The selective adsorption of rare earth elements by modified coal fly ash based SBA-15

doi:10.1016/j.cjche.2021.07.033

Chinese Journal of Chemical Engineering ›› 2022, Vol. 47 ›› Issue (7): 155-164.DOI: 10.1016/j.cjche.2021.07.033

Previous Articles Next Articles

The selective adsorption of rare earth elements by modified coal fly ash based SBA-15

Jinglei Cui, Qian Wang, Jianming Gao, Yanxia Guo, Fangqin Cheng

State Environmental Protection Key Laboratory of Efficient Resource Utilization Techniques of Coal Waste, Institute of Resources and Environmental Engineering, Shanxi Collaborative Innovation Center of High Value-added Utilization of Coal-related Wastes, Shanxi University, Taiyuan 030006, China

Received:2021-03-27 Revised:2021-07-26 Online:2022-08-19 Published:2022-07-28
Contact: Jinglei Cui,E-mail:cuijl@sxu.edu.cn;Yanxia Guo,E-mail:guoyx@sxu.edu.cn
Supported by:
The authors gratefully thanks for the National Natural Science Foundation of China (U1810205), Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2020L0022), Key Research and Development Program of Shanxi Province (201903D311006).

The selective adsorption of rare earth elements by modified coal fly ash based SBA-15

Jinglei Cui, Qian Wang, Jianming Gao, Yanxia Guo, Fangqin Cheng

State Environmental Protection Key Laboratory of Efficient Resource Utilization Techniques of Coal Waste, Institute of Resources and Environmental Engineering, Shanxi Collaborative Innovation Center of High Value-added Utilization of Coal-related Wastes, Shanxi University, Taiyuan 030006, China

通讯作者: Jinglei Cui,E-mail:cuijl@sxu.edu.cn;Yanxia Guo,E-mail:guoyx@sxu.edu.cn
基金资助:
The authors gratefully thanks for the National Natural Science Foundation of China (U1810205), Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2020L0022), Key Research and Development Program of Shanxi Province (201903D311006).

Abstract

Abstract: Rare earth elements (REE) are strategic resources and the recycling of REE in alternative resources is urgent and gets increasingly attention. However, the separation of REE in these alternative resources is still a challenge due to the low concentration of REE and multi coexisted ions in acidic system. In this study, the species distribution of REE within the pH 0-8.0 was calculated. The SBA-15 originated from coal fly ash was modified by two steps with (3-aminopropyl) triethoxysilane (APTES) and diethylenetriaminepentaacetic dianhydride (DTPADA) to obtain DTPADA-SBA-15 adsorbent, which was applied to the selective adsorption of REE. The results showed that DTPADA-SBA-15 possessed excellent adsorption performance on the selective adsorption of REE, including Eu, Gd, Tb, Nd and Sm, in acidic solution (pH 2) with multi competing ions. The FT-IR and Zeta potential characterization verified that the chemical adsorption through the coordination of O in DTPADA-SBA-15 with REE was dominant at lower pH value. The study of adsorption kinetics indicated that the adsorption of rare earth metal ions followed pseudo-second-order kinetic, of which the adsorption process followed the Langmuir isotherm model.

Key words: Rare earth elements, Selective adsorption, SBA-15, Modification

摘要： Rare earth elements (REE) are strategic resources and the recycling of REE in alternative resources is urgent and gets increasingly attention. However, the separation of REE in these alternative resources is still a challenge due to the low concentration of REE and multi coexisted ions in acidic system. In this study, the species distribution of REE within the pH 0-8.0 was calculated. The SBA-15 originated from coal fly ash was modified by two steps with (3-aminopropyl) triethoxysilane (APTES) and diethylenetriaminepentaacetic dianhydride (DTPADA) to obtain DTPADA-SBA-15 adsorbent, which was applied to the selective adsorption of REE. The results showed that DTPADA-SBA-15 possessed excellent adsorption performance on the selective adsorption of REE, including Eu, Gd, Tb, Nd and Sm, in acidic solution (pH 2) with multi competing ions. The FT-IR and Zeta potential characterization verified that the chemical adsorption through the coordination of O in DTPADA-SBA-15 with REE was dominant at lower pH value. The study of adsorption kinetics indicated that the adsorption of rare earth metal ions followed pseudo-second-order kinetic, of which the adsorption process followed the Langmuir isotherm model.

