by PVP on their ambient desulfurization performance, Fuel 319 (2022) 123845.
[3] C. Yang, S. Yang, H.L. Fan, Y.S. Wang, J. Shangguan, Tuning the ZnO-activated carbon interaction through nitrogen modification for enhancing the H₂S removal capacity, J. Colloid Interface Sci. 555 (2019) 548-557.
[4] V.R.R. Pendyala, G. Jacobs, W.P. Ma, W.D. Shafer, D.E. Sparks, A. MacLennan, Y.F. Hu, B.H. Davis, Fischer-Tropsch synthesis: Effect of carbonyl sulfide poison over a Pt promoted Co/alumina catalyst, Catal. Today 299 (2018) 14-19.
[5] X.Z. Wang, L. Ding, Z.B. Zhao, W.Y. Xu, B. Meng, J.S. Qiu, Novel hydrodesulfurization nano-catalysts derived from Co₃O₄ nanocrystals with different shapes, Catal. Today 175 (1) (2011) 509-514.
[6] R. Rivera-Tinoco, C. Bouallou, Reaction kinetics of carbonyl sulfide (COS) with diethanolamine in methanolic solutions, Ind. Eng. Chem. Res. 47 (19) (2008) 7375-7380.
[7] J. Kim, J.Y. Do, K. Nahm, N.K. Park, J. Chi, J.P. Hong, M. Kang, Capturing ability for COS gas by a strong bridge bonding of a pair of potassium anchored on carbonate of activated carbon at low temperatures, Sep. Purif. Technol. 211 (2019) 421-429.
[8] J.Y. Lin, H.X. Guo, K.C. Xie, Studies on deactivation of carbonyl sulfide hydrolysis catalyst. J. Ningxia Univ., Nat. Sci. Ed., 22 (2) (2001) 192-194.
[9] Y.F. Wang, L. Ding, H.M. Long, J.J. Xiao, L.X. Qian, H.T. Wang, C.C. Xu, Carbonyl sulfur removal from blast furnace gas: Recent progress, application status and future development, Chemosphere 307 (Pt 4) (2022) 136090.
[10] P.F. Li, G.C. Wang, Y. Dong, Y.Q. Zhuo, Y.M. Fan, A review on desulfurization technologies of blast furnace gases, Curr. Pollut. Rep. 8 (2) (2022) 189-200.
[11] C. Rhodes, S.A. Riddel, J. West, B.P. Williams, G.J. Hutchings, The low-temperature hydrolysis of carbonyl sulfide and carbon disulfide: a review, Catal. Today 59 (3-4) (2000) 443-464.
[12] S.Z. Zhao, H.H. Yi, X.L. Tang, S.X. Jiang, F.Y. Gao, B.W. Zhang, Y.R. Zuo, Z.X. Wang, The hydrolysis of carbonyl sulfide at low temperature: a review, Sci. World J. 2013 (2013) 739501.
[13] S. Renda, D. Barba, V. Palma, Recent solutions for efficient carbonyl sulfide hydrolysis: a review, Ind. Eng. Chem. Res. 61 (17) (2022) 5685-5697.
[14] Y.R. Lou, J. Shangguan, R.Z. Zhao, J. Song, Research progress in atmosphere effects on and kinetics for carbonyl sulfide catalytic hydrolysis, Ind. Catal. 18 (5) (2010) 1-5.
[15] S. Tong, I.G. Dalla Lana, K.T. Chuang, Appraisal of catalysts for the hydrolysis of carbon disulfide, Can. J. Chem. Eng. 70 (3) (1992) 516-522.
[16] Y.H. Yue, X.P. Zhao, W.M. Hua, Z. Gao, Nanosized titania and zirconia as catalysts for hydrolysis of carbon disulfide, Appl. Catal. B Environ. 46 (3) (2003) 561-572.
[17] J. Bachelier, A. Aboulayt, J.C. Lavalley, O. Legendre, F. Luck, Activity of different metal oxides towards COS hydrolysis. Effect of SO₂ and sulfation, Catal. Today 17 (1-2) (1993) 55-62.
[18] K. Miura, K. Mae, T. Inoue, T. Yoshimi, H. Nakagawa, K. Hashimoto, Simultaneous removal of carbonyl sulfide and hydrogen sulfide from coke oven gas at low temperature by iron oxide, Ind. Eng. Chem. Res. 31 (1) (1992) 415-419.
[19] Z.H. Gao, L.H. Yin, C.H. Li, K.C. Xie. Study on simultaneous removal of COS and H₂S by using α-FeOOH nanoparticle, J. Fuel Chem. Technol., 31 (3) (2003) 249-253.
