Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane

doi:10.1016/j.cjche.2014.09.035

›› 2014, Vol. 22 ›› Issue (11/12): 1187-1192.DOI: 10.1016/j.cjche.2014.09.035

Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane

Zhongqi Ren, Xinyan Zhu, Wei Liu, Wei Sun, Weidong Zhang, Junteng Liu

Beijing Key Laboratory of Membrane Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China

收稿日期:2013-04-20 修回日期:2014-01-02 出版日期:2014-12-28 发布日期:2014-12-24
通讯作者: Zhongqi Ren
基金资助:
Supported by the Programfor NewCentury Excellent Talents in University (NCET-10- 0210) and the National Natural Science Foundation of China (21076011 and 21276012).

Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane

Zhongqi Ren, Xinyan Zhu, Wei Liu, Wei Sun, Weidong Zhang, Junteng Liu

Beijing Key Laboratory of Membrane Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China

Received:2013-04-20 Revised:2014-01-02 Online:2014-12-28 Published:2014-12-24
Supported by:
Supported by the Programfor NewCentury Excellent Talents in University (NCET-10- 0210) and the National Natural Science Foundation of China (21076011 and 21276012).

摘要/Abstract

摘要： Hollow fiber renewal liquidmembrane (HFRLM)methodwas proposed based on the surface renewal theory for removal of aniline from waste water. The system of aniline + D2EHPA in kerosene + HCl was used. Aqueous layer diffusion in the feed phase is the rate-control step, and the influence of lumen side flow rate on the mass transfer is more significant than that on the shell side. The resistance of overall mass transfer is greatly reduced because of the mass transfer intensification in the renewal of liquid membrane on the lumen side. The driving force of mass transfer can be considered as a function of distribution equilibrium, and the overall mass transfer coefficient increases with the increase of pH in the feed solution, HCl concentration and D2EHPA concentration, and decreases with the increase of initial aniline concentration. A mass transfermodel is developed forHFRLMbased on the surface renewal theory. The calculated results agree well with experimental results. The HFRLM process is a promising method for aniline wastewater treatment.

关键词: Aniline, Wastewater treatment, Hollow fiber renewal liquid membrane, Mathematic model, Mass transfer

Abstract: Hollow fiber renewal liquidmembrane (HFRLM)methodwas proposed based on the surface renewal theory for removal of aniline from waste water. The system of aniline + D2EHPA in kerosene + HCl was used. Aqueous layer diffusion in the feed phase is the rate-control step, and the influence of lumen side flow rate on the mass transfer is more significant than that on the shell side. The resistance of overall mass transfer is greatly reduced because of the mass transfer intensification in the renewal of liquid membrane on the lumen side. The driving force of mass transfer can be considered as a function of distribution equilibrium, and the overall mass transfer coefficient increases with the increase of pH in the feed solution, HCl concentration and D2EHPA concentration, and decreases with the increase of initial aniline concentration. A mass transfermodel is developed forHFRLMbased on the surface renewal theory. The calculated results agree well with experimental results. The HFRLM process is a promising method for aniline wastewater treatment.

Key words: Aniline, Wastewater treatment, Hollow fiber renewal liquid membrane, Mathematic model, Mass transfer

Zhongqi Ren, Xinyan Zhu, Wei Liu, Wei Sun, Weidong Zhang, Junteng Liu. Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane[J]. , 2014, 22(11/12): 1187-1192.

