Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate

doi:10.1016/j.cjche.2018.03.009

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (12): 2477-2486.DOI: 10.1016/j.cjche.2018.03.009

• Separation Science and Engineering • 上一篇下一篇

Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate

Hongyong Zhao^1,2, Lizhong Feng^1,2, Xiaoli Ding^1,3, Xiaoyao Tan^1,2, Yuzhong Zhang^1,3

1 State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, Tianjin Polytechnic University, Tianjin 300387, China;
2 School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China;
3 Institute of Separation Material and Process Control, School of Material Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China

收稿日期:2017-12-25 修回日期:2018-03-06 出版日期:2018-12-28 发布日期:2019-01-09
通讯作者: Xiaoli Ding
基金资助:
Supported by the National Natural Science Foundation of China (21506160, 21776217) and the Science and Technology Plans of Tianjin (16PTSYJC00110).

Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate

Hongyong Zhao^1,2, Lizhong Feng^1,2, Xiaoli Ding^1,3, Xiaoyao Tan^1,2, Yuzhong Zhang^1,3

1 State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, Tianjin Polytechnic University, Tianjin 300387, China;
2 School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China;
3 Institute of Separation Material and Process Control, School of Material Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China

Received:2017-12-25 Revised:2018-03-06 Online:2018-12-28 Published:2019-01-09
Contact: Xiaoli Ding
Supported by:
Supported by the National Natural Science Foundation of China (21506160, 21776217) and the Science and Technology Plans of Tianjin (16PTSYJC00110).

摘要/Abstract

摘要： Metallic ion-cross-linked polymer of intrinsic microporosity (PIM-1) thin-film composite (TFC) membranes supported on an ultraviolet (UV)-cross-linked porous substrate were fabricated. The UV-cross-linked porous substrate was prepared via polymerization-induced phase separation. The PIM-1 TFC membranes were fabricated via a dip-coating procedure. Metallic ion-cross-linked PIM-1 TFC membranes were fabricated by hydrolyzing the PIM-1 TFC membrane in an alkali solution and then cross-linking it in a multivalent metallic ion solution. The pore size and porous structures were evaluated by low-temperature N₂ adsorption-desorption analysis. The membrane structure was investigated by field-emission scanning electron microscopy. The effects of heat treatment and pore-forming additives on the gas permeance of the UV-cross-linked porous substrate are reported. The effects of different pre-coating treatments on the gas permeance of the metallic ion-cross-linked PIM-1 TFC membrane are also discussed. The metallic ion-crosslinked PIM-1 TFC membrane displayed high CO₂/N₂ selectivity (23) and good CO₂ permeance (1058 GPU).

关键词: Gas separation, Polymerization-induced phase separation, UV-cross-linked porous substrate, Metallic ion-cross-linked PIM-1TFC membrane

Abstract: Metallic ion-cross-linked polymer of intrinsic microporosity (PIM-1) thin-film composite (TFC) membranes supported on an ultraviolet (UV)-cross-linked porous substrate were fabricated. The UV-cross-linked porous substrate was prepared via polymerization-induced phase separation. The PIM-1 TFC membranes were fabricated via a dip-coating procedure. Metallic ion-cross-linked PIM-1 TFC membranes were fabricated by hydrolyzing the PIM-1 TFC membrane in an alkali solution and then cross-linking it in a multivalent metallic ion solution. The pore size and porous structures were evaluated by low-temperature N₂ adsorption-desorption analysis. The membrane structure was investigated by field-emission scanning electron microscopy. The effects of heat treatment and pore-forming additives on the gas permeance of the UV-cross-linked porous substrate are reported. The effects of different pre-coating treatments on the gas permeance of the metallic ion-cross-linked PIM-1 TFC membrane are also discussed. The metallic ion-crosslinked PIM-1 TFC membrane displayed high CO₂/N₂ selectivity (23) and good CO₂ permeance (1058 GPU).

Key words: Gas separation, Polymerization-induced phase separation, UV-cross-linked porous substrate, Metallic ion-cross-linked PIM-1TFC membrane

Hongyong Zhao, Lizhong Feng, Xiaoli Ding, Xiaoyao Tan, Yuzhong Zhang. Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2477-2486.

