Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts

doi:10.1016/j.cjche.2021.12.027

Chinese Journal of Chemical Engineering ›› 2023, Vol. 53 ›› Issue (1): 381-401.DOI: 10.1016/j.cjche.2021.12.027

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Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts

Tianqi Fang¹, Mengyuan Liu¹, Zhaozhe Li¹, Li Xiong¹, Dongpei Zhang¹, Kexin Meng¹, Xiaolei Qu¹, Guangyu Zhang², Xin Jin¹, Chaohe Yang¹

1. State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum, Qingdao 266580, China;
2. Sinopec Research Institute of Safety Engineering, Qingdao 266580, China

Received:2021-08-15 Revised:2021-11-08 Online:2023-04-08 Published:2023-01-28
Contact: Xin Jin,E-mail:jamesjinxin@upc.edu.cn
Supported by:
The authors acknowledged the funds from National Natural Science Foundation of China (22078365, 21706290), Natural Science Foundation of Shandong Province (ZR2017MB004), Innovative Research Funding from Qingdao City, Shandong Province (17-1-1-80-jch), Fundamental Research Funds for the Central Universities and Development Fund of State Key Laboratory of Heavy Oil Processing (17CX02017A, 20CX02204A) and New Faculty Start-Up Funding from China University of Petroleum (YJ201601059).

Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts

Tianqi Fang¹, Mengyuan Liu¹, Zhaozhe Li¹, Li Xiong¹, Dongpei Zhang¹, Kexin Meng¹, Xiaolei Qu¹, Guangyu Zhang², Xin Jin¹, Chaohe Yang¹

1. State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum, Qingdao 266580, China;
2. Sinopec Research Institute of Safety Engineering, Qingdao 266580, China

通讯作者: Xin Jin,E-mail:jamesjinxin@upc.edu.cn
基金资助:
The authors acknowledged the funds from National Natural Science Foundation of China (22078365, 21706290), Natural Science Foundation of Shandong Province (ZR2017MB004), Innovative Research Funding from Qingdao City, Shandong Province (17-1-1-80-jch), Fundamental Research Funds for the Central Universities and Development Fund of State Key Laboratory of Heavy Oil Processing (17CX02017A, 20CX02204A) and New Faculty Start-Up Funding from China University of Petroleum (YJ201601059).

Abstract

Abstract: With increasing strict regulation on single-use plastics, lactic acid (LA) and alkyl lactates, as essential monomers for bio-degradable polylactic acid (PLA) plastic products, have gained worldwide attention in both academia and industry. While LA is still dominantly produced through fermentation processes from start, chemical synthesis from cellulosic biomass remains a grand challenge, owing to poor selectivity in activating C-H and C-C bonds in sugar molecules. To our best knowledge, recent publications have been focused on hydrothermal conversion of glucose to LA, while this review summarizes the highlights on direct thermal conversion of fructose as starting material to LA and derivatives. In particular, the synergies of metal/metal cations and acid/base catalysts will be critically revised on retro-aldol and dehydration reactions. This work will provide insights into rational design of active and selective catalysts for the production of carboxylic acids from biomass feedstocks.

Key words: Fructose, Lactic acid, Alkyl lactate, Thermal conversion

摘要： With increasing strict regulation on single-use plastics, lactic acid (LA) and alkyl lactates, as essential monomers for bio-degradable polylactic acid (PLA) plastic products, have gained worldwide attention in both academia and industry. While LA is still dominantly produced through fermentation processes from start, chemical synthesis from cellulosic biomass remains a grand challenge, owing to poor selectivity in activating C-H and C-C bonds in sugar molecules. To our best knowledge, recent publications have been focused on hydrothermal conversion of glucose to LA, while this review summarizes the highlights on direct thermal conversion of fructose as starting material to LA and derivatives. In particular, the synergies of metal/metal cations and acid/base catalysts will be critically revised on retro-aldol and dehydration reactions. This work will provide insights into rational design of active and selective catalysts for the production of carboxylic acids from biomass feedstocks.

关键词: Fructose, Lactic acid, Alkyl lactate, Thermal conversion

Tianqi Fang, Mengyuan Liu, Zhaozhe Li, Li Xiong, Dongpei Zhang, Kexin Meng, Xiaolei Qu, Guangyu Zhang, Xin Jin, Chaohe Yang. Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts[J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 381-401.

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Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts

Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts

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