Aminopropyl-containing ionic liquid based organosilica as a novel and efficient adsorbent for removal of crystal violet from wastewaters

doi:10.1016/j.cjche.2016.09.003

Abstract

Abstract: Herein a novel aminopropyl-containing ionic liquid based organosilica (ILOS-NH₂) is prepared, characterized and applied as effective adsorbent for removal of crystal violet (CV) dye from wastewater. The ILOS-NH₂ material was synthesized by hydrolysis and co-condensation of 1,3-bis-(3-trimethoxysilylpropyl)-imidazolium chloride (BTMSPIC) under acidic conditions followed by treatment with 3-aminopropyl-trimethoxysilane in toluene under reflux conditions. This material was characterized using scanning electron microscopy (SEM), diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), thermal gravimetric analysis (TGA) and energy dispersive X-ray analysis (EDAX). The material was effectively used in the removal of crystal violet at ambient temperature and showed high capacity and stability under applied conditions. The efficacy of pH, contact time, adsorbent dose, initial dye concentration, temperature, and isotherm studies and the applicability of pseudo-first, second order and Elovich kinetic models have also been investigated.

Key words: Ionic liquid based organosilica, Aminopropyl-functionalized, Crystal violet (CV), Isotherm, Kinetic

摘要： Herein a novel aminopropyl-containing ionic liquid based organosilica (ILOS-NH₂) is prepared, characterized and applied as effective adsorbent for removal of crystal violet (CV) dye from wastewater. The ILOS-NH₂ material was synthesized by hydrolysis and co-condensation of 1,3-bis-(3-trimethoxysilylpropyl)-imidazolium chloride (BTMSPIC) under acidic conditions followed by treatment with 3-aminopropyl-trimethoxysilane in toluene under reflux conditions. This material was characterized using scanning electron microscopy (SEM), diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), thermal gravimetric analysis (TGA) and energy dispersive X-ray analysis (EDAX). The material was effectively used in the removal of crystal violet at ambient temperature and showed high capacity and stability under applied conditions. The efficacy of pH, contact time, adsorbent dose, initial dye concentration, temperature, and isotherm studies and the applicability of pseudo-first, second order and Elovich kinetic models have also been investigated.

关键词: Ionic liquid based organosilica, Aminopropyl-functionalized, Crystal violet (CV), Isotherm, Kinetic

Frood Shojaeipoor, Bakhshali Masoumi, Mohammad Hossain Banakar, Javad Rastegar. Aminopropyl-containing ionic liquid based organosilica as a novel and efficient adsorbent for removal of crystal violet from wastewaters[J]. , 2017, 25(9): 1294-1302.

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