SCI和EI收录∣中国化工学会会刊

›› 2008, Vol. 16 ›› Issue (1): 151-154.

• RESEARCH NOTES • Previous Articles     Next Articles

Preparation of Butyl Chloride from Butanol and Hydrochloric Acid Using Ionic Liquids as Catalyst

SUN Aijun, NIE Yi, LI Chunxi, WANG Zihao   

  1. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2007-03-26 Revised:2007-12-24 Online:2008-02-28 Published:2008-02-28
  • Supported by:
    the National Natural Science Foundation of China (No.20376004)

Preparation of Butyl Chloride from Butanol and Hydrochloric Acid Using Ionic Liquids as Catalyst

孙爱军, 聂毅, 李春喜, 王子镐   

  1. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • 通讯作者: LI Chunxi, E-mail: licx@mail.buct.edu.cn
  • 基金资助:
    the National Natural Science Foundation of China (No.20376004)

Abstract: The catalytic performance of some quaternary ammonium salts for the liquid phase reaction of butanol and hydrochloric acid at different conditions was studied experimentally and compared with the traditional catalyst (ZnCl2). The organic ammonium catalysts investigated include ionic liquids N-butyl-N-methyl imidazolium fluobo-rate ([BMIM][BF4]) and N-butyl-N-methylimidazolium chloride ([BMIM]Cl) as well as hydrochloric salts of N-methylimidazol ([HMIM]Cl), pyridine ([HPy]Cl) and triethylamine ([HEt3N]Cl). It is shown that the intrinsic catalytic performance of all organic ammonium salts except [HEt3N]Cl is slightly superior to ZnCl2, while the selectivity of butyl chloride is nearly at the same level around 96%. The conversion of butanol increases slightly with temperature and the catalyst amount added while the variation of selectivity is not obvious. Based on the recycle experiments, the ionic liquids as catalyst for the reaction of butanol and hydrochloric acid can be used more than 5 times, which suggests great potential of using ionic liquids as novel catalyst for such reactions.

Key words: ionic liquid, butyl chloride, butanol, hydrochloric acid, catalyst

摘要: The catalytic performance of some quaternary ammonium salts for the liquid phase reaction of butanol and hydrochloric acid at different conditions was studied experimentally and compared with the traditional catalyst (ZnCl2). The organic ammonium catalysts investigated include ionic liquids N-butyl-N-methyl imidazolium fluobo-rate ([BMIM][BF4]) and N-butyl-N-methylimidazolium chloride ([BMIM]Cl) as well as hydrochloric salts of N-methylimidazol ([HMIM]Cl), pyridine ([HPy]Cl) and triethylamine ([HEt3N]Cl). It is shown that the intrinsic catalytic performance of all organic ammonium salts except [HEt3N]Cl is slightly superior to ZnCl2, while the selectivity of butyl chloride is nearly at the same level around 96%. The conversion of butanol increases slightly with temperature and the catalyst amount added while the variation of selectivity is not obvious. Based on the recycle experiments, the ionic liquids as catalyst for the reaction of butanol and hydrochloric acid can be used more than 5 times, which suggests great potential of using ionic liquids as novel catalyst for such reactions.

关键词: ionic liquid, butyl chloride, butanol, hydrochloric acid, catalyst