SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2016, Vol. 24 ›› Issue (4): 468-474.DOI: 10.1016/j.cjche.2015.11.020

• 第25届中国过程控制会议专栏 • 上一篇    下一篇

The effect of copper valence on catalytic combustion of styrene over the copper based catalysts in the absence and presence of water vapor

Hongyan Pan1, Zhiyan He1, Qian Lin2, Fei Liu2, Zhong Li3   

  1. 1 School of Chemical Engineering, Guizhou University, Guiyang 550025, China;
    2 Key Laboratory of Guizhou Province for Green Chemical Industry and Clean Energy Technology, Guiyang 550025, China;
    3 Research Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640, China
  • 收稿日期:2015-03-25 修回日期:2015-09-23 出版日期:2016-04-28 发布日期:2016-05-27
  • 通讯作者: Qian Lin
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21366008), the Foundation of Guizhou University ((2010)040) and the Science & Technology Foundation of Guizhou Province ((2012)2152).

The effect of copper valence on catalytic combustion of styrene over the copper based catalysts in the absence and presence of water vapor

Hongyan Pan1, Zhiyan He1, Qian Lin2, Fei Liu2, Zhong Li3   

  1. 1 School of Chemical Engineering, Guizhou University, Guiyang 550025, China;
    2 Key Laboratory of Guizhou Province for Green Chemical Industry and Clean Energy Technology, Guiyang 550025, China;
    3 Research Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640, China
  • Received:2015-03-25 Revised:2015-09-23 Online:2016-04-28 Published:2016-05-27
  • Contact: Qian Lin
  • Supported by:

    Supported by the National Natural Science Foundation of China (21366008), the Foundation of Guizhou University ((2010)040) and the Science & Technology Foundation of Guizhou Province ((2012)2152).

摘要: Catalysts CuOx/γ-Al2O3-IH and CuOx/γ-Al2O3-IM were prepared, characterized, and tested for styrene combustion in the absence and presence of water vapor. The effect of copper valence of the catalysts on the catalytic activity for styrene combustion was discussed using the theory of hard soft acids and bases (HSAB). The results showed that the existence of water vapor in feed stream inhibited the catalytic activity for styrene combustion due to the competition adsorption of water molecule. HSAB theory confirmed that the local soft acidity of the catalyst CuOx/γ-Al2O3-IH was much stronger than that of the catalyst CuOx/γ-Al2O3-IM because of the higher content of soft acid Cu+ on its surface, which increased the adsorption ability toward soft base of styrene and reduced the adsorption toward hard base of water vapor, and thus increased the catalytic activity for styrene combustion and weakened the negative influence of water vapor.

关键词: Catalyst combustion, Styrene, Copper based catalysts, Water inhibition, Theory of hard soft acids and bases

Abstract: Catalysts CuOx/γ-Al2O3-IH and CuOx/γ-Al2O3-IM were prepared, characterized, and tested for styrene combustion in the absence and presence of water vapor. The effect of copper valence of the catalysts on the catalytic activity for styrene combustion was discussed using the theory of hard soft acids and bases (HSAB). The results showed that the existence of water vapor in feed stream inhibited the catalytic activity for styrene combustion due to the competition adsorption of water molecule. HSAB theory confirmed that the local soft acidity of the catalyst CuOx/γ-Al2O3-IH was much stronger than that of the catalyst CuOx/γ-Al2O3-IM because of the higher content of soft acid Cu+ on its surface, which increased the adsorption ability toward soft base of styrene and reduced the adsorption toward hard base of water vapor, and thus increased the catalytic activity for styrene combustion and weakened the negative influence of water vapor.

Key words: Catalyst combustion, Styrene, Copper based catalysts, Water inhibition, Theory of hard soft acids and bases