Influence of Zr, Ce, and La on Co3O4 catalyst for CO2 methanation at low temperature

doi:10.1016/j.cjche.2017.10.014

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (4): 768-774.DOI: 10.1016/j.cjche.2017.10.014

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Influence of Zr, Ce, and La on Co₃O₄ catalyst for CO₂ methanation at low temperature

Yuwen Zhou¹, Yuexiu Jiang¹, Zuzeng Qin^1,2, Qinruo Xie³, Hongbing Ji^1,2

1 School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China;
2 School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China;
3 School of Biology and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou 545006, China

收稿日期:2017-07-30 修回日期:2017-07-30 出版日期:2018-04-28 发布日期:2018-05-19
通讯作者: Zuzeng Qin,E-mail addresses:qinzuzeng@gmail.com,qinzuzeng@gxu.edu.cn;Hongbing Ji,E-mail addresses:jihb@mail.sysu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21366004), Guangxi Natural Science Foundation (2016GXNSFFA380015), the Dean Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology (2016Z003).

Influence of Zr, Ce, and La on Co₃O₄ catalyst for CO₂ methanation at low temperature

Yuwen Zhou¹, Yuexiu Jiang¹, Zuzeng Qin^1,2, Qinruo Xie³, Hongbing Ji^1,2

1 School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China;
2 School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China;
3 School of Biology and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou 545006, China

Received:2017-07-30 Revised:2017-07-30 Online:2018-04-28 Published:2018-05-19
Contact: Zuzeng Qin,E-mail addresses:qinzuzeng@gmail.com,qinzuzeng@gxu.edu.cn;Hongbing Ji,E-mail addresses:jihb@mail.sysu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (21366004), Guangxi Natural Science Foundation (2016GXNSFFA380015), the Dean Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology (2016Z003).

摘要/Abstract

摘要： The Co₃O₄ and Zr-, Ce-, and La-Co₃O₄catalysts were prepared, characterized, and applied to produce CH₄ from CO₂ catalytic hydrogenation in low temperature as 140-220℃. The results indicated that the addition of Zr, Ce, or La to the Co₃O₄ decreased the crystallite sizes of Co and the outer-shell electron density of Co³⁺, and increased the specific surface area, which would provide more active sites for the CO₂ methanation. Especially, the addition of Zr also changed the reducing state of Co₃O₄ via an obvious change in the interaction between Co₃O₄ and ZrO₂. Furthermore, Zr doped into the Co₃O₄ increased the basic intensity of the weak and medium basic sites, as well as the amount of Lewis acid sites, and Brønsted acid sites were also found on the Zr-Co₃O₄ surface. The introduction of Zr, Ce, or La favored the production of CH₄, and the Zr-Co₃O₄ catalyst exhibited the highest CO₂ conversion (58.2%) and CH₄ selectivity (100%) at 200℃, and 0.5 MPa with a gaseous hourly space velocity of 18,000 ml·g_cat^-1·h^-1, and the catalytic activity of CO₂ methanation for the Zr-, Ce-, and La-Co₃O₄ exhibited more stable than Co₃O₄ in a 20-h reaction.

关键词: CO₂ hydrogenation, Methanation, Co₃O₄ catalyst, Cobalt-zirconium interaction, Basic sites

Abstract: The Co₃O₄ and Zr-, Ce-, and La-Co₃O₄catalysts were prepared, characterized, and applied to produce CH₄ from CO₂ catalytic hydrogenation in low temperature as 140-220℃. The results indicated that the addition of Zr, Ce, or La to the Co₃O₄ decreased the crystallite sizes of Co and the outer-shell electron density of Co³⁺, and increased the specific surface area, which would provide more active sites for the CO₂ methanation. Especially, the addition of Zr also changed the reducing state of Co₃O₄ via an obvious change in the interaction between Co₃O₄ and ZrO₂. Furthermore, Zr doped into the Co₃O₄ increased the basic intensity of the weak and medium basic sites, as well as the amount of Lewis acid sites, and Brønsted acid sites were also found on the Zr-Co₃O₄ surface. The introduction of Zr, Ce, or La favored the production of CH₄, and the Zr-Co₃O₄ catalyst exhibited the highest CO₂ conversion (58.2%) and CH₄ selectivity (100%) at 200℃, and 0.5 MPa with a gaseous hourly space velocity of 18,000 ml·g_cat^-1·h^-1, and the catalytic activity of CO₂ methanation for the Zr-, Ce-, and La-Co₃O₄ exhibited more stable than Co₃O₄ in a 20-h reaction.

