SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2022, Vol. 41 ›› Issue (1): 403-411.DOI: 10.1016/j.cjche.2021.10.022

• Catalysis, Kinetics and Reaction Engineering • Previous Articles     Next Articles

Surface plasmon resonance metal-coupled biomass carbon modified TiO2 nanorods for photoelectrochemical water splitting

Yingzhen Zhang1, Yonggang Lei1, Tianxue Zhu1, Zengxing Li1, Shen Xu1, Jianying Huang1,2, Xiao Li1,2, Weilong Cai1,2, Yuekun Lai1,2, Xiaojun Bao1,2   

  1. 1 National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou 350116, China;
    2 Fujian Science & Technology Innovation Laboratory for Chemical Engineering of China, Quanzhou 362114, China
  • Received:2021-07-01 Revised:2021-09-26 Online:2022-02-25 Published:2022-01-28
  • Contact: Jianying Huang,E-mail address:jyhuang@fzu.edu.cn;Yuekun Lai,E-mail address:yklai@fzu.edu.cn;Xiaojun Bao,E-mail address:baoxj@fzu.edu.cn
  • Supported by:
    The authors thank the National Natural Science Foundation of China (22075046, 51972063, 21501127 and 51502185), National Key Research and Development Program of China (2019YFE0111200), Natural Science Funds for Distinguished Young Scholar of Fujian Province (2020J06038), Natural Science Foundation of Fujian Province (2019J01256), and Overseas Expertise Introduction Project for Discipline Innovation (111 Project) (No. D17005).

Surface plasmon resonance metal-coupled biomass carbon modified TiO2 nanorods for photoelectrochemical water splitting

Yingzhen Zhang1, Yonggang Lei1, Tianxue Zhu1, Zengxing Li1, Shen Xu1, Jianying Huang1,2, Xiao Li1,2, Weilong Cai1,2, Yuekun Lai1,2, Xiaojun Bao1,2   

  1. 1 National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou 350116, China;
    2 Fujian Science & Technology Innovation Laboratory for Chemical Engineering of China, Quanzhou 362114, China
  • 通讯作者: Jianying Huang,E-mail address:jyhuang@fzu.edu.cn;Yuekun Lai,E-mail address:yklai@fzu.edu.cn;Xiaojun Bao,E-mail address:baoxj@fzu.edu.cn
  • 基金资助:
    The authors thank the National Natural Science Foundation of China (22075046, 51972063, 21501127 and 51502185), National Key Research and Development Program of China (2019YFE0111200), Natural Science Funds for Distinguished Young Scholar of Fujian Province (2020J06038), Natural Science Foundation of Fujian Province (2019J01256), and Overseas Expertise Introduction Project for Discipline Innovation (111 Project) (No. D17005).

Abstract: Exploring efficient and stable photoanode materials is a necessary link to realize the practical application of solar-driven photoelectrochemical (PEC) water splitting. Hence, we prepared rutile TiO2 nanorods, with a width of 50 nm, which was growth in situ on carbon cloth (TiO2@CC) by hydrothermal reaction. And then, Ag nanoparticles (NPs) and biomass N,S-C NPs were chosen for the additional modification of the fabricated TiO2 nanorods to produce broccoli-like Ag-N,S-C/TiO2@CC nanocomposites. According to the result of ultraviolet–visible diffuse reflectance spectroscopy (UV–vis) and PEC water splitting performance tests, Ag-N,S-C/TiO2@CC broadens the absorption region of TiO2@CC from the ultraviolet region to the visible region. Under AM 1.5G solar light irradiation, the photocurrent density of Ag-N,S-C/TiO2@CC is 89.8 μA·cm-2, which is 11.8 times higher than TiO2@CC. Under visible light irradiation, the photocurrent density of Ag-N,S-C/TiO2@CC reaches to 12.6 μA·cm-2, which is 21.0 times higher than TiO2@CC. Moreover, Ag-N,S-C/TiO2@CC shows a photocurrent responses in full pH range. It can be found that Ag NPs and N, S-C NPs play key roles in broaden the absorption range of TiO2 nanorods to the visible light region and, promote the occurrence of PEC water oxidation reaction due to the surface plasmon resonance effect of Ag NPs and the synergistic effect of N,S-C NPs. The mechanism demonstrated that Ag-N,S-C/TiO2@CC can separate the photogenerated electron-hole pairs effectively and transfer the photogenerated electrons to the photocathode (Pt plate) in time. This research provides a new strategy for exploration surface plasma metal coupled biomass carbon materials in the field of PEC water splitting.

Key words: Photoelectrochemical, Water oxidation, Ag-N,S-C/TiO2, Surface plasmon resonance, Biomass carbon

摘要: Exploring efficient and stable photoanode materials is a necessary link to realize the practical application of solar-driven photoelectrochemical (PEC) water splitting. Hence, we prepared rutile TiO2 nanorods, with a width of 50 nm, which was growth in situ on carbon cloth (TiO2@CC) by hydrothermal reaction. And then, Ag nanoparticles (NPs) and biomass N,S-C NPs were chosen for the additional modification of the fabricated TiO2 nanorods to produce broccoli-like Ag-N,S-C/TiO2@CC nanocomposites. According to the result of ultraviolet–visible diffuse reflectance spectroscopy (UV–vis) and PEC water splitting performance tests, Ag-N,S-C/TiO2@CC broadens the absorption region of TiO2@CC from the ultraviolet region to the visible region. Under AM 1.5G solar light irradiation, the photocurrent density of Ag-N,S-C/TiO2@CC is 89.8 μA·cm-2, which is 11.8 times higher than TiO2@CC. Under visible light irradiation, the photocurrent density of Ag-N,S-C/TiO2@CC reaches to 12.6 μA·cm-2, which is 21.0 times higher than TiO2@CC. Moreover, Ag-N,S-C/TiO2@CC shows a photocurrent responses in full pH range. It can be found that Ag NPs and N, S-C NPs play key roles in broaden the absorption range of TiO2 nanorods to the visible light region and, promote the occurrence of PEC water oxidation reaction due to the surface plasmon resonance effect of Ag NPs and the synergistic effect of N,S-C NPs. The mechanism demonstrated that Ag-N,S-C/TiO2@CC can separate the photogenerated electron-hole pairs effectively and transfer the photogenerated electrons to the photocathode (Pt plate) in time. This research provides a new strategy for exploration surface plasma metal coupled biomass carbon materials in the field of PEC water splitting.

关键词: Photoelectrochemical, Water oxidation, Ag-N,S-C/TiO2, Surface plasmon resonance, Biomass carbon