The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

doi:10.1016/j.cjche.2020.06.026

Chinese Journal of Chemical Engineering ›› 2020, Vol. 28 ›› Issue (9): 2227-2234.DOI: 10.1016/j.cjche.2020.06.026

• Review • Next Articles

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

Guoju Yang^1,2, Ji Han¹, Yue Liu³, Ziyi Qiu¹, Xiaoxin Chen¹

1 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2 International Center of Future Science, Jilin University, Changchun 130012, China;
3 Department of Chemistry and Catalysis Research Center, Technische Universit?t München, Lichtenbergstrasse 4, 85747 Garching, Germany

Received:2020-05-27 Revised:2020-06-12 Online:2020-10-21 Published:2020-09-28
Contact: Xiaoxin Chen
Supported by:
This work is supported by the National Natural Science Foundation of China (21971082) and the Jilin Province Science and Technology Development Plan (20200201096JC and 20190201229JC). G.J. Yang thanks the China Postdoctoral Science Foundation (2019T120235 and 2018M640280) for supporting this work. This work acknowledges the 111 Project (B17020) and the collaboration in the framework of joint Sino-French international laboratory "Zeolites".

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

Guoju Yang^1,2, Ji Han¹, Yue Liu³, Ziyi Qiu¹, Xiaoxin Chen¹

1 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2 International Center of Future Science, Jilin University, Changchun 130012, China;
3 Department of Chemistry and Catalysis Research Center, Technische Universit?t München, Lichtenbergstrasse 4, 85747 Garching, Germany

通讯作者: Xiaoxin Chen
基金资助:
This work is supported by the National Natural Science Foundation of China (21971082) and the Jilin Province Science and Technology Development Plan (20200201096JC and 20190201229JC). G.J. Yang thanks the China Postdoctoral Science Foundation (2019T120235 and 2018M640280) for supporting this work. This work acknowledges the 111 Project (B17020) and the collaboration in the framework of joint Sino-French international laboratory "Zeolites".

Abstract

Abstract: With the increasingly stringent standards for limiting sulfide content in liquid fuels, oxidative desulfurization (ODS) has become a promising ultra-deep desulfurization process in fuel desulfurization. TS-1 zeolites show great potential as catalysts for ODS reactions, due to its remarkable oxidation activity at low temperatures and pressure. However, the inherent microporous structure of conventional TS-1 zeolites restricts the mass transportation and renders the active sites in the microporous space of TS-1 zeolites inaccessible for bulky aromatic organosulfur compounds. Fabrication of hierarchical TS-1 zeolites by incorporating meso-/macropores into microporous TS-1 zeolites is an effective strategy to improve mass transportability. In recent years, abundant efforts have been dedicated to developing synthetic strategies of hierarchical TS-1 zeolite, thereby improving its catalytic performance in the ODS process. This mini-review addresses the synthetic methods of hierarchical TS-1 catalysts and their catalytic performance in the ODS reactions. In addition, some current problems and prospects of synthesis routes for constructing hierarchical TS-1 catalysts have also been revised. We expect this mini-review to shed light on the more efficient preparation strategies of hierarchical TS-1 zeolites for the ODS process.

Key words: Zeolites, TS-1, Synthesis, Hierarchical, ODS

摘要： With the increasingly stringent standards for limiting sulfide content in liquid fuels, oxidative desulfurization (ODS) has become a promising ultra-deep desulfurization process in fuel desulfurization. TS-1 zeolites show great potential as catalysts for ODS reactions, due to its remarkable oxidation activity at low temperatures and pressure. However, the inherent microporous structure of conventional TS-1 zeolites restricts the mass transportation and renders the active sites in the microporous space of TS-1 zeolites inaccessible for bulky aromatic organosulfur compounds. Fabrication of hierarchical TS-1 zeolites by incorporating meso-/macropores into microporous TS-1 zeolites is an effective strategy to improve mass transportability. In recent years, abundant efforts have been dedicated to developing synthetic strategies of hierarchical TS-1 zeolite, thereby improving its catalytic performance in the ODS process. This mini-review addresses the synthetic methods of hierarchical TS-1 catalysts and their catalytic performance in the ODS reactions. In addition, some current problems and prospects of synthesis routes for constructing hierarchical TS-1 catalysts have also been revised. We expect this mini-review to shed light on the more efficient preparation strategies of hierarchical TS-1 zeolites for the ODS process.