Key words: CO₂ hydrogenation, Methanation, Co₃O₄ catalyst, Cobalt-zirconium interaction, Basic sites

Yuwen Zhou, Yuexiu Jiang, Zuzeng Qin, Qinruo Xie, Hongbing Ji. Influence of Zr, Ce, and La on Co₃O₄ catalyst for CO₂ methanation at low temperature[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 768-774.

Yuwen Zhou, Yuexiu Jiang, Zuzeng Qin, Qinruo Xie, Hongbing Ji. Influence of Zr, Ce, and La on Co₃O₄ catalyst for CO₂ methanation at low temperature[J]. Chin.J.Chem.Eng., 2018, 26(4): 768-774.

参考文献

[1] W. Wang, S. Wang, X. Ma, J. Gong, Recent advances in catalytic hydrogenation of carbon dioxide, Chem. Soc. Rev. 40(2011) 3703-3727.

[2] T. Cantat, L.-N. He, Innovative methods in CO₂ conversion:a breath of fresh air? Curr. Opin. Green Sustain. Chem. 3(2017) iii-iv.

[3] X.D. Xu, J.A. Moulijn, Mitigation of CO₂ by chemical conversion:plausible chemical reactions and promising products, Energy Fuel 10(1996) 305-325.

[4] Q.-W. Song, Z.-H. Zhou, L.-N. He, Efficient, selective and sustainable catalysis of carbon dioxide, Green Chem. 19(2017) 3707-3728.

[5] I. Graca, L.V. Gonzalez, M.C. Bacariza, A. Fernandes, C. Henriques, J.M. Lopes, M.F. Ribeiro, CO₂ hydrogenation into CH₄ on NiHNaUSY zeolites, Appl. Catal. B 147(2014) 101-110.

[6] W. Zhen, B. Li, G. Lu, J. Ma, Enhancing catalytic activity and stability for CO₂ methanation on Ni@MOF-5 via control of active species dispersion, Chem. Commun. 51(2015) 1728-1731.

[7] J. Xu, Q. Lin, X. Su, H. Duan, H. Geng, Y. Huang, CO₂ methanation over TiO₂-Al₂O₃ binary oxides supported Ru catalysts, Chin. J. Chem. Eng. 24(2016) 140-145.

[8] H.L. Song, J. Yang, J. Zhao, L.J. Chou, Methanation of carbon dioxide over a highly dispersed Ni/La₂O₃ catalyst, Chin. J. Catal. 31(2010) 21-23.

[9] F. Ocampo, B. Louis, L. Kiwi-Minsker, A.-C. Roger, Effect of Ce/Zr composition and noble metal promotion on nickel based Ce_xZr_1-xO₂ catalysts for carbon dioxide methanation, Appl. Catal. A 392(2011) 36-44.

[10] H.C. Lee, K.W. Siew, M.R. Khan, S.Y. Chin, J. Gimbun, C.K. Cheng, Catalytic performance of cement clinker supported nickel catalyst in glycerol dry reforming, J. Energy Chem. 23(2014) 645-656.

[11] H. Zhu, R. Razzaq, L. Jiang, C. Li, Low-temperature methanation of CO in coke oven gas using single nanosized Co₃O₄ catalysts, Catal. Commun. 23(2012) 43-47.

[12] P. Munnik, P.E. de Jongh, K.P. de Jong, Control and impact of the nanoscale distribution of supported cobalt particles used in Fischer-Tropsch catalysis, J. Am. Chem. Soc. 136(2014) 7333-7340.

[13] G. Zhou, T. Wu, H. Xie, X. Zheng, Effects of structure on the carbon dioxide methanation performance of Co-based catalysts, Int. J. Hydrog. Energy 38(2013) 10012-10018.

[14] G. Zhou, T. Wu, H. Zhang, H. Xie, Y. Feng, Carbon dioxide Methanation on ordered mesoporous Co/KIT-6 catalyst, Chem. Eng. Commun. 201(2014) 233-240.

[15] A.Y. Khodakov, W. Chu, P. Fongarland, Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels, Chem. Rev. 107(2007) 1692-1744.