[20] H.Y. Wang, H.H. Yi, P. Ning, X.L. Tang, L.L. Yu, D. He, S.Z. Zhao, Calcined hydrotalcite-like compounds as catalysts for hydrolysis carbonyl sulfide at low temperature, Chem. Eng. J. 166 (1) (2011) 99-104.
[21] H.H. Yi, S.Z. Zhao, X.L. Tang, P. Ning, H.Y. Wang, D. He, Influence of calcination temperature on the hydrolysis of carbonyl sulfide over hydrotalcite-derived Zn-Ni-Al catalyst, Catal. Commun. 12 (15) (2011) 1492-1495.
[22] H.H. Yi, H.Y. Wang, X.L. Tang, P. Ning, L.L. Yu, D. He, S.Z. Zhao, Effect of calcination temperature on catalytic hydrolysis of COS over CoNiAl catalysts derived from hydrotalcite precursor, Ind. Eng. Chem. Res. 50 (23) (2011) 13273-13279.
[23] S.Z. Zhao, H.H. Yi, X.L. Tang, C.Y. Song, Low temperature hydrolysis of carbonyl sulfide using Zn-Al hydrotalcite-derived catalysts, Chem. Eng. J. 226 (2013) 161-165.
[24] S.Z. Zhao, H.H. Yi, X.L. Tang, D.J. Kang, F.Y. Gao, J.G. Wang, Y.H. Huang, Z.Y. Yang, Removal of volatile odorous organic compounds over NiAl mixed oxides at low temperature, J. Hazard. Mater. 344 (2018) 797-810.
[25] S.Z. Zhao, H.H. Yi, X.L. Tang, F.Y. Gao, Q.J. Yu, Y.S. Zhou, J.G. Wang, Y.H. Huang, Z.Y. Yang, Enhancement effects of ultrasound assisted in the synthesis of NiAl hydrotalcite for carbonyl sulfide removal, Ultrason. Sonochem. 32 (2016) 336-342.
[26] S.Z. Zhao, H.H. Yi, X.L. Tang, D.J. Kang, Q.J. Yu, F.Y. Gao, J.G. Wang, Y.H. Huang, Z.Y. Yang, Mechanism of activity enhancement of the Ni based hydrotalcite-derived materials in carbonyl sulfide removal, Mater. Chem. Phys. 205 (2018) 35-43.
[27] S.Z. Zhao, H.H. Yi, X.L. Tang, D.J. Kang, H.Y. Wang, K. Li, K.J. Duan, Characterization of Zn-Ni-Fe hydrotalcite-derived oxides and their application in the hydrolysis of carbonyl sulfide, Appl. Clay Sci. 56 (2012) 84-89.
[28] S.Z. Zhao, H.H. Yi, X.L. Tang, F.Y. Gao, Q.J. Yu, J.G. Wang, Y.H. Huang, Z.Y. Yang, The regulatory effect of Al atomic-scale doping in NiAlO for COS removal, Catal. Today 355 (2020) 415-421.
[29] K. Li, H.T. Ruan, P. Ning, C. Wang, X. Sun, X. Song, S. Han, Preparation of walnut shell-based activated carbon and its properties for simultaneous removal of H₂S, COS and CS₂ from yellow phosphorus tail gas at low temperature, Res. Chem. Intermed. 44 (2) (2018) 1209-1233.
[30] X. Song, K. Li, P. Ning, C. Wang, X. Sun, L.H. Tang, H.T. Ruan, S. Han, Surface characterization studies of walnut-shell biochar catalysts for simultaneously removing of organic sulfur from yellow phosphorus tail gas, Appl. Surf. Sci. 425 (2017) 130-140.
[31] R. Fiedorow, R. Leaute, I.G.D. Lana, A study of the kinetics and mechanism of COS hydrolysis over alumina, J. Catal. 85 (2) (1984) 339-348.
[32] A. Aboulayt, F. Mauge, P.E. Hoggan, J.C. Lavalley, Combined FTIR, reactivity and quantum chemistry investigation of COS hydrolysis at metal oxide surfaces used to compare hydroxyl group basicity, Catal. Lett. 39 (3) (1996) 213-218.
[33] J. Shangguan, C.H. Li, H.X. Guo, Hydrolysis of carbonyl sulfur and carbon dioxide on aluminum-based catalyst with oxygen ratio Ⅱ. Study on CO₂-TPD on catalyst, J. Nat. Gas Chem. 7 (1) (1998) 24-30.
[34] P.E. Hoggan, A. Aboulayt, A. Pieplu, P. Nortier, J.C. Lavalley, Mechanism of COS hydrolysis on alumina, J. Catal. 149 (2) (1994) 300-306.
[35] Z.M. George, Effect of catalyst basicity for COS-SO₂ and COS hydrolysis reactions, J. Catal. 35 (2) (1974) 218-224.
