Enhanced properties of solid solution (CeZr)O2 modified with metal oxides for catalytic oxidation of low-concentration methane

doi:10.1016/j.cjche.2016.07.016

›› 2017, Vol. 25 ›› Issue (2): 187-192.DOI: 10.1016/j.cjche.2016.07.016

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Enhanced properties of solid solution (CeZr)O₂ modified with metal oxides for catalytic oxidation of low-concentration methane

Tianyu Guo¹, Jianping Du², Jinting Wu², Jinping Li¹

1 Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China;
2 College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

收稿日期:2016-06-15 修回日期:2016-07-26 出版日期:2017-02-28 发布日期:2017-03-14
通讯作者: Jinping Li
基金资助:
Supported by the National Natural Science Foundation of China (21136007 and 51572185), the Natural Science Foundation of Shanxi Province (2014011016-4) and the Coal-Based Key Scientific and Technological Project of Shanxi Province (MQ2014-10).

Enhanced properties of solid solution (CeZr)O₂ modified with metal oxides for catalytic oxidation of low-concentration methane

Tianyu Guo¹, Jianping Du², Jinting Wu², Jinping Li¹

1 Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China;
2 College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received:2016-06-15 Revised:2016-07-26 Online:2017-02-28 Published:2017-03-14
Supported by:
Supported by the National Natural Science Foundation of China (21136007 and 51572185), the Natural Science Foundation of Shanxi Province (2014011016-4) and the Coal-Based Key Scientific and Technological Project of Shanxi Province (MQ2014-10).

摘要/Abstract

摘要： The solid solution (CeZr)O₂ catalyst was synthesized, and it wasmodified with metal oxides by incipient impregnation. Morphology and structure were characterized by X-ray diffraction, transmission electronmicroscope, nitrogen ad/desorption and H₂-temperature program reduction techniques. The catalytic properties of methane oxidation were also investigated. The results showed that solid solution possessed a mesoporous structure and exhibited excellent catalytic performance. The activity of solid solution was improved effectively by nickel doping, and the optimal loading is 15 wt%. The stability of (CeZr)O₂ and modified (CeZr)O₂ indicated that the structure of pristine solid solution played a key role in promoting molecules diffusion and spatial confining oxide particle sintering.

关键词: Methane, Catalyst, Solid solution, Metal doping

Abstract: The solid solution (CeZr)O₂ catalyst was synthesized, and it wasmodified with metal oxides by incipient impregnation. Morphology and structure were characterized by X-ray diffraction, transmission electronmicroscope, nitrogen ad/desorption and H₂-temperature program reduction techniques. The catalytic properties of methane oxidation were also investigated. The results showed that solid solution possessed a mesoporous structure and exhibited excellent catalytic performance. The activity of solid solution was improved effectively by nickel doping, and the optimal loading is 15 wt%. The stability of (CeZr)O₂ and modified (CeZr)O₂ indicated that the structure of pristine solid solution played a key role in promoting molecules diffusion and spatial confining oxide particle sintering.

Key words: Methane, Catalyst, Solid solution, Metal doping

Tianyu Guo, Jianping Du, Jinting Wu, Jinping Li. Enhanced properties of solid solution (CeZr)O₂ modified with metal oxides for catalytic oxidation of low-concentration methane[J]. , 2017, 25(2): 187-192.

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Enhanced properties of solid solution (CeZr)O₂ modified with metal oxides for catalytic oxidation of low-concentration methane

Enhanced properties of solid solution (CeZr)O₂ modified with metal oxides for catalytic oxidation of low-concentration methane

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