关键词: Rare earth elements, Selective adsorption, SBA-15, Modification

Jinglei Cui, Qian Wang, Jianming Gao, Yanxia Guo, Fangqin Cheng. The selective adsorption of rare earth elements by modified coal fly ash based SBA-15[J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 155-164.

Jinglei Cui, Qian Wang, Jianming Gao, Yanxia Guo, Fangqin Cheng. The selective adsorption of rare earth elements by modified coal fly ash based SBA-15[J]. 中国化学工程学报, 2022, 47(7): 155-164.

References

[1] T. Kegl, A. Košak, A. Lobnik, Z. Novak, A.K. Kralj, I. Ban, Adsorption of rare earth metals from wastewater by nanomaterials:A review, J Hazard Mater 386(2020)121632
[2] A. Golev, M. Scott, P.D. Erskine, S.H. Ali, G.R. Ballantyne, Rare earths supply chains:Current status, constraints and opportunities, Resour. Policy 41(2014)52-59
[3] N. Haque, A. Hughes, S. Lim, C. Vernon, Rare earth elements:Overview of mining, mineralogy, uses, sustainability and environmental impact, Resources 3(4)(2014)614-635
[4] Z.B. Ma, S. Zhang, H.R. Zhang, F.Q. Cheng, Novel extraction of valuable metals from circulating fluidized bed-derived high-alumina fly ash by acid-alkali-based alternate method, J. Clean. Prod. 230(2019)302-313
[5] H. Javadian, M. Ruiz, T.A. Saleh, A.M. Sastre, Ca-alginate/carboxymethyl chitosan/Ni_0.2Zn_0.2Fe_2.6O₄ magnetic bionanocomposite:Synthesis, characterization and application for single adsorption of Nd+3, Tb+3, and Dy+3 rare earth elements from aqueous media, J. Mol. Liq. 306(2020)112760
[6] Z.W. Guo, Q. Li, Z.Y. Li, C. Liu, X.R. Liu, Y.Y. Liu, G.L. Dong, T. Lan, Y. Wei, Fabrication of efficient alginate composite beads embedded with N-doped carbon dots and their application for enhanced rare earth elements adsorption from aqueous solutions, J. Colloid Interface Sci. 562(2020)224-234
[7] R.G. Silva, C.A. Morais, É.D. Oliveira, Selective precipitation of rare earth from non-purified and purified sulfate liquors using sodium sulfate and disodium hydrogen phosphate, Miner. Eng. 134(2019)402-416
[8] C. Tunsu, Y. Menard, D.Ø. Eriksen, C. Ekberg, M. Petranikova, Recovery of critical materials from mine tailings:A comparative study of the solvent extraction of rare earths using acidic, solvating and mixed extractant systems, J. Clean. Prod. 218(2019)425-437
[9] F. H. Spedding, E. I. Fulmer, T. A. Butler, E. M. Gladrow, M. Gobush, P. E. Porter, J. E. Powell, J. M. Wright, The Separation of Rare Earths by Ion Exchange. 1 III. Pilot Plant Scale Separations, J. Am. Chem. Soc. 69(1947)2812-2818
[10] M.Y.M. Abdelrahim, H.H. Osman, S. Cerneaux, N. Masquelez, M. Barboiu, Extraction and membrane transport of lanthanides with dynameric constitutional framework carriers, J. Membr. Sci. 510(2016)50-57