关键词: Zeolites, TS-1, Synthesis, Hierarchical, ODS

Guoju Yang, Ji Han, Yue Liu, Ziyi Qiu, Xiaoxin Chen. The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions[J]. Chinese Journal of Chemical Engineering, 2020, 28(9): 2227-2234.

Guoju Yang, Ji Han, Yue Liu, Ziyi Qiu, Xiaoxin Chen. The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions[J]. 中国化学工程学报, 2020, 28(9): 2227-2234.

References

[1] S. Houda, C. Lancelot, P. Blanchard, L. Poinel, C. Lamonier, Oxidative desulfurization of heavy oils with high sulfur content:A review, Catalysts 8(9) (2018) 344.
[2] M.N. Hossain, H.C. Park, H.S. Choi, A comprehensive review on catalytic oxidative desulfurization of liquid fuel oil, Catalysts 9(3) (2019) 229.
[3] M. Breysse, G. Djega-Mariadassou, S. Pessayre, C. Geantet, M. Vrinat, G. Pérot, M. Lemaire, Deep desulfurization:reactions, catalysts and technological challenges, Catal. Today 84(3) (2003) 129-138.
[4] L. Cedeño-Caero, H. Gomez-Bernal, A. Fraustro-Cuevas, H.D. Guerra-Gomez, R. Cuevas-Garcia, Oxidative desulfurization of synthetic diesel using supported catalysts:Part III. Support effect on vanadium-based catalysts, Catal. Today 133-135(2008) 244-254.
[5] W.A.W.A. Bakar, R. Ali, A.A.A. Kadir, W.N.A.W. Mokhtar, Effect of transition metal oxides catalysts on oxidative desulfurization of model diesel, Fuel Process. Technol. 101(2012) 78-84.
[6] K.-G. Haw, W.A.W.A. Bakar, R. Ali, J.-F. Chong, A.A.A. Kadir, Catalytic oxidative desulfurization of diesel utilizing hydrogen peroxide and functionalized-activated carbon in a biphasic diesel-acetonitrile system, Fuel Process. Technol. 91(9) (2010) 1105-1112.
[7] A.S. Ogunlaja, O.S. Alade, Z.R. Tshentu, Vanadium(IV) catalysed oxidation of organosulfur compounds in heavy fuel oil, CR CHIM 20(2) (2017) 164-168.
[8] J. Přech, Catalytic performance of advanced titanosilicate selective oxidation catalysts-A review, Catal. Rev. 60(1) (2018) 71-131.
[9] J. Li, A. Corma, J. Yu, Synthesis of new zeolite structures, Chem. Soc. Rev. 44(20) (2015) 7112-7127.
[10] M.E. Davis, Ordered porous materials for emerging applications, Nature 417(6891) (2002) 813-821.
[11] Y. Wang, X. Zou, L. Sun, H. Rong, G. Zhu, A zeolite-like aluminophosphate membrane with molecular-sieving property for water desalination, Chem. Sci. 9(9) (2018) 2533-2539.
[12] H.Z. Rong, G.M. Wang, J.X. Yan, X.Q. Zou, G.S. Zhu, Surface-gel-conversion synthesis of submicron-thick MFI zeolite c isomers, Sci. China Mater. (2020) https://doi.org/10.1007/s40843-020-1400-y.
[13] G. Yang, J. Han, Z. Qiu, X. Chen, Z. Feng, J. Yu, An amino acid-assisted approach to fabricate nanosized hierarchical TS-1 zeolites for efficient oxidative desulfurization, Inorg. Chem. Front. 7(10) (2020) 1975-1980.
[14] S. Du, X. Chen, Q. Sun, N. Wang, M.J. Jia, V. Valtchev, J. Yu, A non-chemically selective top-down approach towards the preparation of hierarchical TS-1 zeolites with improved oxidative desulfurization catalytic performance, Chem. Commun. 52(17) (2016) 3580-3583.
[15] R. Bai, Q. Sun, Y. Song, N. Wang, T. Zhang, F. Wang, Y. Zou, Z. Feng, S. Miao, J. Yu, Intermediate-crystallization promoted catalytic activity of titanosilicate zeolites, J. Mater. Chem. A 6(18) (2018) 8757-8762.