[16] S.L. Soled, E. Iglesia, R.A. Fiato, J.E. Baumgartner, H. Vroman, S. Miseo, Control of metal dispersion and structure by changes in the solid-state chemistry of supported cobalt Fischer-Tropsch catalysts, Top. Catal. 26(2003) 101-109.

[17] Y. Zhu, S. Zhang, Y. Ye, X. Zhang, L. Wang, W. Zhu, F. Cheng, F. Tao, Catalytic conversion of carbon dioxide to methane on ruthenium-cobalt bimetallic nanocatalysts and correlation between surface chemistry of catalysts under reaction conditions and catalytic performances, ACS Catal. 2(2012) 2403-2408.

[18] X. Zhou, T. Su, Y. Jiang, Z. Qin, H. Ji, Z. Guo, CuO-Fe₂O₃-CeO₂/HZSM-5 bifunctional catalyst hydrogenated CO₂ for enhanced dimethyl ether synthesis, Chem. Eng. Sci. 153(2016) 10-20.

[19] Z.Z. Qin, X.H. Zhou, T.M. Su, Y.X. Jiang, H.B. Ji, Hydrogenation of CO₂ to dimethyl ether on la-, Ce-modified Cu-Fe/HZSM-5 catalysts, Catal. Commun. 75(2016) 78-82.

[20] R.-w. Liu, Z.-z. Qin, H.-b. Ji, T.-m. Su, Synthesis of dimethyl ether from CO₂ and H₂ using a Cu-Fe-Zr/HZSM-5 catalyst system, Ind. Eng. Chem. Res. 52(2013) 16648-16655.

[21] M.C.Bacariza,I.Graca,S.S.Bebiano, J.M.Lopes, C.Henriques, Magnesium aspromoter of CO₂ Methanation on Ni-based USY zeolites, Energy Fuel 31(2017) 9776-9789.

[22] K. Ray, G. Deo, A potential descriptor for the CO₂ hydrogenation to CH₄ over Al₂O₃ supported Ni and Ni-based alloy catalysts, Appl. Catal. B 218(2017) 525-537.

[23] C.E. Daza, O.A. Gamba, Y. Hernandez, M.A. Centeno, F. Mondragon, S. Moreno, R. Molina, High-stable mesoporous Ni-Ce/clay catalysts for syngas production, Catal. Lett. 141(2011) 1037-1046.

[24] W. Ahmad, M.N. Younis, R. Shawabkeh, S. Ahmed, Synthesis of lanthanide series (La, Ce, Pr, Eu & Gd) promoted Ni/γ-Al₂O₃ catalysts for methanation of CO₂ at low temperature under atmospheric pressure, Catal. Commun. 100(2017) 121-126.

[25] S. Modak, M. Ammar, F. Mazaleyrat, S. Das, P.K. Chakrabarti, XRD, HRTEM and magnetic properties of mixed spinel nanocrystalline Ni-Zn-Cu-ferrite, J. Alloys Compd. 473(2009) 15-19.

[26] M. Bahmani, B. Vasheghani Farahani, S. Sahebdelfar, Preparation of high performance nano-sized Cu/ZnO/Al₂O₃ methanol synthesis catalyst via aluminum hydrous oxide sol, Appl. Catal. A 520(2016) 178-187.

[27] Y. Wang, R. Wu, Y. Zhao, Effect of ZrO₂ promoter on structure and catalytic activity of the Ni/SiO₂ catalyst for CO methanation in hydrogen-rich gases, Catal. Today 158(2010) 470-474.

[28] L. Samiee, F. Shoghi, A. Vinu, Fabrication and electrocatalytic application of functionalized nanoporous carbon material with different transition metal oxides, Appl. Surf. Sci. 265(2013) 214-221.

[29] B.A. Sexton, A.E. Hughes, T.W. Turney, An XPS and TPR study of the reduction of promoted cobalt-kieselguhr Fischer-Tropsch catalysts, J. Catal. 97(1986) 390-406.

[30] J. Li, N.J. Coville, Effect of boron on the sulfur poisoning of Co/TiO₂ Fischer-Tropsch catalysts, Appl. Catal. A 208(2001) 177-184.