[11] Liu WS, Wu LL, Zheng MY, Chao YQ, Zhao CM, Zhong X, Ding KB, Huot H, Zhang MY, Tang YT, Li C, Qiu RL, Controls on rare-earth element transport in a river impacted by ion-adsorption rare-earth mining, Sci Total Environ 660(2019)697-704
[12] C.H. Wang, X.L. Liu, N. Keser Demir, J.P. Chen, K. Li, Applications of water stable metal-organic frameworks, Chem. Soc. Rev. 45(18)(2016)5107-5134
[13] F. Wang, W.B. Wang, Y.F. Zhu, A.Q. Wang, Evaluation of Ce (III) and Gd (III) adsorption from aqueous solution using CTS-g-(AA-co-SS)/ISC hybrid hydrogel adsorbent, J. Rare Earths 35(7)(2017)697-708
[14] Z.N. Lou, X. Xiao, M.N. Huang, Y.J. Wang, Z.Q. Xing, Y. Xiong, Acrylic acid-functionalized metal-organic frameworks for Sc (III) selective adsorption, ACS Appl Mater Interfaces 11(12)(2019)11772-11781
[15] X.Q. Sun, H.M. Luo, S.M. Mahurin, R. Liu, X.S. Hou, S. Dai, Adsorption of rare earth ions using carbonized polydopamine nano carbon shells, J. Rare Earths 34(1)(2016)77-82
[16] X. Xu, J. Zou, J. Teng, Q. Liu, X.Y. Jiang, F.P. Jiao, J.G. Yu, X.Q. Chen, Novel high-gluten flour physically cross-linked graphene oxide composites:Hydrothermal fabrication and adsorption properties for rare earth ions, Ecotoxicol Environ Saf 166(2018)1-10
[17] Y.M. Hu, L.C. Misal Castro, E. Drouin, J. Florek, H. Kählig, D. Larivière, F. Kleitz, F.G. Fontaine, Size-selective separation of rare earth elements using functionalized mesoporous silica materials, ACS Appl Mater Interfaces 11(26)(2019)23681-23691
[18] E. Juère, J. Florek, D. Larivière, K. Kim, F. Kleitz, Support effects in rare earth element separation using diglycolamide-functionalized mesoporous silica, New J. Chem. 40(5)(2016)4325-4334
[19] J. Shusterman, H. Mason, A. Bruchet, M. Zavarin, A.B. Kersting, H. Nitsche, Analysis of trivalent cation complexation to functionalized mesoporous silica using solid-state NMR spectroscopy, Dalton Trans 43(44)(2014)16649-16658
[20] S.M. Ali, S. Pahan, A. Bhattacharyya, P.K. Mohapatra, Complexation thermodynamics of diglycolamide with f-elements:Solvent extraction and density functional theory analysis, Phys Chem Chem Phys 18(14)(2016)9816-9828
[21] J. Florek, D. Larivière, H. Kählig, S.L. Fiorilli, B. Onida, F.G. Fontaine, F. Kleitz, Understanding selectivity of mesoporous silica-grafted diglycolamide-type ligands in the solid-phase extraction of rare earths, ACS Appl Mater Interfaces 12(51)(2020)57003-57016
[22] J.C. Callura, K.M. Perkins, C.W. Noack, N.R. Washburn, D.A. Dzombak, A.K. Karamalidis, Selective adsorption of rare earth elements onto functionalized silica particles, Green Chem. 20(7)(2018)1515-1526
[23] Q. Gao, J.F. Xie, Y.T. Shao, C. Chen, B. Han, K.S. Xia, C.G. Zhou, Ultrafast and high-capacity adsorption of Gd (III) onto inorganic phosphorous acid modified mesoporous SBA-15, Chem. Eng. J. 313(2017)197-206