参考文献

[1] R.W. Baker, Future directions of membrane gas separation technology-A review, Ind. Eng. Chem. Res. 41(2002) 1393-1411.

[2] C.E. Powell, G.G. Qiao, Polymeric CO₂/N₂ gas separation membranes for the capture of carbon dioxide from power plant flue gases-A review, J. Membr. Sci. 279(2006) 1-49.

[3] E.S. Jo, X.H. An, P.G. Ingole, W.K. Choi, Y.S. Park, H.K. Lee, CO₂/CH₄ separation using inside coated thin film composite hollow fiber membranes prepared by interfacial polymerization, Chin. J. Chem. Eng. 25(2017) 278-287.

[4] S.F. Wang, X.Q. Li, H. Wu, Z.Z. Tian, Q.P. Xin, G.W. He, D.D. Peng, S.L. Chen, Y. Yin, Z.Y. Jiang, M.D. Guiver, Advances in high permeability polymer-based membrane materials for CO₂ separations-A review, Energy Environ. Sci. 9(2016) 1863-1890.

[5] P.M. Budd, B.S. Ghanem, S. Makhseed, N.B. McKeown, K.J. Msayib, C.E. Tattershall, Polymers of intrinsic microporosity (PIMs):robust, solution-processable, organic nanoporous materials, Chem. Commun. (2004) 230-231.

[6] P.M. Budd, E.S. Elabas, B.S. Ghanem, S. Makhseed, N.B. McKeown, K.J. Msayib, C.E. Tattershall, D. Wang, Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity, Adv. Mater. 16(2004) 456-459.

[7] P.M. Budd, K.J. Msayib, C.E. Tattershall, B.S. Ghanem, K.J. Reynolds, N.B. McKeown, D. Fritsch, Gas separation membranes from polymers of intrinsic microporosity, J. Membr. Sci. 251(2005) 263-269.

[8] N.B. McKeown, P.M. Budd, D. Fritsch, Thin layer composite membranes, PCT Int. Appl, 2005(WO2005113121).

[9] D. Fritsch, P. Merten, K. Heinrich, M. Lazar, M. Priske, High performance organic solvent nanofiltration membranes:Development and thorough testing of thin film composite membranes made of polymers of intrinsic microporosity (PIMs), J. Membr. Sci. 401-402(2012) 222-231.

[10] P. Gorgojo, S. Karan, H.C. Wong, M.F. Jimenez-Solomon, J.T. Cabral, A.G. Livingston, Ultrathin polymer films with intrinsic microporosity:Anomalous solvent permeation and high flux membranes, Adv. Funct. Mater. 24(2014) 4729-4737.

[11] L. Gao, M. Alberto, P. Gorgojo, G. Szekely, P.M. Budd, High-flux PIM-1/PVDF thin film composite membranes for 1-butanol/water pervaporation, J. Membr. Sci. 529(2017) 207-214.

[12] N.Y. Du, G.P. Robertson, J.S. Song, I. Pinnau, M.D. Guiver, High-performance carboxylated polymers of intrinsic microporosity (PIMs) with tunable gas transport properties, Macromolecules 42(2009) 6038-6043.

[13] N.Y. Du, H.B. Park, G.P. Robertson, M.M. Dal-Cin, T. Visser, L. Scoles, M.D. Guiver, Polymer nanosieve membranes for CO₂-capture applications, Nat. Mater. 10(2011) 372-375.

[14] C. Liu, S.T. Wilson, D.A. Lesch, UV-cross-linked membranes from polymers of intrinsic microporosity for liquid separations, US Patent 7758751(2010).

[15] H.A. Patel, C.T. Yavuz, Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO₂ capture, Chem. Commun. 48(2012) 9989-9991.

[16] F.Y. Li, Y.C. Xiao, T.S. Chung, S. Kawi, High-performance thermally self-cross-linked polymer of intrinsic microporosity (PIM-1) membranes for energy development, Macromolecules 45(2012) 1427-1437.

[17] K.S. Liao, J.Y. Lai, T.S. Chung, Metal ion modified PIM-1 and its application for propylene/propane separation, J. Membr. Sci. 515(2016) 36-44.