[36] J. West, B.P. Williams, N. Young, C. Rhodes, G.J. Hutchings, Low temperature hydrolysis of carbonyl sulfide using γ-Alumina catalysts, Catal. Lett., 74 (3-4) (2001) 111-114.
[37] H.M. Huisman, P. Van Der Berg, R. Mos, A.J. Van Dillen, J.W. Geus, ChemInform abstract: hydrolysis of COS on titania catalysts. mechanism and influence of oxygen, ChemInform 25 (32) (1994): 393-404.
[38] A. Vidal-Vidal, M. Perez-Rodriguez, M.M. Pineiro, Computational study of the hydrolysis of carbonyl sulphide: Thermodynamics and kinetic constants estimation using ab initio calculations, J. Chem. Thermodyn. 110 (2017) 154-161.
[39] J.X. Qu, X.Q. Wang, L.L. Wang, B.W. Xu, P. Ning, Y.X. Ma, Y.B. Xie, R. Cao, Q. Ma, The investigation of the role of nitrogen in the improvement of catalytic activity and stability of Zr/Ti-based material for carbon disulfide hydrolysis, Sep. Purif. Technol. 296 (2022) 121357.
[40] L.X. Ling, R.G. Zhang, P.D. Han, B.J. Wang, A theoretical study on the hydrolysis mechanism of carbon disulfide, J. Mol. Model. 18 (4) (2012) 1625-1632.
[41] X. Song, C. Wang, K.A.M. Gasem, K. Li, X. Sun, P. Ning, W.B. Gong, T.T. Wang, M.H. Fan, L.N. Sun, New insight into the reaction mechanism of carbon disulfide hydrolysis and the impact of H₂S with density functional modeling, New J. Chem. 43 (5) (2019) 2347-2352.
[42] E. Laperdrix, I. Justin, G. Costentin, O. Saur, J.C. Lavalley, A. Aboulayt, J.L. Ray, C. Nedez, Comparative study of CS₂ hydrolysis catalyzed by alumina and titania, Appl. Catal. B Environ. 17 (1-2) (1998) 167-173.
[43] X. Song, P. Ning, C. Wang, K. Li, L.H. Tang, X. Sun, Catalytic hydrolysis of COS over CeO₂ (110) surface: a density functional theory study, Appl. Surf. Sci. 414 (2017) 345-352.
[44] S. Han, H. Yang, P. Ning, K. Li, L.H. Tang, C. Wang, X. Sun, X. Song, Density functional theory study on the hydrolysis process of COS and CS₂ on a graphene surface, Res. Chem. Intermed. 44 (4) (2018) 2637-2651.
[45] X. Song, X. Chen, L.N. Sun, K. Li, X. Sun, C. Wang, P. Ning, Synergistic effect of Fe2O₃ and CuO on simultaneous catalytic hydrolysis of COS and CS₂: Experimental and theoretical studies, Chem. Eng. J. 399 (2020) 125764.
[46] B. Peter Williams, N.C. Young, J. West, C. Rhodes, G.J. Hutchings, Carbonyl sulphide hydrolysis using alumina catalysts, Catal. Today 49 (1-3) (1999) 99-104.
[47] D. Chiche, J.M. Schweitzer, Investigation of competitive COS and HCN hydrolysis reactions upon an industrial catalyst: Langmuir-Hinshelwood kinetics modeling, Appl. Catal. B Environ. 205 (2017) 189-200.
[48] S. Tong, I.G. Dalla Lana, K.T. Chuang. Kinetic modelling of the hydrolysis of carbonyl sulfide catalyzed by either titania or alumina, The Canadian J. Chem. Eng., 71 (3) (1993) 392-400.
[49] B. Thomas, B.P. Williams, N. Young, C. Rhodes, G.J. Hutchings, Ambient temperature hydrolysis of carbonyl sulfide using γ-alumina catalysts: effect of calcination temperature and alkali doping, Catal. Lett. 86 (4) (2003) 201-205.
[50] J. West, B. Peter Williams, N. Young, C. Rhodes, G.J. Hutchings, Ni- and Zn-promotion of γ-Al₂O₃ for the hydrolysis of COS under mild conditions, Catal. Commun. 2 (3-4) (2001) 135-138.
[51] H.M. Huang, N. Young, B.P. Williams, S.H. Taylor, G. Hutchings, COS hydrolysis using zinc-promoted alumina catalysts, Catal. Lett. 104 (1) (2005) 17-21.
[52] H.M. Huang, N. Young, B.P. Williams, S.H. Taylor, G. Hutchings, Purification of chemical feedstocks by the removal of aerial carbonyl sulfide by hydrolysis using rare earth promoted alumina catalysts, Green Chem. 10 (5) (2008) 571-577.
