Research progress in the SO2 resistance of the catalysts for selective catalytic reduction of NOx

doi:10.1016/j.cjche.2017.03.030

Chinese Journal of Chemical Engineering ›› 2017, Vol. 25 ›› Issue (12): 1695-1705.DOI: 10.1016/j.cjche.2017.03.030

• 第25届中国过程控制会议专栏 • 下一篇

Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x

Minhua Zhang^1,2, Baojuan Huang^1,2, Haoxi Jiang^1,2, Yifei Chen^1,2

1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Tianjin University, Tianjin 300072, China;
2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

收稿日期:2016-10-28 修回日期:2017-03-01 出版日期:2017-12-28 发布日期:2018-01-18
通讯作者: Yifei Chen,E-mail address:yfchen@tju.edu.cn.
基金资助:
Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry, and the National Natural Science Foundation of China (21506150).

Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x

Minhua Zhang^1,2, Baojuan Huang^1,2, Haoxi Jiang^1,2, Yifei Chen^1,2

1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Tianjin University, Tianjin 300072, China;
2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Received:2016-10-28 Revised:2017-03-01 Online:2017-12-28 Published:2018-01-18
Contact: Yifei Chen,E-mail address:yfchen@tju.edu.cn.
Supported by:
Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry, and the National Natural Science Foundation of China (21506150).

摘要/Abstract

摘要： The selective catalytic reduction (SCR) of NO_x with NH₃ has been proven to be an efficient technology for NO_x conversion to N₂. However, the catalysts used for SCR usually suffer from the problem of sulfur poisoning which seriously limits their practical application. This review summarized sulfur poisoning mechanisms of various SCR deNO_x catalysts and strategies to reduce deactivation caused by SO₂ such as doping metals, controlling the structures and morphologies of the catalysts, and selecting appropriate supports. The methods and procedures of catalysts preparation and the reaction conditions also have effect on SO₂-resistance of the catalysts. Several novel catalyst systems that exhibited good SO₂ resistance are also introduced. This paper could provide guidance for the development of highly efficient sulfur-tolerant deNO_x catalysts.

关键词: Words Selective catalytic reduction (SCR), SO₂ resistance, catalyst, No_x

Abstract: The selective catalytic reduction (SCR) of NO_x with NH₃ has been proven to be an efficient technology for NO_x conversion to N₂. However, the catalysts used for SCR usually suffer from the problem of sulfur poisoning which seriously limits their practical application. This review summarized sulfur poisoning mechanisms of various SCR deNO_x catalysts and strategies to reduce deactivation caused by SO₂ such as doping metals, controlling the structures and morphologies of the catalysts, and selecting appropriate supports. The methods and procedures of catalysts preparation and the reaction conditions also have effect on SO₂-resistance of the catalysts. Several novel catalyst systems that exhibited good SO₂ resistance are also introduced. This paper could provide guidance for the development of highly efficient sulfur-tolerant deNO_x catalysts.

Key words: Words Selective catalytic reduction (SCR), SO₂ resistance, catalyst, No_x

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen. Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x[J]. Chinese Journal of Chemical Engineering, 2017, 25(12): 1695-1705.

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen. Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x[J]. Chin.J.Chem.Eng., 2017, 25(12): 1695-1705.

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Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x

Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x

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