[24] R. Ashour, M. Samouhos, E. Polido Legaria, M. Svärd, J. Högblom, K. Forsberg, M. Palmlöf, V.G. Kessler, G.A. Seisenbaeva, Å.C. Rasmuson, DTPA-functionalized silica nano-and microparticles for adsorption and chromatographic separation of rare earth elements, ACS Sustain. Chem. Eng. 6(5)(2018)6889-6900
[25] D.Y. Zhao, J.Y. Sun, Q.Z. Li, G.D. Stucky, Morphological control of highly ordered mesoporous silica SBA-15, Chem. Mater. 12(2)(2000)275-279
[26] M. Kruk, M. Jaroniec, C.H. Ko, R. Ryoo, Characterization of the porous structure of SBA-15, Chem. Mater. 12(7)(2000)1961-1968
[27] E. P. Legaria, M. Samouhos, V. G. Kessler, G. A. Seisenbaeva, Toward molecular recognition of REEs:Comparative analysis of hybrid nanoadsorbents with the different complexonate ligands EDTA, DTPA, and TTHA, Inorg. Chem. 56(2017)13938-13948
[28] C.W. Noack, K.M. Perkins, J.C. Callura, N.R. Washburn, D.A. Dzombak, A.K. Karamalidis, Effects of ligand chemistry and geometry on rare earth element partitioning from saline solutions to functionalized adsorbents, ACS Sustainable Chem. Eng. 4(11)(2016)6115-6124
[29] D.D. Shi, K.G. Haw, C. Kouvatas, L.X. Tang, Y.Y. Zhang, Q.R. Fang, S.L. Qiu, V. Valtchev, Expanding the synthesis field of high-silica zeolites, Angew Chem Int Ed Engl 59(44)(2020)19576-19581
[30] G.X. Tian, L.R. Martin, Z.Y. Zhang, L.F. Rao, Thermodynamic, spectroscopic, and computational studies of lanthanide complexation with diethylenetriaminepentaacetic acid:Temperature effect and coordination modes, Inorg. Chem. 50(7)(2011)3087-3096
[31] J.H. Pan, T.C. Nie, B. Vaziri Hassas, M. Rezaee, Z.P. Wen, C.C. Zhou, Recovery of rare earth elements from coal fly ash by integrated physical separation and acid leaching, Chemosphere 248(2020)126112
[32] L.J. Wang, Y. Wang, L. Cui, J.M. Gao, Y.X. Guo, F.Q. Cheng, A sustainable approach for advanced removal of iron from CFA sulfuric acid leach liquor by solvent extraction with P507, Sep. Purif. Technol. 251(2020)117371
[33] Park S, Kim M, Lim Y, Yu J, Chen S, Woo SW, Yoon S, Bae S, Kim HS, Characterization of rare earth elements present in coal ash by sequential extraction, J Hazard Mater 402(2021)123760
[34] J.H. Pan, B.V. Hassas, M. Rezaee, C.C. Zhou, S.V. Pisupati, Recovery of rare earth elements from coal fly ash through sequential chemical roasting, water leaching, and acid leaching processes, J. Clean. Prod. 284(2021)124725
[35] R. Cejnar, K. Hložková, L. Jelínek, P. Kotrba, P. Dostálek, Development of engineered yeast for biosorption of beer haze-active polyphenols, Appl. Microbiol. Biotechnol. 101(4)(2017)1477-1485
[36] S.S. Dubey, S. Grandhi, Sorption studies of yttrium (III) ions on nano maghemite, J. Environ. Chem. Eng. 4(4)(2016)4719-4730