[16] L. Xu, H. Peng, K. Zhang, H. Wu, L. Chen, Y. Liu, P. Wu, Core-shell-structured titanosilicate as a robust catalyst for cyclohexanone ammoximation, ACS Catal. 3(1) (2013) 103-110.
[17] X. Feng, N. Sheng, Y. Liu, X. Chen, D. Chen, C. Yang, X. Zhou, Simultaneously enhanced stability and selectivity for propene epoxidation with H₂ and O₂ on Au catalysts supported on nano-crystalline mesoporous TS-1, ACS Catal. 7(4) (2017) 2668-2675.
[18] Z. Deng, Y. Yang, X. Lu, J. Ding, M. He, P. Wu, Studies on the epoxidation of methallyl chloride over TS-1 microsphere catalysts in a continuous slurry reactor, Catal. Sci. Technol. 6(8) (2016) 2605-2615.
[19] M. Sasaki, Y. Sato, Y. Tsuboi, S. Inagaki, Y. Kubota, Ti-YNU-2:A microporous titanosilicate with enhanced catalytic performance for phenol oxidation, ACS Catal. 4(8) (2014) 2653-2657.
[20] T. Zhang, X. Chen, G. Chen, M. Chen, R. Bai, M. Jia, J. Yu, Synthesis of anatase-free nano-sized hierarchical TS-1 zeolites and their excellent catalytic performance in alkene epoxidation, J. Mater. Chem. A 6(20) (2018) 9473-9479.
[21] V. Valtchev, S. Mintova, Hierarchical zeolites, MRS Bull. 41(9) (2016) 689-693.
[22] R. Bai, Y. Song, Y. Li, J. Yu, Creating hierarchical pores in zeolite catalysts, Trends Chem. 1(6) (2019) 601-611.
[23] L.-H. Chen, X.-Y. Li, G. Tian, Y. Li, J. Rooke, G.-S. Zhu, S.-L. Qiu, X.-Y. Yang, B.-L. Su, Highly stable and reusable multimodal zeolite TS-1 based catalysts with hierarchically interconnected three-level micro-meso-macroporous structure, Angew. Chem. Int. Ed. 50(47) (2011) 11156-11161.
[24] Z. Hua, J. Zhou, J. Shi, Recent advances in hierarchically structured zeolites:Synthesis and material performances, Chem. Commun. 47(38) (2011) 10536-10547.
[25] V. Valtchev, G. Majano, S. Mintova, J. Pérez-Ramírez, Tailored crystalline microporous materials by post-synthesis modification, Chem. Soc. Rev. 42(1) (2013) 263-290.
[26] P. Bai, E. Haldoupis, P. Dauenhauer, M. Tsapatsis, I. Siepmann, Understanding diffusion in hierarchical zeolites with house-of-cards nanosheets, ACS Nano 10(8) (2016) 7612-7618.
[27] W. Schwieger, G. Machoke, T. Weissenberger, A. Inayat, T. Selvam, M. Klumpp, A. Inayat, Hierarchy concepts:Classification and preparation strategies for zeolite containing materials with hierarchical porosity, Chem. Soc. Rev. 45(12) (2016) 3353-3376.
[28] S. Du, Q. Sun, N. Wang, X. Chen, M. Jia, J. Yu, Synthesis of hierarchical TS-1 zeolites with abundant and uniform intracrystalline mesopores and their highly efficient catalytic performance for oxidation desulfurization, J. Mater. Chem. A 5(17) (2017) 7992-7998.
[29] S. Du, F. Li, Q. Sun, N. Wang, M. Jia, J. Yu, A green surfactant-assisted synthesis of hierarchical TS-1 zeolites with excellent catalytic properties for oxidative desulfurization, Chem. Commun. 52(16) (2016) 3368-3371.
[30] X. Wang, G. Li, W. Wang, C. Jin, Y. Chen, Synthesis, characterization and catalytic performance of hierarchical TS-1 with carbon template from sucrose carbonization, Microporous Mesoporous Mater. 142(2) (2011) 494-502.
[31] W. Wang, G. Li, L. Liu, Y. Chen, Synthesis and catalytic performance of hierarchical TS-1 directly using agricultural products sucrose as meso/macropores template, Microporous Mesoporous Mater. 179(2013) 165-171.