[53] J.N. Gu, J.X. Liang, S.J. Hu, Y.X. Xue, X. Min, M.M. Guo, X.F. Hu, J.P. Jia, T.H. Sun, Enhanced removal of COS from blast furnace gas via catalytic hydrolysis over Al₂O₃-based catalysts: Insight into the role of alkali metal hydroxide, Sep. Purif. Technol. 295 (2022) 121356.
[54] J. Shangguan, H.X. Guo, Study on hydrolysis reactivity of carbon disulfide on alumina-based catalyst, J. Fuel Chem. Technol. 25 (3) (1997) 277-283.
[55] K. Nimthuphariyha, A. Usmani, N. Grisdanurak, E. Kanchanatip, M. Yan, S. Suthirakun, S. Tulaphol, Hydrolysis of carbonyl sulfide over modified Al₂O₃ by platinum and barium in a packed-bed reactor, Chem. Eng. Commun., 208 (4) (2019) 539-548.
[56] K. Li, X. Song, G.J. Zhang, C. Wang, P. Ning, X. Sun, L.H. Tang, Low temperature catalytic hydrolysis of carbon disulfide over nano-active carbon based catalysts prepared by liquid phase deposition, RSC Adv. 7 (64) (2017) 40354-40361.
[57] K.L. Li, C. Wang, P. Ning, K. Li, X. Sun, X. Song, Y. Mei, Surface characterization of metal oxides-supported activated carbon fiber catalysts for simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide, J. Environ. Sci. (China) 96 (2020) 44-54.
[58] P. Ning, K. Li, H.H. Yi, X.L. Tang, J.H. Peng, D. He, H.Y. Wang, S.Z. Zhao, Simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide over modified microwave coal-based active carbon catalysts at low temperature, J. Phys. Chem. C 116 (32) (2012) 17055-17062.
[59] H.H. Yi, D. He, X.L. Tang, H.Y. Wang, S.Z. Zhao, K. Li, Effects of preparation conditions for active carbon-based catalyst on catalytic hydrolysis of carbon disulfide, Fuel 97 (2012) 337-343.
[60] X. Song, P. Ning, C. Wang, K. Li, L.H. Tang, X. Sun, H.T. Ruan, Research on the low temperature catalytic hydrolysis of COS and CS₂ over walnut shell biochar modified by Fe-Cu mixed metal oxides and basic functional groups, Chem. Eng. J. 314 (2017) 418-433.
[61] H.H. Han, Z.H. Zhang, Y.L. Zhang, Research on the catalytic hydrolysis of COS by Fe-Cu/AC catalyst and its inactivation mechanism at low temperature, ChemistrySelect 7 (15) (2022) e202200194.
[62] K. Li, X. Song, P. Ning, H.H. Yi, X.L. Tang, C. Wang, Energy utilization of yellow phosphorus tail gas: simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide at low temperature, Energy Technol. 3 (2) (2015) 136-144.
[63] Xin S, H.T. Ruan, S. Xin, L.N. Sun, K. Li, P. Ning, C. Wang, Research into the reaction process and the effect of reaction conditions on the simultaneous removal of H₂S, COS and CS₂ at low temperature, RSC Adv., 8 (13) (2018) 6996-7004.
[64] X. Sun, P. Ning, X.L. Tang, H.H. Yi, K. Li, D. He, X.M. Xu, B. Huang, R.Y. Lai, Simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide over Al₂O₃-K/CAC catalyst at low temperature, J. Energy Chem. 23 (2) (2014) 221-226.
[65] N. Liu, P. Ning, X. Sun, C. Wang, X. Song, F. Wang, K. Li, Simultaneous catalytic hydrolysis of HCN, COS and CS₂ over metal-modified microwave coal-based activated carbon, Sep. Purif. Technol. 259 (2021) 118205.
[66] X. Li, X.Q. Wang, L.L. Wang, P. Ning, Y.X. Ma, L. Zhong, Y. Wu, L. Yuan, Efficient removal of carbonyl sulfur and hydrogen sulfide from blast furnace gas by one-step catalytic process with modified activated carbon, Appl. Surf. Sci. 579 (2022) 152189.
[67] L. Wang, Y. Guo, G.Z. Lu, Effect of activated carbon support on CS₂ removal over coupling catalysts, J. Nat. Gas Chem. 20 (4) (2011) 397-402.
[68] H.H. Yi, K. Li, X.L. Tang, P. Ning, J.H. Peng, C. Wang, D. He, Simultaneous catalytic hydrolysis of low concentration of carbonyl sulfide and carbon disulfide by impregnated microwave activated carbon at low temperatures, Chem. Eng. J. 230 (2013) 220-226.
