Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe2O4 supported 0D carbon dots with up-conversion property

doi:10.1016/j.cjche.2021.11.026

Chinese Journal of Chemical Engineering ›› 2022, Vol. 49 ›› Issue (9): 213-223.DOI: 10.1016/j.cjche.2021.11.026

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Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

Weilong Shi^1,3, Jie Gao², Haoran Sun³, Zhongyi Liu¹, Feng Guo³, Lijing Wang^1,4

1. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
2. School of Life Sciences, Northwestern Polytechnical University, Xi'an 710072, China;
3. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4. Henan Engineering Center of New Energy Battery Materials, Henan D&A Engineering Center of Advanced Battery Materials, College of Chemistry and Chemical Engineering, Institute of Architectural Engineering, Shangqiu Normal University, Shangqiu 476000, China

Received:2021-08-28 Revised:2021-10-19 Online:2022-10-19
Contact: Zhongyi Liu,E-mail:liuzhongyi@zzu.edu.cn;Feng Guo,E-mail:gfeng0105@126.com;Lijing Wang,E-mail:wanglijing1989@126.com
Supported by:
The authors would like to acknowledge the founding support from the National Natural Science Foundation of China (21906072 and 22006057), the Natural Science Foundation of Jiangsu Province (BK20190982), Henan Postdoctoral Foundation (202003013), "Doctor of Mass Entrepreneurship and Innovation" Project in Jiangsu Province, the Natural Science Basic Research Plan in Shaanxi Province of China (2021JM-047), Science and Technology Research Project of Henan Province (202102210055), and General project of Chinese postdoctoral program (2020M672263).

Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

Weilong Shi^1,3, Jie Gao², Haoran Sun³, Zhongyi Liu¹, Feng Guo³, Lijing Wang^1,4

1. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
2. School of Life Sciences, Northwestern Polytechnical University, Xi'an 710072, China;
3. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4. Henan Engineering Center of New Energy Battery Materials, Henan D&A Engineering Center of Advanced Battery Materials, College of Chemistry and Chemical Engineering, Institute of Architectural Engineering, Shangqiu Normal University, Shangqiu 476000, China

通讯作者: Zhongyi Liu,E-mail:liuzhongyi@zzu.edu.cn;Feng Guo,E-mail:gfeng0105@126.com;Lijing Wang,E-mail:wanglijing1989@126.com
基金资助:
The authors would like to acknowledge the founding support from the National Natural Science Foundation of China (21906072 and 22006057), the Natural Science Foundation of Jiangsu Province (BK20190982), Henan Postdoctoral Foundation (202003013), "Doctor of Mass Entrepreneurship and Innovation" Project in Jiangsu Province, the Natural Science Basic Research Plan in Shaanxi Province of China (2021JM-047), Science and Technology Research Project of Henan Province (202102210055), and General project of Chinese postdoctoral program (2020M672263).

Abstract

Abstract: The development of effective visible and near-infrared photocatalysts is highly promising in the current field of photocatalysis. Herein, carbon dots/ZnFe₂O₄ (CDs/ZFO) with coating zero dimensional (0D) CDs on the surface of three dimensional (3D) yolk-shell ZFO spheres was designed and synthesized via a self-templated solvothermal method. The as-prepared CDs/ZFO composites displayed outstanding visible and near-infrared photocatalytic degradation activity of tetracycline (TC), and the optimal 3% CDs/ZFO sample with loading 3% (mass) CDs displayed the highest photocatalytic TC degradation ability under visible light (79.5% within 120 min) and near-infrared light (41% within 120 min). The enhancement of photocatalytic activity for CDs/ZFO composite is mainly ascribed to the fact that 0D/3D yolk-shell CDs/ZFO structure not only effectively reflect the incident light to increase the utilization efficiency of solar light, but also utilize the up-conversion photoluminescence and electronic conductivity properties of CDs to broaden sunlight absorption range and promote separation and transfer of electron-hole pairs.

Key words: Carbon dots, ZnFe₂O₄, York-shell, Near-infrared, Photocatalytic

摘要： The development of effective visible and near-infrared photocatalysts is highly promising in the current field of photocatalysis. Herein, carbon dots/ZnFe₂O₄ (CDs/ZFO) with coating zero dimensional (0D) CDs on the surface of three dimensional (3D) yolk-shell ZFO spheres was designed and synthesized via a self-templated solvothermal method. The as-prepared CDs/ZFO composites displayed outstanding visible and near-infrared photocatalytic degradation activity of tetracycline (TC), and the optimal 3% CDs/ZFO sample with loading 3% (mass) CDs displayed the highest photocatalytic TC degradation ability under visible light (79.5% within 120 min) and near-infrared light (41% within 120 min). The enhancement of photocatalytic activity for CDs/ZFO composite is mainly ascribed to the fact that 0D/3D yolk-shell CDs/ZFO structure not only effectively reflect the incident light to increase the utilization efficiency of solar light, but also utilize the up-conversion photoluminescence and electronic conductivity properties of CDs to broaden sunlight absorption range and promote separation and transfer of electron-hole pairs.

关键词: Carbon dots, ZnFe₂O₄, York-shell, Near-infrared, Photocatalytic

Weilong Shi, Jie Gao, Haoran Sun, Zhongyi Liu, Feng Guo, Lijing Wang. Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property[J]. Chinese Journal of Chemical Engineering, 2022, 49(9): 213-223.

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Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

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