DBU-based CO2 absorption-mineralization system: Reaction process, feasibility and process intensification

doi:10.1016/j.cjche.2019.12.008

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (4): 1145-1155.DOI: 10.1016/j.cjche.2019.12.008

• Energy, Resources and Environmental Technology • 上一篇下一篇

DBU-based CO₂ absorption-mineralization system: Reaction process, feasibility and process intensification

Cong Luo^1,2, Kejing Wu², Hairong Yue¹, Yingying Liu², Yingming Zhu², Wei Jiang¹, Houfang Lu^1,2, Bin Liang^1,2

1 School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2 Institute of New Energy and Low-carbon Technology, Sichuan University, Chengdu 610207, China

收稿日期:2019-10-24 修回日期:2019-12-10 出版日期:2020-04-28 发布日期:2020-07-27
通讯作者: Houfang Lu
基金资助:
The authors gratefully thank the National Natural Science Foundation of China (No. 21878190) and National Key R&D Program of China (2018YFB0605700) for financial support, and the Institute of New Energy and Low-Carbon Technology, Sichuan University, for SEM images capturing and XRD patterns acquisition work.

DBU-based CO₂ absorption-mineralization system: Reaction process, feasibility and process intensification

Cong Luo^1,2, Kejing Wu², Hairong Yue¹, Yingying Liu², Yingming Zhu², Wei Jiang¹, Houfang Lu^1,2, Bin Liang^1,2

1 School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2 Institute of New Energy and Low-carbon Technology, Sichuan University, Chengdu 610207, China

Received:2019-10-24 Revised:2019-12-10 Online:2020-04-28 Published:2020-07-27
Contact: Houfang Lu
Supported by:
The authors gratefully thank the National Natural Science Foundation of China (No. 21878190) and National Key R&D Program of China (2018YFB0605700) for financial support, and the Institute of New Energy and Low-Carbon Technology, Sichuan University, for SEM images capturing and XRD patterns acquisition work.

摘要/Abstract

摘要： Amine-based carbon dioxide (CO₂) capture is still limited by high desorption energy consumption. Fixing CO₂ into carbonate is a safer and more permanent method. In this work, calcium oxide (CaO) is introduced to perform chemical desorption instead of thermal desorption on 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) aqueous solution after CO₂ absorption. The X-ray diffraction (XRD) patterns of solid products show the formation of calcite calcium carbonate (CaCO₃), which prove the feasibility of this method. The effects of reaction temperature, reaction time and Ca²⁺/CO₃^2- molar ratios on the related reactions in CO₂ absorption-mineralization process and CaCO₃ precipitation are discussed, and purer CaCO₃ is obtained by ultrasonic treatment. The CaCO₃ content can be increased to 95.8% and the CO₂ desorption ratio can achieve 80% by 30 min ultrasonic dispersion treatment under the conditions (40 ℃, 180 min, Ca²⁺/CO₃^2- molar ratio = 1.0). After five cycles, DBU aqueous solution shows stable CO₂ absorption and mineralization ability. Fourier transform infrared spectroscopy (FT-IR) spectra of the reaction process also indicate the regeneration of the solvent. Compared with thermal desorption, this process is exothermic, almost without no additional heat.

关键词: CO₂ mineralization, CaCO3, 1,8-Diazabicyclo [5.4.0] undec-7-ene aqueous, Reaction process

Abstract: Amine-based carbon dioxide (CO₂) capture is still limited by high desorption energy consumption. Fixing CO₂ into carbonate is a safer and more permanent method. In this work, calcium oxide (CaO) is introduced to perform chemical desorption instead of thermal desorption on 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) aqueous solution after CO₂ absorption. The X-ray diffraction (XRD) patterns of solid products show the formation of calcite calcium carbonate (CaCO₃), which prove the feasibility of this method. The effects of reaction temperature, reaction time and Ca²⁺/CO₃^2- molar ratios on the related reactions in CO₂ absorption-mineralization process and CaCO₃ precipitation are discussed, and purer CaCO₃ is obtained by ultrasonic treatment. The CaCO₃ content can be increased to 95.8% and the CO₂ desorption ratio can achieve 80% by 30 min ultrasonic dispersion treatment under the conditions (40 ℃, 180 min, Ca²⁺/CO₃^2- molar ratio = 1.0). After five cycles, DBU aqueous solution shows stable CO₂ absorption and mineralization ability. Fourier transform infrared spectroscopy (FT-IR) spectra of the reaction process also indicate the regeneration of the solvent. Compared with thermal desorption, this process is exothermic, almost without no additional heat.

Key words: CO₂ mineralization, CaCO3, 1,8-Diazabicyclo [5.4.0] undec-7-ene aqueous, Reaction process

Cong Luo, Kejing Wu, Hairong Yue, Yingying Liu, Yingming Zhu, Wei Jiang, Houfang Lu, Bin Liang. DBU-based CO₂ absorption-mineralization system: Reaction process, feasibility and process intensification[J]. 中国化学工程学报, 2020, 28(4): 1145-1155.

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DBU-based CO₂ absorption-mineralization system: Reaction process, feasibility and process intensification

DBU-based CO₂ absorption-mineralization system: Reaction process, feasibility and process intensification

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