[69] M.Y. Ma, C.M. Li, Y.J. Li, C. Wang, S.Q. Gao, H.D. Ye, J.J. Li, J. Yu, Resource utilization of spent activated coke as an efficient material for simultaneous removal of COS and H₂S, Energy Fuels 36 (9) (2022) 4837-4846.
[70] P. Wu, Y.P. Zhang, Y.L. Liu, H.Q. Yang, K. Shen, G.B. Li, S. Wang, S.P. Ding, S.L. Zhang, Experimental and theoretical research on pore-modified and K-doped Al₂O₃ catalysts for COS hydrolysis: The role of oxygen vacancies and basicity, Chem. Eng. J. 450 (2022) 138091.
[71] R.H. Sui, C.B. Lavery, D. Li, C.E. Deering, N. Chou, N.I. Dowling, R.A. Marriott, Improving low-temperature CS₂ conversion for the Claus process by using La(III)-doped nanofibrous TiO₂ xerogel, Appl. Catal. B Environ. 241 (2019) 217-226.
[72] S.Z. Zhao, D.J. Kang, Y.P. Liu, Y.F. Wen, X.Z. Xie, H.H. Yi, X.L. Tang, Spontaneous Formation of asymmetric oxygen vacancies in transition-metal-doped CeO₂ nanorods with improved activity for carbonyl sulfide hydrolysis, ACS Catal. 10 (20) (2020) 11739-11750.
[73] G.Y. Mu, Y. Zeng, Y. Zheng, Y.N. Cao, F.J. Liu, S.J. Liang, Y.Y. Zhan, L.L. Jiang, Oxygen vacancy defects engineering on Cu-doped Co₃O₄ for promoting effective COS hydrolysis, Green Energy Environ. 8 (3) (2023) 831-841.
[74] X. Kan, G.Q. Zhang, Y.Y. Luo, F.J. Liu, Y. Zheng, Y.H. Xiao, Y.N. Cao, C.T. Au, S.J. Liang, L.L. Jiang, Efficient catalytic removal of COS and H₂S over graphitized 2D micro-meso-macroporous carbons endowed with ample nitrogen sites synthesized via mechanochemical carbonization, Green Energy Environ. 7 (5) (2022) 983-995.
[75] S.J. Liang, J.X. Mi, F.J. Liu, Y. Zheng, Y.H. Xiao, Y.N. Cao, L.L. Jiang, Efficient catalytic elimination of COS and H₂S by developing ordered mesoporous carbons with versatile base N sites via a calcination induced self-assembly route, Chem. Eng. Sci. 221 (2020) 115714.
[76] H.H. Yi, S.Z. Zhao, X.L. Tang, C.Y. Song, F.Y. Gao, B.W. Zhang, Z.X. Wang, Y.R. Zuo, Low-temperature hydrolysis of carbon disulfide using the FeCu/AC catalyst modified by non-thermal plasma, Fuel 128 (2014) 268-273.
[77] K. Li, G. Liu, T.Y. Gao, F. Lu, L.H. Tang, S.J. Liu, P. Ning, Surface modification of Fe/MCSAC catalysts with coaxial cylinder dielectric barrier discharge plasma for low-temperature catalytic hydrolysis of CS₂, Appl. Catal. A Gen. 527 (2016) 171-181.
[78] G. Liu, P. Ning, F. Lu, K. Li, L.H. Tang, X. Song, H. Guo, C. Wang, Fe/MCSAC catalysts surface modified with nitrogen DBD non-thermal plasma for carbonyl sulfide catalytic hydrolysis activity enhancement, Surf. Interface Anal. 49 (2017) 766-775.
[79] K.L. Li, G. Liu, C. Wang, K. Li, X. Sun, X. Song, P. Ning, Acidic and basic groups introducing on the surface of activated carbon during the plasma-surface modification for changing of COS catalytic hydrolysis activity, Catal. Commun. 144 (2020) 106093.
[80] J.X. Mi, X.P. Chen, Q.Y. Zhang, Y. Zheng, Y.H. Xiao, F.J. Liu, C.T. Au, L.L. Jiang, Mechanochemically synthesized MgAl layered double hydroxide nanosheets for efficient catalytic removal of carbonyl sulfide and H₂S, Chem. Commun. 55 (63) (2019) 9375-9378.
[81] C.M. Li, S.Y. Zhao, X.L. Yao, L. He, S.M. Xu, X.B. Shen, Z.L. Yao, The catalytic mechanism of intercalated chlorine anions as active basic sites in MgAl-layered double hydroxide for carbonyl sulfide hydrolysis, Environ. Sci. Pollut. Res. 29 (7) (2022) 10605-10616.
[82] Y.Q. Zhang, Z.B. Xiao, J.X. Ma, Hydrolysis of carbonyl sulfide over rare earth oxysulfides, Appl. Catal. B Environ. 48 (1) (2004) 57-63.
