SCI和EI收录∣中国化工学会会刊

›› 2009, Vol. 17 ›› Issue (3): 401-406.

• CATALYSIS, KINETICS AND REACTORS • Previous Articles     Next Articles

Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

LIANG Yinghua1, GUO Hongxia1,2, CHEN Hongping1, LÜJingde3, ZHANG Bobo1   

  1. 1. School of Chemical Engineering and Biological Technology, Hebei Polytechnic University, Tangshan 063009, China;
    2. College of Light Industry, Hebei Polytechnic University, Tangshan 063000, China;
    3. Tangshan Zhongrun Coal Chemical Co., Ltd., Tangshan 063611, China
  • Received:2008-10-17 Revised:2008-12-05 Online:2009-06-28 Published:2009-06-28

Effect of Doping Cerium in the Support of Catalyst Pd-Co/Cu-Co-Mn Mixed Oxides on the Oxidative Carbonylation of Phenol

梁英华1, 郭红霞1,2, 陈红萍1, 吕敬德3, 张波波1   

  1. 1. School of Chemical Engineering and Biological Technology, Hebei Polytechnic University, Tangshan 063009, China;
    2. College of Light Industry, Hebei Polytechnic University, Tangshan 063000, China;
    3. Tangshan Zhongrun Coal Chemical Co., Ltd., Tangshan 063611, China
  • 通讯作者: LIANG Yinghua,E-mail:Liangyh64@yahoo.com.cn

Abstract: Effect of doping cerium in the support on the catalytic activity and side product of the reaction in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) over the catalyst Pd-Co/Cu-Co-Mn mixed oxides was studied. The specific surface areas, crystal phase, valency, and content of the element on the surface of the catalysts were determined, and the products were detected by gas chromatograph/mass spectrometry (GC-MS). It is found that the catalyst without Ce shows higher activity than that with Ce, and the yields of DPC for the two catalysts can reach 30% and 23%, respectively. However, doping cerium can prevent the formation of 2-hydroxyphenyl benzoate and p-bromophenyl phenyl carbonate.

Key words: diphenyl carbonate, oxidative carbonylation, doping cerium, sol-gel method

摘要: Effect of doping cerium in the support on the catalytic activity and side product of the reaction in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) over the catalyst Pd-Co/Cu-Co-Mn mixed oxides was studied. The specific surface areas, crystal phase, valency, and content of the element on the surface of the catalysts were determined, and the products were detected by gas chromatograph/mass spectrometry (GC-MS). It is found that the catalyst without Ce shows higher activity than that with Ce, and the yields of DPC for the two catalysts can reach 30% and 23%, respectively. However, doping cerium can prevent the formation of 2-hydroxyphenyl benzoate and p-bromophenyl phenyl carbonate.

关键词: diphenyl carbonate, oxidative carbonylation, doping cerium, sol-gel method