[32] D.P. Serrano, R. Sanz, P. Pizarro, I. Moreno, S. Shami, Narrowing the mesopore size distribution in hierarchical TS-1 zeolite by surfactant-assisted reorganization, Microporous Mesoporous Mater. 189(2014) 71-82.
[33] G. Lv, S. Deng, Y. Zhai, Y. Zhu, H. Li, F. Wang, X. Zhang, P123 lamellar micelle-assisted construction of hierarchical TS-1 stacked nanoplates with constrained mesopores for enhanced oxidative desulfurization, Appl. Catal. A 567(2018) 28-35.
[34] Q. Du, Y. Guo, P. Wu, H. Liu, Y. Chen, Facile synthesis of hierarchical TS-1 zeolite without using mesopore templates and its application in deep oxidative desulfurization, Microporous Mesoporous Mater. 275(2019) 61-68.
[35] J. Pérez-Ramírez, C. Christensen, K. Egeblad, C. Christensen, J.C. Groen, Hierarchical zeolites:Enhanced utilisation of microporous crystals in catalysis by advances in materials design, Chem. Soc. Rev. 37(11) (2008) 2530-2542.
[36] I. Schmidt, A. Krogh, K. Wienberg, A. Carlsson, M. Brorson, C. Jacobsen, Catalytic epoxidation of alkenes with hydrogen peroxide over first mesoporous titaniumcontaining zeolite, Chem. Commun. (21) (2000) 2157-2158.
[37] I. Schmidt, A. Boisen, E. Gustavsson, K. Ståhl, S. Pehrson, S. Dahl, A. Carlsson, C. Jacobsen, Carbon nanotube templated growth of mesoporous zeolite single crystals, Chem. Mater. 13(12) (2001) 4416-4418.
[38] Y. Fang, H. Hu, Mesoporous TS-1:Nanocasting synthesis with CMK-3 as template and its performance in catalytic oxidation of aromatic thiophene, Catal. Commun. 8(5) (2007) 817-820.
[39] Y. Tao, H. Kanoh, K. Kaneko, ZSM-5 monolith of uniform mesoporous channels, J. Am. Chem. Soc. 125(20) (2003) 6044-6045.
[40] Y. Wei, G. Li, Q. Lü, C. Cheng, H. Guo, Green and efficient epoxidation of methyl oleate over hierarchical TS-1, Chin. J. Catal. 39(5) (2018) 964-972.
[41] X. Gao, J. An, J. Gu, L. Li, Y. Li, A green template-assisted synthesis of hierarchical TS-1 with excellent catalytic activity and recyclability for the oxidation of 2,3,6-trimethylphenol, Microporous Mesoporous Mater. 239(2017) 381-389.
[42] S.S. Soni, G. Brotons, M. Bellour, T. Narayanan, A. Gibaud, Quantitative SAXS analysis of the P123/water/ethanol ternary phase diagram, J. Phys. Chem. B 110(31) (2006) 15157-15165.
[43] Y. Dou, T. Liao, Z. Ma, D. Tian, Q. Liu, F. Xiao, Z. Sun, J. Ho Kim, S. Xue Dou, Graphenelike holey Co₃O₄ nanosheets as a highly efficient catalyst for oxygen evolution reaction, Nano Energy 30(2016) 267-275.
[44] S. Goergen, E. Guillon, J. Patarin, L. Rouleau, Preparation of advanced zeolite catalysts by dry gel conversion, in:A. Gédéon, P. Massiani, F. Babonneau (Eds.), Stud. Surf. Sci. Catal. Elsevier 2008, pp. 277-280.
[45] Z. You, G. Liu, L. Wang, X. Zhang, Binderless nano-HZSM-5 zeolite coatings prepared through combining washcoating and dry-gel conversion (DGC) methods, Microporous Mesoporous Mater. 170(2013) 235-242.
[46] Y. Jiao, L. Forster, S. Xu, H. Chen, J. Han, X. Liu, Y. Zhou, J. Liu, J. Zhang, J. Yu, C. D'Agostino, X. Fan, Creation of Al-enriched mesoporous ZSM-5 nanoboxes with high catalytic activity:Converting tetrahedral extra-framework Al into framework sites by post treatment, Angew. Chem. Int. Ed. (2020)https://doi.org/10.1002/ange.202002416.
