Synthesis methods and powder quality of titanium monocarbide

doi:10.1016/j.cjche.2024.03.019

Chinese Journal of Chemical Engineering ›› 2024, Vol. 72 ›› Issue (8): 10-18.DOI: 10.1016/j.cjche.2024.03.019

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Synthesis methods and powder quality of titanium monocarbide

Maoqiao Xiang^1,2, Wenjun Ding^1,2, Qinghua Dong^1,2, Qingshan Zhu^1,2,3

1 State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Chemical Engineering, University of the Chinese Academy of Sciences, Beijing 100049, China;
3 Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China

Received:2023-11-26 Revised:2024-02-22 Online:2024-10-17 Published:2024-08-28
Contact: Qingshan Zhu,E-mail:qszhu@ipe.ac.cn
Supported by:
This work was supported by Basic Frontier Scientific Research of the Chinese Academy of Sciences (ZDBS-LY-JSC041), the National Natural Science Foundation of China (22178348), the open research fund of the State Key Laboratory of Mesoscience and Engineering (MESO-23-D06), and the Youth Innovation Promotion Association CAS (292021000085).

Synthesis methods and powder quality of titanium monocarbide

Maoqiao Xiang^1,2, Wenjun Ding^1,2, Qinghua Dong^1,2, Qingshan Zhu^1,2,3

1 State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Chemical Engineering, University of the Chinese Academy of Sciences, Beijing 100049, China;
3 Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China

通讯作者: Qingshan Zhu,E-mail:qszhu@ipe.ac.cn
基金资助:
This work was supported by Basic Frontier Scientific Research of the Chinese Academy of Sciences (ZDBS-LY-JSC041), the National Natural Science Foundation of China (22178348), the open research fund of the State Key Laboratory of Mesoscience and Engineering (MESO-23-D06), and the Youth Innovation Promotion Association CAS (292021000085).

Abstract

Abstract: Titanium monocarbide (TiC), which is the most stable titanium-based carbide, has attracted considerable interest in the fields of energy, catalysis, and structural materials due to its excellent properties. Synthesis of high-quality TiC powders with low cost and high efficiency is crucial for industrial applications; however major challenges face its realization. Herein, the methods for synthesizing TiC powders based on a reaction system are reviewed. This analysis is focused on the underlying mechanisms by which synthesis methods affect the quality of powders. Notably, strategies for improving the synthesis of high-quality powders are analyzed from the perspective of enhancing heat and mass transfer processes. Furthermore, the critical issues, challenges, and development trends of the synthesis technology and application of high-quality TiC powder are discussed.

Key words: Titanium carbide, Synthesis methods, Reaction engineering, Reaction kinetics, Powder technology

摘要： Titanium monocarbide (TiC), which is the most stable titanium-based carbide, has attracted considerable interest in the fields of energy, catalysis, and structural materials due to its excellent properties. Synthesis of high-quality TiC powders with low cost and high efficiency is crucial for industrial applications; however major challenges face its realization. Herein, the methods for synthesizing TiC powders based on a reaction system are reviewed. This analysis is focused on the underlying mechanisms by which synthesis methods affect the quality of powders. Notably, strategies for improving the synthesis of high-quality powders are analyzed from the perspective of enhancing heat and mass transfer processes. Furthermore, the critical issues, challenges, and development trends of the synthesis technology and application of high-quality TiC powder are discussed.

关键词: Titanium carbide, Synthesis methods, Reaction engineering, Reaction kinetics, Powder technology

Maoqiao Xiang, Wenjun Ding, Qinghua Dong, Qingshan Zhu. Synthesis methods and powder quality of titanium monocarbide[J]. Chinese Journal of Chemical Engineering, 2024, 72(8): 10-18.

Maoqiao Xiang, Wenjun Ding, Qinghua Dong, Qingshan Zhu. Synthesis methods and powder quality of titanium monocarbide[J]. 中国化学工程学报, 2024, 72(8): 10-18.

