A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

doi:10.1016/j.cjche.2022.08.023

Chinese Journal of Chemical Engineering ›› 2023, Vol. 56 ›› Issue (4): 25-32.DOI: 10.1016/j.cjche.2022.08.023

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A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

Shujun Peng¹, Song Lei², Sisi Wen², Jian Xue², Haihui Wang³

1. School of Chemistry & Chemical Engineering, Jinggangshan University, Ji'an 343009, China;
2. School of Chemistry & Chemical Engineering, Guangdong Provincial Key Lab of Green Chemical Product Technology, South China University of Technology, Guangzhou 510640, China;
3. Beijing Key Laboratory of Membrane Materials and Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2022-05-18 Revised:2022-08-06 Online:2023-06-13 Published:2023-04-28
Contact: Jian Xue,E-mail:xuejian@scut.edu.cn
Supported by:
The authors greatly acknowledge the financial support by the National Key Research and Development Program of China (2020YFB1505603), the National Natural Science Foundation of China (22075086), the Guangdong Basic and Applied Basic Research Foundation (2020A1515011157, 2022A1515010980) and the Doctor Scientific Research Startup Foundation of Jinggangshan University (JZB1324).

A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

Shujun Peng¹, Song Lei², Sisi Wen², Jian Xue², Haihui Wang³

1. School of Chemistry & Chemical Engineering, Jinggangshan University, Ji'an 343009, China;
2. School of Chemistry & Chemical Engineering, Guangdong Provincial Key Lab of Green Chemical Product Technology, South China University of Technology, Guangzhou 510640, China;
3. Beijing Key Laboratory of Membrane Materials and Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

通讯作者: Jian Xue,E-mail:xuejian@scut.edu.cn
基金资助:
The authors greatly acknowledge the financial support by the National Key Research and Development Program of China (2020YFB1505603), the National Natural Science Foundation of China (22075086), the Guangdong Basic and Applied Basic Research Foundation (2020A1515011157, 2022A1515010980) and the Doctor Scientific Research Startup Foundation of Jinggangshan University (JZB1324).

Abstract

Abstract: Solid oxide fuel cells (SOFCs) that operate at intermediate temperatures of 600 to 800 ℃ have recently received increased attention due to their improved durability, more rapid startup and shutdown, better sealing and lower cost than their counterparts operate at high temperatures. Nevertheless, intermediate-temperature SOFCs (IT-SOFCs) with popular perovskite cathodes contain alkaline-earth elements, which are prone to reaction with carbon dioxide (CO₂), even when the CO₂ content is comparatively low. In this work, an alkaline-earth metal-free Ruddlesden–Popper oxide, Nd_1.8La_0.2Ni_0.74Cu_0.21Ga_0.05O (NLNCG), is developed for IT-SOFC cathodes. The cell is based on an electrolyte with 8% (mol) Y₂O₃-stabilized ZrO₂ (8YSZ). The NLNCG cathode exhibits an excellent CO₂ tolerance, as proven by thermogravimetry analysis, in situ X-ray diffraction, I-V-P test, and electrochemical impedance spectroscopy (EIS), and stability measurements. The anode-supported single-cell NiO-YSZ|YSZ|NLNCG outputs a peak power density of 0.522 W·cm^-2 at 800 ℃. These findings suggest that NLNCG could be a highly suitable cathode material with CO₂ tolerance for IT-SOFCs.

Key words: Fuel cell, Hydrogen, Kinetics, Catalyst, CO₂ tolerance

摘要： Solid oxide fuel cells (SOFCs) that operate at intermediate temperatures of 600 to 800 ℃ have recently received increased attention due to their improved durability, more rapid startup and shutdown, better sealing and lower cost than their counterparts operate at high temperatures. Nevertheless, intermediate-temperature SOFCs (IT-SOFCs) with popular perovskite cathodes contain alkaline-earth elements, which are prone to reaction with carbon dioxide (CO₂), even when the CO₂ content is comparatively low. In this work, an alkaline-earth metal-free Ruddlesden–Popper oxide, Nd_1.8La_0.2Ni_0.74Cu_0.21Ga_0.05O (NLNCG), is developed for IT-SOFC cathodes. The cell is based on an electrolyte with 8% (mol) Y₂O₃-stabilized ZrO₂ (8YSZ). The NLNCG cathode exhibits an excellent CO₂ tolerance, as proven by thermogravimetry analysis, in situ X-ray diffraction, I-V-P test, and electrochemical impedance spectroscopy (EIS), and stability measurements. The anode-supported single-cell NiO-YSZ|YSZ|NLNCG outputs a peak power density of 0.522 W·cm^-2 at 800 ℃. These findings suggest that NLNCG could be a highly suitable cathode material with CO₂ tolerance for IT-SOFCs.

关键词: Fuel cell, Hydrogen, Kinetics, Catalyst, CO₂ tolerance

Shujun Peng, Song Lei, Sisi Wen, Jian Xue, Haihui Wang. A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures[J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 25-32.

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A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

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