[83] L.J. Shen, G.J. Wang, X.X. Zheng, Y.N. Cao, Y.F. Guo, K. Lin, L.L. Jiang, Tuning the growth of Cu-MOFs for efficient catalytic hydrolysis of carbonyl sulfide, Chin. J. Catal. 38 (8) (2017) 1373-1381.
[84] F.S. Guo, S.R. Li, Y.D. Hou, J.K. Xu, S. Lin, X.C. Wang, Metalated carbon nitrides as base catalysts for efficient catalytic hydrolysis of carbonyl sulfide, Chem. Commun. 55 (75) (2019) 11259-11262.
[85] I.A. Santos-Lopez, B.E. Handy, R. Garcia-de-Leon, Titanate nanotubes as support of solid base catalyst, Thermochim. Acta 567 (2013) 85-92.
[86] M.J. Yan, Z.B. Xiao, Y.Q. Zhang, J.X. Ma, Reaction of COS hydrolysis over La-Al/cordierite honeycomb catalyst, J. East China Univ. Sci. Technol. 31 (1) (2005) 130-132.
[87] Z. Wei, M.F. Zhao, Z.W. Yang, X.X. Duan, G.X. Jiang, G.G. Li, F.L. Zhang, Z.P. Hao, Oxygen vacancy-engineered titanium-based perovskite for boosting H₂O activation and lower-temperature hydrolysis of organic sulfur, Proc. Natl. Acad. Sci. USA 120 (3) (2023) e2217148120.
[88] S.Z. Zhao, H.H. Yi, X.L. Tang, D.J. Kang, F.Y. Gao, J.G. Wang, Y.H. Huang, Z.Y. Yang, Calcined ZnNiAl hydrotalcite-like compounds as bifunctional catalysts for carbonyl sulfide removal, Catal. Today 327 (2019) 161-167.
[89] B. Wang, Y.T. Lin, Y.R. Li, J. Wang, T.Y. Zhu, Influence factors of catalytic hydrolysis of carbonyl sulfide in blast furnace gas, Clean Coal Technol., 27 (5) (2021) 233-238.
[90] J. Huang, X.D. Li, Y.H. Kong. Study on chlorine poisoning of COS hydrolysis catalyst, Gas Purif., 3 (4) (2003) 39-41.
[91] M.S. Liang, C.H. Li, H.X. Guo, K.C. Xie, Ftir study on oxygen poisoning behavior of Cos hydrolysis catalyst, J. Fuel Chem. Technol. 30 (4) (2002) 347-352.
[92] J. Liu, Y. Liu, L. Xue, Y. Yu, H. He, Oxygen poisoning mechanism of catalytic hydrolysis of OCS over Al₂O₃ at room temperature, Acta Phys. Chim. Sin. 23 (7) (2007) 997-1002.
[93] H.Y. Wang, H.H. Yi, X.L. Tang, P. Ning, L.L. Yu, D. He, S.Z. Zhao, K. Li, Catalytic hydrolysis of COS over calcined CoNiAl hydrotalcite-like compounds modified by cerium, Appl. Clay Sci. 70 (2012) 8-13.
[94] K. Li, X. Song, C. Wang, Y. Mei, X. Sun, P. Ning, Deactivation mechanism of the simultaneous removal of carbonyl sulphide and carbon disulphide over Fe-Cu-Ni/MCSAC catalysts, J. Chem. Sci. 129 (12) (2017) 1893-1903.
[95] H.K. Jin, Z.Y. An, Q.C. Li, Y.Q. Duan, Z.H. Zhou, Z.K. Sun, L.B. Duan, Catalysts of ordered mesoporous alumina with a large pore size for low-temperature hydrolysis of carbonyl sulfide, Energy Fuels 35 (10) (2021) 8895-8908.
[96] E.Y. He, G. Huang, H.L. Fan, C. Yang, H. Wang, Z. Tian, L.J. Wang, Y.R. Zhao, Macroporous alumina- and titania-based catalyst for carbonyl sulfide hydrolysis at ambient temperature, Fuel 246 (2019) 277-284.
[97] Y.X. Liu, J. Shangguan, Z.X. Wang, Y.K. Xu, L. Lin, Moderate temperature COS hydrolysis activity of γ-Al₂O₃ based catalyst modified by TiO₂, Chem. Ind. Eng. Process, 37 (10) (2018) 3885-3894.
[98] C. She, J. Shangguan, L.T. Liang, Y.S. Zhao, Hydrolysis of organic sulfide on aluminum catalysts with TiO₂ and V₂O₅ modification, Petrochem. Technol. 38 (4) (2009) 384-388.