[18] Q. Song, S. Cao, R.H. Pritchard, B. Ghalei, S. Al-Muhtaseb, E.M. Terentjev, A.K. Cheetham, E. Sivaniah, Controlled thermal oxidative crosslinking of polymers of intrinsic microporosity towards tunable molecular sieve membranes, Nature Commun. 5(2014) 4813-4825.

[19] C.R. Mason, L. Maynard-Atem, N.M. Al-Harbi, P.M. Budd, P. Bernardo, F. Bazzarelli, G. Clarizia, J.C. Jansen, Polymer of intrinsic microporosity incorporating thioamide functionality:Preparation and gas transport properties, Macromolecules 44(2011) 6471-6479.

[20] C.R. Mason, L. Maynard-Atem, K.W.J. Heard, B. Satilmis, P.M. Budd, K. Friess, M. Lanc, P. Bernardo, G. Clarizia, J.C. Jansen, Enhancement of CO₂ affinity in a polymer of intrinsic microporosity by amine modification, Macromolecules 47(2014) 1021-1029.

[21] B. Satilmis, M.N. Alnajrani, P.M. Budd, Hydroxyalkylaminoalkylamide PIMs:Selective adsorption by ethanolamine-and diethanolamine-modified PIM-1, Macromolecules 48(2015) 5663-5669.

[22] H.Y. Zhao, Q. Xie, X.L. Ding, J.M. Chen, M.M. Hua, X.Y. Tan, Y.Z. Zhang, High performance post-modified polymers of intrinsic microporosity (PIM-1) membranes based on multivalent metal ions for gas separation, J. Membr. Sci. 514(2016) 305-312.

[23] K. Dusek, Phase separation during the formation of three-dimensional polymers, J. Polym. Sci. C Polym. Lett. (1967) 1289-1299.

[24] M. Okada, J. Sun, J. Tao, T. Chiba, T. Nose, Phase separation kinetics and morphology in the critical to off-critical crossover region, Macromolecules 28(1995) 7514-7518.

[25] R.J.J. Williams, B.A. Rozenberg, J.P. Pascault, Reaction-induced phase separation in modified thermosetting polymers, Adv. Polym. Sci. 128(1997) 95-156.

[26] O. Okay, Macroporous copolymer networks, Prog. Polym. Sci. 25(2000) 711-779.

[27] Y.H. Wu, H.B. Park, T. Kai, B.D. Freeman, D.S. Kalik, Water uptake, transport and structure characterization in poly(ethylene glycol) diacrylate hydrogels, J. Membr. Sci. 347(2010) 197-208.

[28] M. Mulder, Basic Principles of Membrane Technology, 2nd ed. Kluwer Academic Publishers, Netherlands, 1996.

[29] C.M. Cheng, F.J. Micale, J.W. Vander hoff, M.S. EI-Aasser, Pore structural studies of monodisperse porous polymer particles, J. Colloid Interface Sci. 150(1992) 549-558.

[30] K. Dusek, in:A.J. Chompff, S. Newman (Eds.), Polymer Networks:Structure and Mechanical Properties in Homogeneities Induced by Crosslinking in the Course of Crosslinking Copolymerization, Plenum Press, New York 1971, pp. 245-260.

[31] K.S.W. Sing, R.T. Williams, Physisorption hysteresis loops and the characterization of nanoporous materials-A review, Adsorpt. Sci. Technol. 22(2004) 773-782.

[32] Z.X. Low, Y.T. Chua, B.M. Ray, D. Mattia, I.S. Metcalfe, D.A. Patterson, Perspective on 3D printing of separation membranes and comparison to related unconventional fabrication techniques-A review, J. Membr. Sci. 523(2017) 596-613.

[33] I.F.J. Vankelecom, B. Moermans, G. Verschueren, P.A. Jacobs, Intrusion of PDMS top layers in porous supports, J. Membr. Sci. 158(1999) 289-297.

[34] T.C. Merkel, H.Q. Lin, X.T. Wei, R. Baker, Power plant post-combustion carbon dioxide capture:An opportunity for membranes-A review, J. Membr. Sci. 359(2010) 126-139.

Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate

Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[2]	Zhengchi Yin, Xiaoke Wu, Yanwei Yang, Huayu Zhang, Wangtao Li, Ruimin Zhu, Qiancheng Zheng, Zhengbao Wang. Fabrication of ZIF-8 membranes on dual-layer ZnO-PES/PES organic hollow fibers by in-situ crystallization[J]. 中国化学工程学报, 2023, 55(3): 101-110.
[3]	Xionghui Liu, Jianfeng Du, Yu Ye, Yuchuan Liu, Shun Wang, Xianyu Meng, Xiaowei Song, Zhiqiang Liang, Wenfu Yan. Boosting selective C₂H₂/CH₄, C₂H₄/CH₄ and CO₂/CH₄ adsorption performance via 1,2,3-triazole functionalized triazine-based porous organic polymers[J]. 中国化学工程学报, 2022, 42(2): 64-72.
[4]	Golchehreh Bayat, Roozbeh Saghatchi, Jafar Azamat, Alireza Khataee. Separation of methane from different gas mixtures using modified silicon carbide nanosheet: Micro and macro scale numerical studies[J]. 中国化学工程学报, 2020, 28(5): 1268-1276.
[5]	Mengqi Shi, Chenxi Dong, Zhi Wang, Xinxia Tian, Song Zhao, Jixiao Wang. Support surface pore structures matter: Effects of support surface pore structures on the TFC gas separation membrane performance over a wide pressure range[J]. 中国化学工程学报, 2019, 27(8): 1807-1816.
[6]	Gholamhossein Sodeifian, Mojtaba Raji, Morteza Asghari, Mashallah Rezakazemi, Amir Dashti. Polyurethane-SAPO-34 mixed matrix membrane for CO₂/CH₄ and CO₂/N₂ separation[J]. Chinese Journal of Chemical Engineering, 2019, 27(2): 322-334.
[7]	Yibin Wei, Hengfei Zhang, Jiaojiao Lei, Huating Song, Hong Qi. Controlling pore structures of Pd-doped organosilica membranes by calcination atmosphere for gas separation[J]. 中国化学工程学报, 2019, 27(12): 3036-3042.
[8]	Gang Yue, Aixian Liu, Qiang Sun, Xingxun Li, Wenjie Lan, Lanying Yang, Xuqiang Guo. The combination of 1-octyl-3-methylimidazolium tetrafluorborate with TBAB or THF on CO₂ hydrate formation and CH₄ separation from biogas[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2495-2502.
[9]	Misagh Ahmadi, Sara Masoumi, Shadi Hassanajili, Feridun Esmaeilzadeh. Modification of PES/PU membrane by supercritical CO₂ to enhance CO₂/CH₄ selectivity: Fabrication and correlation approach using RSM[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2503-2515.
[10]	Pannir Selvam Murugiah, Pei Ching Oh, Kok Keong Lau. Impregnation of carbonaceous nanofibers into glassy polymer-based composite membrane for CO₂ separation[J]. Chinese Journal of Chemical Engineering, 2018, 26(11): 2385-2390.
[11]	Yang Han, W. S. Winston Ho. Recent advances in polymeric membranes for CO₂ capture[J]. Chinese Journal of Chemical Engineering, 2018, 26(11): 2238-2254.
[12]	Huating Song, Yibin Wei, Chenying Wang, Shuaifei Zhao, Hong Qi. Tuning sol size to optimize organosilica membranes for gas separation[J]. Chinese Journal of Chemical Engineering, 2018, 26(1): 53-59.
[13]	Kang Huang, Jianwei Yuan, Guoshun Shen, Gongping Liu, Wanqin Jin. Graphene oxide membranes supported on the ceramic hollow fibre for efficient H₂ recovery[J]. , 2017, 25(6): 752-759.
[14]	Li Li, Hong Qi. Gas separation using sol-gel derived microporous zirconia membranes with high hydrothermal stability[J]. Chinese Journal of Chemical Engineering, 2015, 23(8): 1300-1306.
[15]	杨宏军, 樊栓狮, 郎雪梅, 王燕鸿, 聂江华. Economic Comparison of Three Gas Separation Technologies for CO₂ Capture from Power Plant Flue Gas [J]. , 2011, 19(4): 615-620.