参考文献

[1] G. Palmiotto, G. Pieraccini, G. Moneti, P. Dolora, Determination of the levels of aromatic amines in indoor and outdoor air in Italy, Chemosphere 43 (2001) 355-361.
[2] H.L. An, L.L. Zhang, B.G. Yuan, X.Q. Zhao, Y.J. Wang, Influence of solvent on reaction path to synthesis of methyl n-phenyl carbamate from aniline, CO₂ and methanol, Chin. J. Chem. Eng. 22 (5) (2014) 607-610.
[3] S. Laha, R.G. Luthy, Oxidation of aniline and other primary aromatic amines bymanganese dioxide, Environ. Sci. Technol. 24 (1990) 363-373.
[4] R. Devulapalli, F. Jones, Separation of aniline from aqueous solutions using emulsion liquid membranes, J. Hazard. Mater. 70 (1999) 157-170.
[5] X.H. Wu, Z.G. Lei, Q.S. Li, J.Q. Zhu, B.H. Chen, Liquid-liquid extraction of lowconcentration aniline from aqueous solutions with salts, Ind. Eng. Chem. Res. 49 (2010) 2581-2588.
[6] C.H. Li, Recovery of aniline from wastewater by nitrobenzene extraction enhanced with salting-out effect, Biomed. Environ. Sci. 23 (2010) 208-212.
[7] F.Q. An, X.Q. Feng, B.J. Gao, Adsorption of aniline from aqueous solution using novel adsorbent PAM/SiO₂, Chem. Eng. J. 151 (2009) 183-187.
[8] A.A. Gürten, S. Ucan, M.A. ñzler, A. Ayar, Removal of aniline from aqueous solution by PVC-CDAE ligand-exchanger, J. Hazard. Mater. 120 (2005) 81-87.
[9] L. Wang, S. Barrington, J.W. Kim, Biodegradation of pentyl amine and aniline from petrochemical wastewater, J. Environ. Manag. 83 (2007) 191-197.
[10] A. Kumar, N. Mathur, Photocatalytic oxidation of aniline using Ag+-loaded TiO₂ suspensions, Appl. Catal. A 275 (2004) 189-197.
[11] J.D. Gyves, E. Rodrîıguez, Metal ion separations by supported liquidmembranes, Ind. Eng. Chem. Res. 38 (1999) 2182-2193.
[12] R. Bloch, A. Finkelstein, O. Kedem, Metal ion separation by dialysis through solvent membranes, Ind. Eng. Chem. Process. Des. Dev. 6 (1967) 231-237.
[13] P.S. Kulkarni, S. Mukhopadhyay, M.P. Bellary, S.K. Ghosh, Studies on membrane stability and recovery of uranium (VI) from aqueous solutions using a liquid emulsion membrane process, hydrometallurgy 64 (2002) 49-58.
[14] L. Pei, L.M.Wang, Stripping dispersion hollow fiber liquidmembrane containing PC-88A as carrier and HCl for transport behavior of trivalent dysprosium, J. Membr. Sci. 378 (2011) 520-530.
[15] C.B. Xiao, J. Ning, H. Yan, X.D. Sun, J.Y. Hu, Biodegradation of aniline by a newly isolated Delftia sp. XYJ6, Chin. J. Chem. Eng. 17 (3) (2009) 500-505.
[16] E. Otal, L.F. Vilches, Y. Luna, R. Poblete, J.M. Garcia-Maya, C. Fernandez-Pereira, Ammonium ion adsorption and settleability improvement achieved in a synthetic zeolite-amended activated sludge, Chin. J. Chem. Eng. 21 (9) (2013) 1062-1068.
[17] S. Datta, P.K. Bhattacharya, N. Velma, Removal of aniline from aqueous solution in a mixed flow reactor using emulsion liquid membrane, J. Membr. Sci. 226 (2003) 185-201.
[18] Z.Q. Ren, W.D. Zhang, Y. Dai, Y.Q. Yang, Z.S. Hao, Modeling of effect of pH on mass transfer of copper extraction by hollow fiber renewal liquid membrane, Ind. Eng. Chem. Res. 47 (2008) 4256-4262.
[19] W.D. Zhang, A.M. Li, Z.Q. Ren, Study on mass transfer characteristics of hollow fiber renewal liquid membrane, J. Chem. Eng. China Univ. 20 (2006) 843-846.
[20] Z.Q. Ren, W.D. Zhang, Y.M. Liu, Y. Dai, C.H. Chui, New liquid membrane technology for simultaneous extraction and stripping of copper(II) from wastewater, Chem. Eng. Sci. 62 (2007) 6090-6101.
[21] Z.Q. Ren, W.D. Zhang, Y.Y. Lv, J. Li, Simultaneous extraction and concentration of penicillin G by hollow fiber renewal liquid membrane, Biotechnol. Prog. 25 (2) (2009) 468-474.
[22] S.Y. Hu, J.M. Wiencek, Emulsion liquid membrane extraction of copper using a hollow fiber contactor, AIChE J. 44 (1998) 570-581.
[23] R. Prasad, K.K. Sirkar, Dispersion-free solvent extraction with micro-porous hollowfiber modules, AIChE J. 34 (2) (1988) 177-188.

Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane

Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane

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