[37] D.M. Park, D.W. Reed, M.C. Yung, A. Eslamimanesh, M.M. Lencka, A. Anderko, Y. Fujita, R.E. Riman, A. Navrotsky, Y.Q. Jiao, Bioadsorption of rare earth elements through cell surface display of lanthanide binding tags, Environ Sci Technol 50(5)(2016)2735-2742
[38] C.Y. Yu, X.D. Sun, L.F. Zou, G.H. Li, L.R. Zhang, Y.L. Liu, A pillar-layered Zn-LMOF with uncoordinated carboxylic acid sites:High performance for luminescence sensing Fe³⁺and TNP, Inorg Chem 58(6)(2019)4026-4032
[39] B. Wang, L.M. Liao, Q.H. Huang, Y.X. Cheng, Adsorption behaviors of benzonic acid by carboxyl methyl konjac glucomannan gel micropheres cross-linked with Fe³⁺, J. Chem. Eng. Data 57(1)(2012)72-77
[40] U. Habiba, A.M. Afifi, A. Salleh, B.C. Ang, Chitosan/(polyvinyl alcohol)/zeolite electrospun composite nanofibrous membrane for adsorption of Cr⁶⁺, Fe³⁺and Ni²⁺, J. Hazard. Mater. 322(2017)182-194
[41] D.B. Wu, Y.H. Sun, Q.G. Wang, Adsorption of lanthanum (III) from aqueous solution using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester-grafted magnetic silica nanocomposites, J Hazard Mater 260(2013)409-419
[42] D.L. Ramasamy, V. Puhakka, E. Repo, S. Khan, M. Sillanpää, Coordination and silica surface chemistry of lanthanides (III), scandium (III) and yttrium (III) sorption on 1-(2-pyridylazo)-2-napththol (PAN) and acetylacetone (acac) immobilized gels, Chem. Eng. J. 324(2017)104-112
[43] D.G. Liu, Z.H. Li, W. Li, Z.R. Zhong, J.Q. Xu, J.J. Ren, Z.S. Ma, Adsorption behavior of heavy metal ions from aqueous solution by soy protein hollow microspheres, Ind. Eng. Chem. Res. 52(32)(2013)11036-11044
[44] X.M. Liu, X.X. Qiu, X. Sun, L.B. Mei, L.Y. Wang, Q.J. Guo, Preparation and kinetic study of organic amine-loaded ion-exchange resin as CO₂ adsorbents, Environ. Prog. Sustainable Energy 40(1)(2021) e13476. https://doi.org/10.1002/ep.13476
[45] S. Iftekhar, V. Srivastava, M. Sillanpää, Enrichment of lanthanides in aqueous system by cellulose based silica nanocomposite, Chem. Eng. J. 320(2017)151-159
[46] P.R. Yaashikaa, P.S. Kumar, A. Saravanan, Modeling and Cr (VI) ion uptake kinetics of Sorghum bicolor plant assisted by plant growth-promoting Pannonibacter phragmetitus:An ecofriendly approach, Environ Sci Pollut Res Int 27(22)(2020)27307-27318
[47] Y.M. Hu, E. Drouin, D. Larivière, F. Kleitz, F.G. Fontaine, Highly efficient and selective recovery of rare earth elements using mesoporous silica functionalized by preorganized chelating ligands, ACS Appl Mater Interfaces 9(44)(2017)38584-38593
[48] R.M. Ashour, R. El-Sayed, A.F. Abdel-Magied, A.A. Abdel-Khalek, M.M. Ali, K. Forsberg, A. Uheida, M. Muhammed, J. Dutta, Selective separation of rare earth ions from aqueous solution using functionalized magnetite nanoparticles:Kinetic and thermodynamic studies, Chem. Eng. J. 327(2017)286-296

