SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2023, Vol. 57 ›› Issue (5): 88-97.DOI: 10.1016/j.cjche.2022.08.020

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Boost activation of peroxymonosulfate by iron doped K2-xMn8O16: Mechanism and properties

Linlin Su1, Meijun Chen1, Li Gong2, Hua Yang1, Chao Chen1, Jun Wu1, Ling Luo1, Gang Yang1, Lulu Long1   

  1. 1. Institute of Ecological and Environmental Sciences, Sichuan Agricultural University, Chengdu 611130, China;
    2. Sichuan Keyuan Testing Center of Engineering Technology, Chengdu 610091, China
  • Received:2022-06-05 Revised:2022-08-15 Online:2023-07-08 Published:2023-05-28
  • Contact: Lulu Long,E-mail:lululong@sicau.edu.cn
  • Supported by:
    This work is supported by the National Natural Science Foundation of China (21806115), Sichuan Science and Technology Program (2020YJ0149), the Power Construction of China (P42819, DJ-ZDXM-2019-42) and the Supported by Sichuan Science and Technology Program (2021ZDZX0012).

Boost activation of peroxymonosulfate by iron doped K2-xMn8O16: Mechanism and properties

Linlin Su1, Meijun Chen1, Li Gong2, Hua Yang1, Chao Chen1, Jun Wu1, Ling Luo1, Gang Yang1, Lulu Long1   

  1. 1. Institute of Ecological and Environmental Sciences, Sichuan Agricultural University, Chengdu 611130, China;
    2. Sichuan Keyuan Testing Center of Engineering Technology, Chengdu 610091, China
  • 通讯作者: Lulu Long,E-mail:lululong@sicau.edu.cn
  • 基金资助:
    This work is supported by the National Natural Science Foundation of China (21806115), Sichuan Science and Technology Program (2020YJ0149), the Power Construction of China (P42819, DJ-ZDXM-2019-42) and the Supported by Sichuan Science and Technology Program (2021ZDZX0012).

Abstract: Among the numerous transition metal catalysts, manganese-based compounds are considered as promising peroxymonosulfate (PMS) catalysts due to their low cost and environmental friendliness, such as cryptomelane manganese oxide (K2-xMn8O16: abbreviation KMnO). However, the limited catalytic performance of KMnO limits its practical application. In this work, iron-doped KMnO (Fe-KMnO) was prepared by one-step hydrothermal method to optimize its catalytic performance. Compared with KMnO/PMS system, Fe-KMnO/PMS system possessed more excellent removal efficiency of tetracycline (TC). Meanwhile, the Fe-KMnO/PMS system also exhibited good practical application potential and excellent stability. The mechanism of Fe-KMnO activation of PMS was further analyzed in detail. It was found that Fe participated in the redox of high-valent Mn, which promoted the activation of PMS. Moreover, The Fe site as an adsorption site enhanced the TC enrichment ability of the catalyst, reducing the mass transfer resistance and further enhancing the TC removal ability of Fe-KMnO/PMS system. This work not only provides an excellent PMS catalyst, but also offers new insights into the mechanism of PMS activation by bimetallic manganese-based catalysts.

Key words: Catalyst, Environment, Waste water, Peroxymonosulfate, K2-xMn8O16, Iron doping

摘要: Among the numerous transition metal catalysts, manganese-based compounds are considered as promising peroxymonosulfate (PMS) catalysts due to their low cost and environmental friendliness, such as cryptomelane manganese oxide (K2-xMn8O16: abbreviation KMnO). However, the limited catalytic performance of KMnO limits its practical application. In this work, iron-doped KMnO (Fe-KMnO) was prepared by one-step hydrothermal method to optimize its catalytic performance. Compared with KMnO/PMS system, Fe-KMnO/PMS system possessed more excellent removal efficiency of tetracycline (TC). Meanwhile, the Fe-KMnO/PMS system also exhibited good practical application potential and excellent stability. The mechanism of Fe-KMnO activation of PMS was further analyzed in detail. It was found that Fe participated in the redox of high-valent Mn, which promoted the activation of PMS. Moreover, The Fe site as an adsorption site enhanced the TC enrichment ability of the catalyst, reducing the mass transfer resistance and further enhancing the TC removal ability of Fe-KMnO/PMS system. This work not only provides an excellent PMS catalyst, but also offers new insights into the mechanism of PMS activation by bimetallic manganese-based catalysts.

关键词: Catalyst, Environment, Waste water, Peroxymonosulfate, K2-xMn8O16, Iron doping