[31] A. Feller, M. Claeys, E. van Steen, Cobalt cluster effects in zirconium promoted Co/SiO₂ Fischer-Tropsch catalysts, J. Catal. 185(1999) 120-130.

[32] C.I. Ahn, Y.J. Lee, S.H. Um, J.W. Bae, Ordered mesoporous CoMOx (M=Al or Zr) mixed oxides for Fischer-Tropsch synthesis, Chem. Commun. 52(2016) 4820-4823.

[33] S. Rojanapipatkul, B. Jongsomjit, Synthesis of cobalt on cobalt-aluminate via solvothermal method and its catalytic properties for carbon monoxide hydrogenation, Catal. Commun. 10(2008) 232-236.

[34] J.-Y. Luo, M. Meng, X. Li, X.-G. Li, Y.-Q. Zha, T.-D. Hu, Y.-N. Xie, J. Zhang, Mesoporous Co₃O₄-CeO₂ and Pd/Co₃O₄-CeO₂ catalysts:synthesis, characterization and mechanistic study of their catalytic properties for low-temperature CO oxidation, J. Catal. 254(2008) 310-324.

[35] S.D. Jones, L.M. Neal, M.L. Everett, G.B. Hoflund, H.E. Hagelin-Weaver, Characterization of ZrO₂-promoted Cu/ZnO/nano-Al₂O₃ methanol steam reforming catalysts, Appl. Surf. Sci. 256(2010) 7345-7353.

[36] P. Gao, F. Li, N. Zhao, F.K. Xiao, W. Wei, L.S. Zhong, Y.H. Sun, Influence of modifier (Mn, La, Ce, Zr and Y) on the performance of Cu/Zn/Al catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol, Appl. Catal. A 468(2013) 442-452.

[37] L.T. Jia, K.G. Fang, J.G. Chen, Y.H. Sun, Cobalt loss from Co-ZrO₂ catalyst for FischerTropsch synthesis in continuously stirred tank reactor, React. Kinet. Catal. Lett. 93(2008) 351-358.

[38] T. Nowitzki, A.F. Carlsson, O. Martyanov, M. Naschitzki, V. Zielasek, T. Risse, M. Schmal, H.J. Freund, M. Baumer, Oxidation of alumina-supported Co and Co-Pd model catalysts for the Fischer-Tropsch reaction, J. Phys. Chem. C 111(2007) 8566-8572.

[39] R. Razzaq, C. Li, M. Usman, K. Suzuki, S. Zhang, A highly active and stable Co₄N/γ-Al₂O₃ catalyst for CO and CO₂ methanation to produce synthetic natural gas (SNG), Chem. Eng. J. 262(2015) 1090-1098.

[40] G. Busca, Spectroscopic characterization of the acid properties of metal oxide catalysts, Catal. Today 41(1998) 191-206.

[41] F. Benaliouche, Y. Boucheffa, P. Ayrault, S. Mignard, P. Magnoux, NH₃-TPD and FTIR spectroscopy of pyridine adsorption studies for characterization of Ag-and Cu-exchanged X zeolites, Microporous Mesoporous Mater. 111(2008) 80-88.

[42] G.R. Johnson, A.T. Bell, Effects of Lewis acidity of metal oxide promoters on the activity and selectivity of Co-based Fischer-Tropsch synthesis catalysts, J. Catal. 338(2016) 250-264.

[43] X. Tang, J. Li, L. Sun, J. Hao, Origination of N₂O from NO reduction by NH₃ over β-MnO₂ and α-Mn₂O₃, Appl. Catal. B 99(2010) 156-162.

[44] R.W. StevensJr., S.S.C. Chuang, B.H. Davis, In situ infrared study of pyridine adsorption/desorption dynamics over sulfated zirconia and Pt-promoted sulfated zirconia, Appl. Catal. A 252(2003) 57-74.

