Sustainable value-added C3 chemicals from glycerol transformations: A mini review for heterogeneous catalytic processes

doi:10.1016/j.cjche.2019.03.001

Abstract

Abstract: It is of importance to convert glycerol, the primary by-product from biodiesel manufacturing, to various valuable C₃ chemicals, such as acrolein via dehydration, lactic acid, 1,3-dihydroxyacetone via oxidation, and 1,3-propanediol, allyl alcohol via hydrogenolysis. As compared to petroleum-based resources, C₃ chemicals from glycerol provide a benign, sustainable and atomically economic feature. Extensive heterogeneous catalysts have been designed, prepared and tested for these transformations. In recent five years, great progress, including high yields to target products over appropriate catalysts, insight into reaction mechanism and network, has been achieved. The present review systematically covers recent research progress on sustainable C₃ chemical production from catalytic glycerol transformations. We hope that it will benefit future research on transformations of glycerol as well as other polyols.

Key words: Catalysis, Biodiesel, Glycerol, Sustainable C₃ compounds, Glycerol oxidation, Glycerol hydrogenolysis, Glycerol dehydration

摘要： It is of importance to convert glycerol, the primary by-product from biodiesel manufacturing, to various valuable C₃ chemicals, such as acrolein via dehydration, lactic acid, 1,3-dihydroxyacetone via oxidation, and 1,3-propanediol, allyl alcohol via hydrogenolysis. As compared to petroleum-based resources, C₃ chemicals from glycerol provide a benign, sustainable and atomically economic feature. Extensive heterogeneous catalysts have been designed, prepared and tested for these transformations. In recent five years, great progress, including high yields to target products over appropriate catalysts, insight into reaction mechanism and network, has been achieved. The present review systematically covers recent research progress on sustainable C₃ chemical production from catalytic glycerol transformations. We hope that it will benefit future research on transformations of glycerol as well as other polyols.

关键词: Catalysis, Biodiesel, Glycerol, Sustainable C₃ compounds, Glycerol oxidation, Glycerol hydrogenolysis, Glycerol dehydration

Yuan Wang, Yang Xiao, Guomin Xiao. Sustainable value-added C₃ chemicals from glycerol transformations: A mini review for heterogeneous catalytic processes[J]. Chinese Journal of Chemical Engineering, 2019, 27(7): 1536-1542.

Yuan Wang, Yang Xiao, Guomin Xiao. Sustainable value-added C₃ chemicals from glycerol transformations: A mini review for heterogeneous catalytic processes[J]. 中国化学工程学报, 2019, 27(7): 1536-1542.

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Sustainable value-added C₃ chemicals from glycerol transformations: A mini review for heterogeneous catalytic processes

Sustainable value-added C₃ chemicals from glycerol transformations: A mini review for heterogeneous catalytic processes

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[3]	Tingjun Fu, Ran Wang, Kun Ren, Liangliang Zhang, Zhong Li. Intensified shape selectivity and alkylation reaction for the two-step conversion of methanol aromatization to p-xylene [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 240-250.
[4]	Haodi Tan, Minjiao Yang, Yingquan Chen, Xu Chen, Francesco Fantozzi, Pietro Bartocci, Roman Tschentscher, Federica Barontini, Haiping Yang, Hanping Chen. Preparation of aromatic hydrocarbons from catalytic pyrolysis of digestate [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 1-9.
[5]	Chenyang Zhao, Yinhan Cheng, Guangfei Qu, Yongheng Yuan, Fenghui Wu, Ye Liu, Shan Liu, Junyan Li, Ping Ning. High-performance liquid-phase catalytic purification of phosphine in tail gas using Pd(II)/Cu(II) composite [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 98-108.
[6]	Juan Du, Aibing Chen, Senlin Hou, Xueqing Gao. Self-deposition for mesoporous carbon nanosheet with supercapacitor application [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 34-40.
[7]	Mengting Liu, Xuexue Dong, Zengjing Guo, Aihua Yuan, Shuying Gao, Fu Yang. Enabling tandem oxidation of benzene to benzenediol over integrated neighboring V-Cu oxides in mesoporous silica [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 236-245.
[8]	Qian Zhu, Yan Zhuang, Hongqing Zhao, Peng Zhan, Cong Ren, Changsheng Su, Wenqiang Ren, Jiawen Zhang, Di Cai, Peiyong Qin. 2,5-Diformylfuran production by photocatalytic selective oxidation of 5-hydroxymethylfurfural in water using MoS₂/CdIn₂S₄ flower-like heterojunctions [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 180-191.
[9]	Wenjuan Yan, Puhua Sun, Chen Luo, Xingfan Xia, Zhifei Liu, Yuming Zhao, Shuxia Zhang, Liang Sun, Feng Du. PtCo-based nanocatalyst for oxygen reduction reaction: Recent highlights on synthesis strategy and catalytic mechanism [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 101-123.
[10]	Kechang Gao, Shengjuan Shao, Zhixing Li, Jiaxin Jing, Weizhou Jiao, Youzhi Liu. Kinetics of the direct reaction between ozone and phenol by high-gravity intensified heterogeneous catalytic ozonation [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 317-323.
[11]	Yishuang Wang, Na Li, Mingqiang Chen, Defang Liang, Chang Li, Quan Liu, Zhonglian Yang, Jun Wang. Glycerol steam reforming over hydrothermal synthetic Ni-Ca/attapulgite for green hydrogen generation [J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 176-190.
[12]	Shuo Li, Jianlin Cao, Xiang Feng, Yupeng Du, De Chen, Chaohe Yang, Wenhua Wang, Wanzhong Ren. Insights into the confinement effect on isobutane alkylation with C₄ olefin catalyzed by zeolite catalyst: A combined theoretical and experimental study [J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 174-184.
[13]	Zhouxin Chang, Feng Yu, Zhisong Liu, Zijun Wang, Jiangbing Li, Bin Dai, Jinli Zhang. Ni-Al mixed metal oxide with rich oxygen vacancies: CO methanation performance and density functional theory study [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 73-83.
[14]	Weizhou Jiao, Xingyue Wei, Shengjuan Shao, Youzhi Liu. Catalytic decomposition and mass transfer of aqueous ozone promoted by Fe-Mn-Cu/γ-Al₂O₃ in a rotating packed bed [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 133-142.
[15]	Xin Ren, Li Leng, Yueqiang Cao, Jing Zhang, Xuezhi Duan, Xueqing Gong, Jinghong Zhou, Xinggui Zhou. Enhanced recycling performance of bimetallic Ir-Re/SiO₂ catalyst by amberlyst-15 for glycerol hydrogenolysis [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 171-181.