[47] R. Zhang, P. Zhong, H. Arandiyan, Y. Guan, J. Liu, N. Wang, Y. Jiao, X. Fan, Using ultrasound to improve the sequential post-synthesis modification method for making mesoporous Y zeolites, Front. Chem. Sci. Eng. 14(2) (2020) 275-287.
[48] Z. Qin, J.-P. Gilson, V. Valtchev, Mesoporous zeolites by fluoride etching, Curr. Opin. Chem. Eng. 8(2015) 1-6.
[49] D. Verboekend, J. Pérez-Ramírez, Design of hierarchical zeolite catalysts by desilication, Catal. Sci. Technol. 1(6) (2011) 879-890.
[50] S.-T. Tsai, P.-Y. Chao, T.-C. Tsai, I. Wang, X. Liu, X.-W. Guo, Effects of pore structure of post-treated TS-1 on phenol hydroxylation, Catal. Today 148(1) (2009) 174-178.
[51] Y. Xue, Y. Xie, H. Wei, Y. Wen, X. Wang, B. Li, Improving the performance of TS-1 catalysts for continuous cyclohexanone ammoximation through controlment of active species distribution, New J. Chem. 38(9) (2014) 4229-4234.
[52] L. Xu, G. Lv, H. Li, Y. Shen, W. Cai, F. Wang, X. Zhang, Surface-modified TS-1 with enhanced activity for cyclohexanone ammoximation in a Pickering emulsion and increased stability in hot aqueous ammonia, RSC Adv. 5(77) (2015) 62652-62658.
[53] C.C. Pavel, W. Schmidt, Generation of hierarchical pore systems in the titanosilicate ETS-10 by hydrogen peroxide treatment under microwave irradiation, Chem. Commun. (8) (2006) 882-884.
[54] F. Thibault-Starzyk, I. Stan, S. Abelló, A. Bonilla, K. Thomas, C. Fernandez, J.-P. Gilson, J. Pérez-Ramírez, Quantification of enhanced acid site accessibility in hierarchical zeolites-the accessibility index, J. Catal. 264(1) (2009) 11-14.
[55] X. Chen, A. Vicente, Z. Qin, V. Ruaux, J.-P. Gilson, V. Valtchev, The preparation of hierarchical SAPO-34 crystals via post-synthesis fluoride etching, Chem. Commun. 52(17) (2016) 3512-3515.
[56] X. Chen, D. Xi, Q. Sun, N. Wang, Z. Dai, D. Fan, V. Valtchev, J. Yu, A top-down approach to hierarchical SAPO-34 zeolites with improved selectivity of olefin, Microporous Mesoporous Mater. 234(2016) 401-408.
[57] Z. Qin, L. Hafiz, Y. Shen, S. Daele, P. Boullay, V. Ruaux, S. Mintova, J.-P. Gilson, V. Valtchev, Defect-engineered zeolite porosity and accessibility, J. Mater. Chem. A 8(7) (2020) 3621-3631.
[58] Z. Qin, K. Cychosz, G. Melinte, H. El Siblani, J.-P. Gilson, M. Thommes, C. Fernandez, S. Mintova, O. Ersen, V. Valtchev, Opening the cages of Faujasite-type zeolite, J. Am. Chem. Soc. 139(48) (2017) 17273-17276.
[59] Z. Qin, G. Melinte, J.-P. Gilson, M. Jaber, K. Bozhilov, P. Boullay, S. Mintova, O. Ersen, V. Valtchev, The mosaic structure of zeolite crystals, Angew. Chem. Int. Ed. 128(48) (2016) 15273-15276.
[60] K.-G. Haw, S. Moldovan, L. Tang, Z. Qin, Q. Fang, S. Qiu, V. Valtchev, A sponge-like small pore zeolite with great accessibility to its micropores, Inorg. Chem. Front. 7(11) (2020) 2154-2159.
[61] K.-G. Haw, J.-P. Gilson, N. Nesterenko, M. Akouche, H. El Siblani, J.-M. Goupil, B. Rigaud, D. Minoux, J.-P. Dath, V. Valtchev, Supported embryonic zeolites and their use to process bulky molecules, ACS Catal. 8(9) (2018) 8199-8212.
[62] K.-G. Haw, J.-M. Goupil, J.-P. Gilson, N. Nesterenko, D. Minoux, J.-P. Dath, V. Valtchev, Embryonic ZSM-5 zeolites:Zeolitic materials with superior catalytic activity in 1,3,5-triisopropylbenzene dealkylation, New J. Chem. 40(5) (2016) 4307-4313.