The selective adsorption of rare earth elements by modified coal fly ash based SBA-15

The selective adsorption of rare earth elements by modified coal fly ash based SBA-15

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles 0

Metrics

Comments

[1]	Suhang Jiang, Lijuan Tan, Yujia Tong, Lijian Shi, Weixing Li. A heterogeneous double chamber electro-Fenton with high production of H₂O₂ using La–CeO₂ modified graphite felt as cathode [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 98-105.
[2]	Xiaodong Yang, Na Yang, Ziqiang Gong, Feifei Peng, Bin Jiang, Yongli Sun, Luhong Zhang. The superhydrophobic sponge decorated with Ni-Co double layered oxides with thiol modification for continuous oil/water separation [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 296-305.
[3]	Eid H. Alosaimi, Ibrahim Hotan Alsohaimi, Hassan M.A. Hassan, Qiao Chen, Saad Melhi, Ayman Abdelaziz Younes. Towards superior permeability and antifouling performance of sulfonated polyethersulfone ultrafiltration membranes modified with sulfopropyl methacrylate functionalized SBA-15 [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 89-100.
[4]	Lu Lv, Min Zhao, Yanan Liu, Yufei He, Dianqing Li. Fabrication of hydrophobic Pd/Al₂O₃-phosphoric acid via P-O-Al bond for liquid hydrogenation reaction [J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 232-242.
[5]	Ting He, Songhong Yu, Jinhui He, Dejian Chen, Jie Li, Hongjun Hu, Xingrui Zhong, Yawei Wang, Zhaohui Wang, Zhaoliang Cui. Membranes for extracorporeal membrane oxygenator (ECMO): History, preparation, modification and mass transfer [J]. Chinese Journal of Chemical Engineering, 2022, 49(9): 46-75.
[6]	Linyang Wang, Qiang Wang, Yongqi Liu, Qiuxiang Yao, Ming Sun, Xiaoxun Ma. Catalytic conversion of asphaltenes to BTXN using metal-loaded modified HZSM-5 [J]. Chinese Journal of Chemical Engineering, 2022, 49(9): 253-264.
[7]	Lei Zhou, Lingling Peng, Xingbang Hu. Hydrogenation of CO₂ to formate catalyzed by SBA-15-supported cyclic (alkyl)(amino)carbene-iridium [J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 283-291.
[8]	Dongqi An, Yuyao Yang, Weixin Zou, Yandi Cai, Qing Tong, Jingfang Sun, Lin Dong. Insight into the promotional mechanism of Cu modification towards wide-temperature NH₃-SCR performance of NbCe catalyst [J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 301-309.
[9]	Chen Zhao, Yahan Ye, Xianfu Chen, Xiaowei Da, Minghui Qiu, Yiqun Fan. Charged modified tight ceramic ultrafiltration membranes for treatment of cationic dye wastewater [J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 267-277.
[10]	Shiyue Li, Shouying Huang, Kai Cai, Ying Li, Jing Lv, Xinbin Ma. Importance of metal location in M-H zeolite for synergistically catalyzing dimethyl ether carbonylation [J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 350-357.
[11]	Hang Yao, Yuwei He, Jinrong Ma, Lang Jiang, Jingan Li, Jin Wang, Nan Huang. Recent advances in cardiovascular stent for treatment of in-stent restenosis: Mechanisms and strategies [J]. Chinese Journal of Chemical Engineering, 2021, 37(9): 12-29.
[12]	Chunxiao Zhang, Yingjie Li, Zhiguo Bian, Wan Zhang, Zeyan Wang. Simultaneous CO₂ capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)₂ cycles [J]. Chinese Journal of Chemical Engineering, 2021, 36(8): 76-85.
[13]	Qingpeng Cheng, Yunhao Liu, Shuaishuai Lyu, Ye Tian, Qingxiang Ma, Xingang Li. Manipulating metal-support interactions of metal catalysts for Fischer-Tropsch synthesis [J]. Chinese Journal of Chemical Engineering, 2021, 35(7): 220-230.
[14]	Yongqi Liu, Qiuxiang Yao, Ming Sun, Xiaoxun Ma. Selective preparation of light aromatic hydrocarbons from catalytic fast pyrolysis vapors of coal tar asphaltene over transition metal ion modified zeolites [J]. Chinese Journal of Chemical Engineering, 2021, 35(7): 275-287.
[15]	Zhibin Deng, Xing Ge, Wenting Zhang, Shizhong Luo, Jun Shen, Fangli Jing, Wei Chu. Oxidative dehydrogenation of ethane with carbon dioxide over silica molecular sieves supported chromium oxides: Pore size effect [J]. Chinese Journal of Chemical Engineering, 2021, 34(6): 77-86.