[99] L.T. Liang, J. Shangguan, H.L. Fan, F. Shen, W. Huang, Effects of pore structure on anti-sulfur poisoning of the catalyst for high concentration carbonyl sulfide hydrolysis, J. China Coal Soc. 37 (12) (2012) 2102-2106.
[100] L.T. Liang, J. Shangguan, F. Shen, M.S. Liang, Investigation on COS hydrolysis over TiO₂ alumina catalyst, 2nd Int. Conf. Bioinform. Biomed. Eng. Icbbe 2008 (2008) 3938-3940.
[101] R. Cao, P. Ning, X.Q. Wang, L.L. Wang, Y.X. Ma, Y.B. Xie, H. Zhang, J.X. Qu, Low-temperature hydrolysis of carbonyl sulfide in blast furnace gas using Al₂O₃-based catalysts with high oxidation resistance, Fuel 310 (2022) 122295.
[102] L. Zhang, H.L. Wang, Z. Lei, Y. Jia, Q. Wang, A study on the catalytic performance of the ZrO₂@γ-Al₂O₃ hollow sphere catalyst for COS hydrolysis, New J. Chem. 47 (15) (2023) 7070-7083.
[103] Y.K. Xu, S.G. Ju, Z.X. Wang, Y.X. Liu, The study of the preparation of catalysts for carbonyl sulfide hydrolysis under moderate temperature, J. Mater. Sci. Chem. Eng. 6 (4) (2018) 31-38.
[104] Z. Wei, X. Zhang, F.L. Zhang, Q. Xie, S.Z. Zhao, Z.P. Hao, Boosting carbonyl sulfide catalytic hydrolysis performance over N-doped Mg-Al oxide derived from MgAl-layered double hydroxide, J. Hazard. Mater. 407 (2021) 124546.
[105] R. Cao, X.Q. Wang, P. Ning, Y.B. Xie, L.L. Wang, Y.X. Ma, X. Li, H. Zhang, J.Y. Liu, Advantageous Role of N-doping on K@Al in COS/CS₂ Hydrolysis: Diminished Oxygen Mobility and Rich basic sites, Fuel 337 (2023) 126882.
[106] G.C. Lei, D. Li, Y.J. Ma, S.P. Wang, L.J. Shen, Y.Y. Zhan, L.L. Jiang, Holey carbon nanomeshes with atomically Cu-N₄ active sites for efficient carbonyl sulfide catalytic hydrolysis, Carbon 210 (2023) 118039.
[107] G.L. Zhou, Y.S. Fu, H.J. Zhou, Deactivation and regeneration of ambient temperature COS hydrolysis catalyst, Petrochem. Technol. 30 (8) (2001) 602-604.
[108] L.L. Yu, H.H. Yi, P. Ning, X.L. Tang, H. Li, H.Y. Wang, L.N. Yang, Regeneration of modified activated carbons used as COS hydrolysis catalysts, J. Cent. South Univ. Sci. Technol. 42 (3) (2011) 841-847.
[109] X. Song, P. Ning, L.H. Tang, X. Sun, Y. Mei, C. Wang, K. Li, The kinetic model of simultaneous catalytic hydrolysis of carbon disulfide and carbonyl sulfide over modified walnut shell biochar, J. Chem. Eng. Japan / JCEJ 50 (2) (2017) 115-121.
[110] C. Wang, K. Li, X. Sun, Y. Mei, X. Song, P. Ning, L.N. Sun, Surface characteristics of regenerative Fe-KOH/LSB catalysts for low-temperature catalytic hydrolysis of carbon disulfide and research of the surface regeneration mechanism, Front. Mater. Sci. 12 (4) (2018) 426-437.
[111] K. Yang, J.J. Chen, J.X. Mi, R.Q. Yin, J.H. Yuan, J.Q. Shi, G.M. Wang, J.H. Li, More than just a reactant: H₂O promotes carbonyl sulfide hydrolysis activity over Ni-MgAl-LDO by inhibiting H₂S poisoning, Fuel, 333 (2023) 126503.
[112] Y.R. Lou. Catalysis activities for carbonyl sulfide hydrolysis in complex atmosphere under moderate temperature, Master Thesis, Taiyuan Univ. Technol., China, 2010.
[113] X.P. Wang. The preparation of catalysts and research of kinetics for carbon disulfide hydrolysis under moderate temperature: Master Thesis, Taiyuan Univ. Technol., China, 2007.
[114] X. Song, L.N. Sun, H.B. Guo, K. Li, X. Sun, C. Wang, P. Ning, Experimental and theoretical studies on the influence of carrier gas for COS catalytic hydrolysis over MgAlCe composite oxides, ACS Omega 4 (4) (2019) 7122-7127.