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Baoyu Liu, Feng Xiong, Jianwen Zhang, Manna Wang, Yi Huang, Yanxiong Fang, Jinxiang Dong. Enhanced ortho-selective t–butylation of phenol over sulfonic acid functionalized mesopore MTW zeolites [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 1-7.
[2]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 205-211.
[3]	Mingzhi Li, Zhikai Liu, Wang Yao, Chao Xu, Yangping Yu, Mei Yang, Guangwen Chen. Ultrasonic cavitation-enabled microfluidic approach toward the continuous synthesis of cesium lead halide perovskite nanocrystals [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 32-41.
[4]	Haixiang Liu, Jun Zhang, Chunlei Dong, Gang Zhu, Guanben Du, Shuduan Deng. Synthesis, performance and structure characterization of glyoxal-monomethylolurea-melamine (G-MMU-M) co-condensed resin [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 92-104.
[5]	Yi Wu, Pengfei Song, Ningyan Li, Yanan Jiang, Yuan Liu. Molybdenum tailored Co⁰/Co²⁺ active pairs on a perovskite-type oxide for direct ethanol synthesis from syngas [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 279-289.
[6]	Yaqiao Liu, Shuozhen Hu, Xinsheng Zhang, Shigang Sun. Investigation of photoelectrocatalytic degradation mechanism of methylene blue by α-Fe₂O₃ nanorods array [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 162-172.
[7]	Kai Xue, Yanchun Xue, Jing Wang, Shuya Zhang, Xingmei Guo, Xiangjun Zheng, Fu Cao, Qinghong Kong, Junhao Zhang, Zhong Jin. KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 214-223.
[8]	Shuang Qiu, Yonghou Xiao, Haoran Wu, Shengnan Lu, Qidong Zhao, Gaohong He. One-pot synthesis of bimetallic CeCu-SAPO-34 for high-efficiency selective catalytic reduction of nitrogen oxides with NH₃ at low temperature [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 193-202.
[9]	Wufeng Wu, Xilu Hong, Jiang Fan, Yanying Wei, Haihui Wang. Research progress on the substrate for metal–organic framework (MOF) membrane growth for separation [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 299-313.
[10]	Lianlian Zhao, Fufu Di, Xiaonan Wang, Sumbal Farid, Suzhen Ren. Constructing a hollow core-shell structure of RuO₂ wrapped by hierarchical porous carbon shell with Ru NPs loading for supercapacitor [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 93-100.
[11]	Aiqin Gao, Xiang Luo, Huanghuang Chen, Aiqin Hou, Hongjuan Zhang, Kongliang Xie. Design of the reactive dyes containing large planar multi-conjugated systems and their application in non-aqueous dyeing [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 264-271.
[12]	Lijian Shi, Yaping Zhang, Yujia Tong, Wenlong Ding, Weixing Li. Plant-inspired biomimetic hybrid PVDF membrane co-deposited by tea polyphenols and 3-amino-propyl-triethoxysilane for high-efficiency oil-in-water emulsion separation [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 170-180.
[13]	Tengjie Wang, Wenkai Li, Xuehui Ge, Ting Qiu, Xiaoda Wang. Kinetics measurement of ethylene-carbonate synthesis via a fast transesterification by microreactors [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 243-250.
[14]	Xuan Gao, Zhihui Li, Dongsheng Zhang, Xinqiang Zhao, Yanji Wang. Synthesis and kinetics of 2,5-dicyanofuran in the presence of hydroxylamine ionic liquid salts [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 310-316.
[15]	Xin Yong, Hong Chen, Huawang Zhao, Miao Wei, Yingnan Zhao, Yongdan Li. Insight into SO₂ poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃ [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 184-193.