SCI和EI收录∣中国化工学会会刊

›› 2012, Vol. 20 ›› Issue (1): 27-35.

• FESTSCHRIFT IN HONOR OF THE 90TH BIRTHDAY OF PROF. CHEN JIAYONG • Previous Articles     Next Articles

Liquid-Liquid-Liquid Three Phase Extraction Apparatus:Operation Strategy and Influences on Mass Transfer Efficiency

HE Xiuqiong1,2, HUANG Kun1, YU Pinhua1,2, ZHANG Chao1,2, XIE Keng1,2, LI Pengfei1,2, WANG Juan1,2, AN Zhentao1, LIU Huizhou1   

  1. 1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sci-ences, Beijing 100190, China;
    2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2011-06-28 Revised:2011-09-23 Online:2012-05-03 Published:2012-02-28
  • Supported by:
    Supported by the National Natural Science Foundation of China (51074150,21027004);the National Basic Research Program of China (2012CBA01203,2007CB613507);the Innovative Research Group Science Fund (20221603)

Liquid-Liquid-Liquid Three Phase Extraction Apparatus:Operation Strategy and Influences on Mass Transfer Efficiency

何秀琼1,2, 黄昆1, 于品华1,2, 张超1,2, 谢铿1,2, 李鹏飞1,2, 王娟1,2, 安震涛1, 刘会洲1   

  1. 1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sci-ences, Beijing 100190, China;
    2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • 通讯作者: HUANG Kun,E-mail:khuang@home.ipe.ac.cn;LIU Huizhou,E-mail:hzliu@home.ipe.ac.cn
  • 基金资助:
    Supported by the National Natural Science Foundation of China (51074150,21027004);the National Basic Research Program of China (2012CBA01203,2007CB613507);the Innovative Research Group Science Fund (20221603)

Abstract: A new mixer-settler-mixer three chamber integrated extractor is proposed in this work for liquid-liquid-liquid three phase countercurrent and continuous extraction.Experiments revealed the influences of the structural design of the three-liquid-phase extractor and some key operational parameters on three-phase partition of two phenolic isomers,p-nitrophenol(p-NP) and o-nitrophenol(o-NP).The model three-liquid-phase extraction system used here is nonane(organic top-phase)-polyethylene glycol(PEG 2000)(polymer middle-phase)-(NH4)2SO4 aqueous solution(aqueous bottom-phase).It is indicated that agitating speed and retention time in three-phase mixer are key parameters to extraction fraction of nitrophenol.Dispersion band behavior is related to agitating intensity,and its occurrence does not affect the extraction fraction of target compounds.The present work highlights the possibility of a feasible approach of scaling up of the proposed three-phase extraction apparatus for future industrial-aimed applications.

Key words: three-liquid-phase extraction, extractor, mixer-settler-mixer, separation, nitrophenol

摘要: A new mixer-settler-mixer three chamber integrated extractor is proposed in this work for liquid-liquid-liquid three phase countercurrent and continuous extraction.Experiments revealed the influences of the structural design of the three-liquid-phase extractor and some key operational parameters on three-phase partition of two phenolic isomers,p-nitrophenol(p-NP) and o-nitrophenol(o-NP).The model three-liquid-phase extraction system used here is nonane(organic top-phase)-polyethylene glycol(PEG 2000)(polymer middle-phase)-(NH4)2SO4 aqueous solution(aqueous bottom-phase).It is indicated that agitating speed and retention time in three-phase mixer are key parameters to extraction fraction of nitrophenol.Dispersion band behavior is related to agitating intensity,and its occurrence does not affect the extraction fraction of target compounds.The present work highlights the possibility of a feasible approach of scaling up of the proposed three-phase extraction apparatus for future industrial-aimed applications.

关键词: three-liquid-phase extraction, extractor, mixer-settler-mixer, separation, nitrophenol

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