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Synthesis methods and powder quality of titanium monocarbide

Synthesis methods and powder quality of titanium monocarbide

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[3]	Shida Gao, Cuimei Bo, Chao Jiang, Quanling Zhang, Genke Yang, Jian Chu. Hybrid modeling for carbon monoxide gas-phase catalytic coupling to synthesize dimethyl oxalate process [J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 234-250.
[4]	Shen Li, Yin-Ning Zhou, Zhong-Xin Liu, Zheng-Hong Luo. Effect of solvent on the initiation mechanism of living anionic polymerization of styrene: A computational study [J]. Chinese Journal of Chemical Engineering, 2024, 69(5): 135-142.
[5]	Jiangtao Cai, Qingfu Huang, Huan Chen, Tao Zhang, Bo Niu, Yayun Zhang, Donghui Long. Evaluating two stages of silicone-containing arylene resin oxidation via experiment and molecular simulation [J]. Chinese Journal of Chemical Engineering, 2024, 66(2): 189-202.
[6]	Xinyu Liu, Hongliang Sheng, Song He, Chunhua Du, Yuansheng Ma, Chichi Ruan, Chunxiang He, Huaming Dai, Yajun Huang, Yuelei Pan. Insight into pyrolysis of hydrophobic silica aerogels: Kinetics, reaction mechanism and effect on the aerogels [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 266-281.
[7]	Xianglin Liu, Minjie Xu, Chenxi Cao, Zixu Yang, Jing Xu. Effects of zinc on χ-Fe₅C₂ for carbon dioxide hydrogenation to olefins: Insights from experimental and density function theory calculations [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 206-214.
[8]	Yu-Gao Wang, Xiao-Chen Han, Bao Gu, Hua-Shuai Wu, Jun Shen. Insight into the green route to dimethyl succinate by direct esterification of bio-based disodium succinate using CO₂ and CH₃OH [J]. Chinese Journal of Chemical Engineering, 2023, 64(12): 188-195.
[9]	Zhiwei Wang, Yu Zhang, Zhi Zhang, Daowei Zhou, Zhikai Cao, Yong Sha. Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 63-72.
[10]	Yingjie Song, Shuqi Zhong, Yingjiao Li, Kun Dong, Yong Luo, Guangwen Chu, Haikui Zou, Baochang Sun. Study on the catalytic degradation of sodium lignosulfonate to aromatic aldehydes over nano-CuO: Process optimization and reaction kinetics [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 300-309.
[11]	Hongbo Song, Wei Wang, Jiachen Sun, Xianhui Wang, Xianhua Zhang, Sai Chen, Chunlei Pei, Zhi-Jian Zhao. Chemical looping oxidative propane dehydrogenation controlled by oxygen bulk diffusion over FeVO₄ oxygen carrier pellets [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 409-420.
[12]	Kai Zhang, Fangming Xue, Zhiqiang Wang, Xingxing Cheng. Research on prediction model of formation temperature of ammonium bisulfate in air preheater of coal-fired power plant [J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 202-210.
[13]	Hualiang An, Rui Wang, Wenhao Wang, Daolai Sun, Xinqiang Zhao, Yanji Wang. A core–shell Ni/SiO₂@TiO₂ catalyst for highly selective one-step synthesis of 2-propylheptanol from n-pentanal [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 104-112.
[14]	N. M'hanni, T. Anik, R. Touir, M. Galai, M. Ebn Touhami, E.H. Rifi, Z. Asfari, S. Bakkali. Effect of additives on nickel-phosphorus deposition obtained by electroless plating: Characterization and corrosion resistance in 3%(mass) sodium chloride medium [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 341-350.
[15]	Cao Kuang, Shuzhong Wang, Ming Luo, Jun Zhao. Reactivity study and kinetic evaluation of CuO-based oxygen carriers modified by three different ores in chemical looping with oxygen uncoupling (CLOU) process [J]. Chinese Journal of Chemical Engineering, 2021, 37(9): 54-63.