Influence of Zr, Ce, and La on Co₃O₄ catalyst for CO₂ methanation at low temperature

Influence of Zr, Ce, and La on Co₃O₄ catalyst for CO₂ methanation at low temperature

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Zhouxin Chang, Feng Yu, Zhisong Liu, Zijun Wang, Jiangbing Li, Bin Dai, Jinli Zhang. Ni-Al mixed metal oxide with rich oxygen vacancies: CO methanation performance and density functional theory study[J]. 中国化学工程学报, 2022, 46(6): 73-83.
[2]	Bo Wu, Xing Yu, Min Huang, Liangshu Zhong, Yuhan Sun. Rh single atoms embedded in CeO₂ nanostructure boost CO₂ hydrogenation to HCOOH[J]. 中国化学工程学报, 2022, 43(3): 62-69.
[3]	Yiquan Zhao, Yao Shi, Guanghua Ye, Jing Zhang, Xuezhi Duan, Gang Qian, Xinggui Zhou. Optimization of catalyst pellet structures and operation conditions for CO methanation[J]. 中国化学工程学报, 2021, 40(12): 106-113.
[4]	Xiao Fan, Shoujie Ren, Baitang Jin, Shiguang Li, Miao Yu, Xinhua Liang. Enhanced stability of Fe-modified CuO-ZnO-ZrO₂-Al₂O₃/HZSM-5 bifunctional catalysts for dimethyl ether synthesis from CO₂ hydrogenation[J]. 中国化学工程学报, 2021, 38(10): 106-113.
[5]	Xinxin Dong, Baosheng Jin, Zhiwei Kong, Yiqing Sun. Promotion effect of Re additive on the bifunctional Ni catalysts for methanation coupling with water gas shift of biogas: Insights from activation energy[J]. 中国化学工程学报, 2020, 28(6): 1628-1636.
[6]	Jiao Liu, Chuanyue Zheng, Junrong Yue, Guangwen Xu. Synthesis, characterization and catalytic methanation performance of modified kaolin-supported Ni-based catalysts[J]. 中国化学工程学报, 2019, 27(12): 2953-2959.
[7]	Songshou Ye, Jiawei Guo, Yanbing Wang, Jianrong Xie, Zhiming Liu, Nuowei Zhang, Jinbao Zheng, Zhikai Cao, Binghui Chen. Effect of sodium content on the interaction between Ni and support and catalytic performance for syngas methanation over Ni/Zr-Yb-O catalysts[J]. 中国化学工程学报, 2019, 27(11): 2705-2711.
[8]	Mengjuan Zhang, Panpan Li, Mingyuan Zhu, Zhiqun Tian, Jianming Dan, Jiangbing Li, Bin Dai, Feng Yu. Ultralow-weight loading Ni catalyst supported on two-dimensional vermiculite for carbon monoxide methanation[J]. Chinese Journal of Chemical Engineering, 2018, 26(9): 1873-1878.
[9]	Xu Wang, Jianli Zhang, Jingyu Chen, Qingxiang Ma, Subing Fan, Tiansheng Zhao. Effect of preparation methods on the structure and catalytic performance of Fe-Zn/K catalysts for CO₂ hydrogenation to light olefins[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 761-767.
[10]	Baowei Wang, Wenxia Yu, Weihan Wang, Zhenhua Li, Yan Xu, Xinbin M. Effect of boron addition on the MoO₃/CeO₂-Al₂O₃ catalyst in the sulfur-resistant methanation[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 509-513.
[11]	Yuexiu Jiang, Tongxia Huang, Lihui Dong, Zuzeng Qin, Hongbing Ji. Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation[J]. Chinese Journal of Chemical Engineering, 2018, 26(11): 2361-2367.
[12]	Yincong Liu, Lingjun Zhu, Xiaoliu Wang, Shi Yin, Furong Leng, Fan Zhang, Haizhou Lin, Shurong Wang. Catalytic methanation of syngas over Ni-based catalysts with different supports[J]. , 2017, 25(5): 602-608.
[13]	Jinghua Xu, Qingquan Lin, Xiong Su, Hongmin Duan, Haoran Geng, Yanqiang Huang. CO₂ methanation over TiO₂-Al₂O₃ binary oxides supported Ru catalysts[J]. Chinese Journal of Chemical Engineering, 2016, 24(1): 140-145.
[14]	Xingxing Li, Jiageng Li, Bolun Yang, Yong Zhang. Dynamic analysis on methanation reactor using a double-input-multi-output linearized model[J]. , 2015, 23(2): 389-397.
[15]	Jiao Liu, Dianmiao Cui, Jian Yu, Fabing Su, Guangwen Xu. Performance characteristics of fluidized bed syngas methanation over Ni-Mg/Al₂O₃ catalyst[J]. Chinese Journal of Chemical Engineering, 2015, 23(1): 86-92.