SCI和EI收录∣中国化工学会会刊

Chin.J.Chem.Eng. ›› 2013, Vol. 21 ›› Issue (9): 1007-1014.DOI: 10.1016/S1004-9541(13)60573-X

Previous Articles     Next Articles

A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

Abolfazl Gharibi Kharaji1, Ahmad Shariati1, Mohammad Ali Takassi2   

  1. 1 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Chemical Engineering Department, Ahwaz, Iran;
    2 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Science Department, Ahwaz, Iran
  • Received:2012-01-21 Revised:2012-06-03 Online:2013-10-01 Published:2013-09-28
  • Contact: Ahmad Shariati
  • Supported by:

    Supported by the Iranian Nano Technology Initiative Council and Petroleum University of Technology

A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

Abolfazl Gharibi Kharaji1, Ahmad Shariati1, Mohammad Ali Takassi2   

  1. 1 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Chemical Engineering Department, Ahwaz, Iran;
    2 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Science Department, Ahwaz, Iran
  • 通讯作者: Ahmad Shariati
  • 基金资助:

    Supported by the Iranian Nano Technology Initiative Council and Petroleum University of Technology

Abstract: In reverse water gas shift (RWGS) reaction CO2 is converted to CO which in turn can be used to produce beneficial chemicals such as methanol. In the present study, Mo/Al2O3, Fe/Al2O3 and Fe-Mo/Al2O3 catalysts were synthesised using impregnation method. The structures of catalysts were studied using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) method, inductively coupled plasma atomic emission spectrometer (ICP-AES), temperature programmed reduction (H2-TPR), CO chemisorption, energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. Kinetic properties of all catalysts were investigated in a batch reactor for RWGS reaction. The results indicated that Mo existence in structure of Fe-Mo/Al2O3 catalyst enhances its activity as compared to Fe/Al2O3. This enhancement is probably due to better Fe dispersion and smaller particle size of Fe species. Stability test of Fe-Mo/Al2O3 catalyst was carried out in a fixed bed reactor and a high CO yield for 60 h of time on stream was demonstrated. Fe2(MoO4)3 phase was found in the structures of fresh and used catalysts. TPR results also indicate that Fe2(MoO4)3 phase has low reducibility, therefore the Fe2(MoO4)3 phase significantly inhibits the reduction of the remaining Fe oxides in the catalyst, resulted in high stability of Fe-Mo/Al2O3 catalyst. Overall, this study introduces Fe-Mo/Al2O3 as a novel catalyst with high CO yield, almost no by-products and fairly stable for RWGS reaction.

Key words: reverse water gas shift reaction, Fe-Mo/Al2O3 catalyst, selectivity, stability, reducibility

摘要: In reverse water gas shift (RWGS) reaction CO2 is converted to CO which in turn can be used to produce beneficial chemicals such as methanol. In the present study, Mo/Al2O3, Fe/Al2O3 and Fe-Mo/Al2O3 catalysts were synthesised using impregnation method. The structures of catalysts were studied using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) method, inductively coupled plasma atomic emission spectrometer (ICP-AES), temperature programmed reduction (H2-TPR), CO chemisorption, energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. Kinetic properties of all catalysts were investigated in a batch reactor for RWGS reaction. The results indicated that Mo existence in structure of Fe-Mo/Al2O3 catalyst enhances its activity as compared to Fe/Al2O3. This enhancement is probably due to better Fe dispersion and smaller particle size of Fe species. Stability test of Fe-Mo/Al2O3 catalyst was carried out in a fixed bed reactor and a high CO yield for 60 h of time on stream was demonstrated. Fe2(MoO4)3 phase was found in the structures of fresh and used catalysts. TPR results also indicate that Fe2(MoO4)3 phase has low reducibility, therefore the Fe2(MoO4)3 phase signifificantly inhibits the reduction of the remaining Fe oxides in the catalyst, resulted in high stability of Fe-Mo/Al2O3 catalyst. Overall, this study introduces Fe-Mo/Al2O3 as a novel catalyst with high CO yield, almost no by-products and fairly stable for RWGS reaction.

关键词: reverse water gas shift reaction, Fe-Mo/Al2O3 catalyst, selectivity, stability, reducibility