V-MOF-derived V2O5 nanoparticles-modified carbon fiber cloth-based dendrite-free anode for high-performance lithium metal batteries

doi:10.1016/j.cjche.2024.02.014

Abstract

Abstract: At present, commercial Li-ion batteries are hardly to satisfy the growing demand for high energy density, for this purpose, lithium metal batteries have attracted worldwide attention in recent years. However, its practical applications are hindered by the formation of Li dendrites and volume effect during Li plating/stripping process, which leads to a lot of safety hazards. Herein, we first employed MOF-derived V₂O₅ nanoparticles to decorate the carbon fiber cloth (CFC) backbone to acquire a lithiophilic 3D porous conductive framework (CFC@V₂O₅). Subsequently, the CFC@V₂O₅ skeleton was permeated with molten Li to prepare CFC@V₂O₅@Li composite anode. The CFC@V₂O₅@Li composite anode can be stably cycled for more than 1650 h at high current density (5 mA·cm^-2) and areal capacity (5 mA·h·cm^–2). The prepared full cell can initially maintain a high capacity of about 143 mA·h·g^-1 even at a high current density of 5 C, and can still maintain 114 mA·h·g^-1 after 1000 cycles.

Key words: Three-dimensional (3D) conductive frameworks, Lithium metal anode, Lithiophilic material, MOF-derived materials, Prestoring lithium

摘要： At present, commercial Li-ion batteries are hardly to satisfy the growing demand for high energy density, for this purpose, lithium metal batteries have attracted worldwide attention in recent years. However, its practical applications are hindered by the formation of Li dendrites and volume effect during Li plating/stripping process, which leads to a lot of safety hazards. Herein, we first employed MOF-derived V₂O₅ nanoparticles to decorate the carbon fiber cloth (CFC) backbone to acquire a lithiophilic 3D porous conductive framework (CFC@V₂O₅). Subsequently, the CFC@V₂O₅ skeleton was permeated with molten Li to prepare CFC@V₂O₅@Li composite anode. The CFC@V₂O₅@Li composite anode can be stably cycled for more than 1650 h at high current density (5 mA·cm^-2) and areal capacity (5 mA·h·cm^–2). The prepared full cell can initially maintain a high capacity of about 143 mA·h·g^-1 even at a high current density of 5 C, and can still maintain 114 mA·h·g^-1 after 1000 cycles.

关键词: Three-dimensional (3D) conductive frameworks, Lithium metal anode, Lithiophilic material, MOF-derived materials, Prestoring lithium

Tao Wei, Mengting Wang, Yanyan Zhou, Xingtong Guo, Sijia Wang, Ye Liu, Cheng Sun, Qian Wang. V-MOF-derived V₂O₅ nanoparticles-modified carbon fiber cloth-based dendrite-free anode for high-performance lithium metal batteries[J]. Chinese Journal of Chemical Engineering, 2024, 71(7): 13-23.

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V-MOF-derived V₂O₅ nanoparticles-modified carbon fiber cloth-based dendrite-free anode for high-performance lithium metal batteries

V-MOF-derived V₂O₅ nanoparticles-modified carbon fiber cloth-based dendrite-free anode for high-performance lithium metal batteries

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