[115] H.H. Yi, C.C. Du, X.D. Zhang, S.Z. Zhao, X.Z. Xie, L.L. Miao, X.L. Tang, Inhibition of CO in blast furnace flue gas on poisoning and deactivation of a Ni/activated carbon catalyst in COS hydrolysis, Ind. Eng. Chem. Res. 60 (49) (2021) 18183-18193.

Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Junyang Li, Roberta Campardelli, Giuseppe Firpo, Jingtao Zhang, Patrizia Perego. Oil-in-water nanoemulsions loaded with lycopene extracts encapsulated by spray drying: Formulation, characterization and optimization [J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 73-81.
[2]	Xiaona Liu, Baohua Zhao, Yanyun Hu, Luyue Huang, Jingxiang Ma, Shuqiao Xu, Zhonglin Xia, Xiaoying Ma, Shuangchen Ma. Enhancing capacitive deionization performance and cyclic stability of nitrogen-doped activated carbon by the electro-oxidation of anode materials [J]. Chinese Journal of Chemical Engineering, 2024, 69(5): 23-33.
[3]	Yuhang Wei, Qingpeng Zhu, Weiwei Xie, Xinyue Wang, Song Li, Zhiming Chen. Biocatalytic enhancement of laccase immobilized on ZnFe₂O₄ nanoparticles and its application for degradation of textile dyes [J]. Chinese Journal of Chemical Engineering, 2024, 68(4): 216-223.
[4]	Yao Li, Yuchun Zhang, Zhiyu Li, Huiyan Zhang, Peng Fu. Reaction pathways and selectivity in the chemo-catalytic conversion of cellulose and its derivatives to ethylene glycol: A review [J]. Chinese Journal of Chemical Engineering, 2024, 66(2): 310-331.
[5]	Xiaojing Liu, Ruohan Zhao, Hao Zhao, Zhimiao Wang, Fang Li, Wei Xue, Yanji Wang. Enhanced stability of nitrogen-doped carbon-supported palladium catalyst for oxidative carbonylation of phenol [J]. Chinese Journal of Chemical Engineering, 2024, 65(1): 19-28.
[6]	Yanfei Pan, Hejian Li, Li Zheng, Xiufeng Xu. The Al₂O₃ and Mn/Al₂O₃ sorbents highly utilized in destructive sorption of NF₃ [J]. Chinese Journal of Chemical Engineering, 2024, 65(1): 54-62.
[7]	Fangren Qian, Lishan Peng, Yujuan Zhuang, Lei Liu, Qingjun Chen. Direct atomic-level insight into oxygen reduction reaction on size-dependent Pt-based electrocatalysts from density functional theory calculations [J]. Chinese Journal of Chemical Engineering, 2023, 61(9): 140-146.
[8]	Jianfeng Cheng, Meixuan Li, Yutong Wang, Jiexiang Li, Jiawei Wen, Chunxia Wang, Guoyong Huang. Effects of Al and Co doping on the structural stability and high temperature cycling performance of LiNi_0.5Mn_1.5O₄ spinel cathode materials [J]. Chinese Journal of Chemical Engineering, 2023, 61(9): 201-209.
[9]	Yifan Jiang, Bingqi Xie, Jisong Zhang. Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 165-172.
[10]	Peipei Ai, Huiqing Jin, Jie Li, Xiaodong Wang, Wei Huang. Ultra-stable Cu-based catalyst for dimethyl oxalate hydrogenation to ethylene glycol [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 186-193.
[11]	Fei Li, Xuemei Wang, Pengze Zhang, Qinqin Wang, Mingyuan Zhu, Bin Dai. Nitrogen and phosphorus co-doped activated carbon induces high density Cu⁺ active center for acetylene hydrochlorination [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 193-199.
[12]	Wei Yang, Yalun Ma, Xu Zhang, Fan Yang, Dong Zhang, Shengji Wu, Huanghu Peng, Zezhou Chen, Lei Che. Effect of acid-associated mechanical pretreatment on the hydrolysis behavior of pine sawdust in subcritical water [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 195-204.
[13]	Bingxiao Feng, Lining Hao, Chaoting Deng, Jiaqiang Wang, Hongbing Song, Meng Xiao, Tingting Huang, Quanhong Zhu, Hengjun Gai. A highly hydrothermal stable copper-based catalyst for catalytic wet air oxidation of m-cresol in coal chemical wastewater [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 338-348.
[14]	Zhenfu Wang, Jie Gao, Qinghong Shi, Xiaoyan Dong, Yan Sun. Facile purification and immobilization of organophosphorus hydrolase on protein-inorganic hybrid phosphate nanosheets [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 119-125.
[15]	Xia Xiong, Zuohua Liu, Changyuan Tao, Yundong Wang, Fangqin Cheng, Hong Li. Reduced power consumption in stirred vessel with high solid loading by equipping punched baffles [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 203-214.