Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples

doi:10.1016/j.cjche.2020.08.047

中国化学工程学报 ›› 2021, Vol. 33 ›› Issue (5): 306-318.DOI: 10.1016/j.cjche.2020.08.047

• Resources and Environmental Technology • 上一篇下一篇

Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples

Dauda Mohammed¹, Muhammad H. Al-Malack¹, Basheer Chanbasha²

1 Department of Civil and Environmental Engineering, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia;
2 Department of Chemistry, King Fahd University of Petroleum & Minerals, Dhahran 31262, Saudi Arabia

收稿日期:2020-03-26 修回日期:2020-08-03 出版日期:2021-05-28 发布日期:2021-08-19
通讯作者: Dauda Mohammed
基金资助:
The authors would like to express their gratitude to King Fahd University of Petroleum & Minerals (Dhahran, Saudi Arabia) for the technical and financial support provided. CB thank the Deanship of Scientific Research for the financial support through the project No:DF181034.

Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples

Dauda Mohammed¹, Muhammad H. Al-Malack¹, Basheer Chanbasha²

1 Department of Civil and Environmental Engineering, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia;
2 Department of Chemistry, King Fahd University of Petroleum & Minerals, Dhahran 31262, Saudi Arabia

Received:2020-03-26 Revised:2020-08-03 Online:2021-05-28 Published:2021-08-19
Contact: Dauda Mohammed
Supported by:
The authors would like to express their gratitude to King Fahd University of Petroleum & Minerals (Dhahran, Saudi Arabia) for the technical and financial support provided. CB thank the Deanship of Scientific Research for the financial support through the project No:DF181034.

摘要/Abstract

摘要： Surface functionalization of blast furnace slag with sulfamic acid (a zwitterion) was performed for the removal of Cr³⁺ and methylene blue dye (MB) from water samples. The slag functionalization process was optimized using Response Surface Methodology Design. Statistical analysis of the parameters that include the sulfamic acid amount (A), reaction time (B), and temperature (C) revealed that (A) increase had a negative effect on the adsorption of both pollutants by the zwitterion slag, whereas (B) and (C) increase presented a positive impact. At the optimum condition of 2 g sulfamic acid amount, 50 min reaction time and 37 C temperature, the prepared slag showed a removal efficiency of more than 90% for both Cr³⁺ and MB. Surface characterization by SEM/EDS, FTIR, XPS and surface area analyser, showed an improvement in surface properties and the incorporation of zwitterionic NH₂⁺ and S=O groups of sulfamic acid. Adsorption isotherm and kinetic studies conducted with the zwitterion slag showed the adsorption process was suited to Freundlich isotherm model and pseudo-second-order kinetic model. The thermodynamic study conducted revealed the spontaneity of the process based on the calculated negative ΔG (Gibb’s free energy) values. The prepared zwitterion slag offered easy regeneration with dilute HCl solution and showed a considerable removal (Cr³⁺: 65% and MB: 80%) for both pollutants even after 3 cycles of usage.

关键词: Functional groups, Optimization, Zwitterion, Adsorption, Waste treatment, Industrial waste

Abstract: Surface functionalization of blast furnace slag with sulfamic acid (a zwitterion) was performed for the removal of Cr³⁺ and methylene blue dye (MB) from water samples. The slag functionalization process was optimized using Response Surface Methodology Design. Statistical analysis of the parameters that include the sulfamic acid amount (A), reaction time (B), and temperature (C) revealed that (A) increase had a negative effect on the adsorption of both pollutants by the zwitterion slag, whereas (B) and (C) increase presented a positive impact. At the optimum condition of 2 g sulfamic acid amount, 50 min reaction time and 37 C temperature, the prepared slag showed a removal efficiency of more than 90% for both Cr³⁺ and MB. Surface characterization by SEM/EDS, FTIR, XPS and surface area analyser, showed an improvement in surface properties and the incorporation of zwitterionic NH₂⁺ and S=O groups of sulfamic acid. Adsorption isotherm and kinetic studies conducted with the zwitterion slag showed the adsorption process was suited to Freundlich isotherm model and pseudo-second-order kinetic model. The thermodynamic study conducted revealed the spontaneity of the process based on the calculated negative ΔG (Gibb’s free energy) values. The prepared zwitterion slag offered easy regeneration with dilute HCl solution and showed a considerable removal (Cr³⁺: 65% and MB: 80%) for both pollutants even after 3 cycles of usage.

Key words: Functional groups, Optimization, Zwitterion, Adsorption, Waste treatment, Industrial waste

Dauda Mohammed, Muhammad H. Al-Malack, Basheer Chanbasha. Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples[J]. 中国化学工程学报, 2021, 33(5): 306-318.

参考文献

[1] A. Ramírez-Estrada, V.Y. Mena-Cervantes, J. Fuentes-García, J. Vazquez-Arenas, R. Palma-Goyes, A.I. Flores-Vela, R. Vazquez-Medina, R.H. Altamirano, Cr(III) removal from synthetic and real tanning effluents using an electroprecipitation method, J. Environ. Chem. Eng. 6(2018) 1219-1225.
[2] M. Ahmaruzzaman, V.K. Gupta, Rice husk and its ash as low-cost adsorbents in water and wastewater treatment, Ind. Eng. Chem. Res. 50(2011) 13589-13613.
[3] G. Lofrano, S. Meriç, G.E. Zengin, D. Orhon, Chemical and biological treatment technologies for leather tannery chemicals and wastewaters: A review, Sci. Total Environ. 461-462(2013) 265-281.
[4] V.K. Gupta, I. Ali, T.A. Saleh, M.N. Siddiqui, S. Agarwal, Chromium removal from water by activated carbon developed from waste rubber tires, Environ. Sci. Pollut. Res. Int 20(2013) 1261-1268.
[5] N. Mathur, P. Bhatnagar, P. Sharma, Review of the mutagenicity of textile dye products, Univ. J Environ. Res Technol. 2(2012) 1-18.
[6] United State Environmental Protection Agency (USEPA), Priority Pollutant List, 1986(2014) 1-2.
[7] PME Presidency of Metrology and Environment, Kingdom of Saudi Arabia, General Environmental Regulations And Rules for Implementation, Document No.1409-01(2001).
[8] G.R. Kishore, R.P. Sree, D. Krishna, Industrial wastes as adsorbents for the removal of chromium from waste water: A review. Int. J. Chem. Sci. 11(2013) 1371-1384.
[9] S. Lin, C. Lian, M. Xu, W. Zhang, L. Liu, K. Lin, Study on competitive adsorption mechanism among oxyacid-type heavy metals in co-existing system: Removal of aqueous As (V), Cr (III) and As (III) using magnetic iron oxide nanoparticles (MIONPs) as adsorbents, Appl. Surf. Sci. 422(2017) 675-681.
[10] M. Syakirin, F. Mohd, S. Nurjaliah, Adsorption of manganese in aqueous solution by steel slag, Procedia Environ. Sci. 30(2015) 145-150.
[11] L. Bláhová, Z. Navrátilová, M. Mucha, Alkali-activation of blast furnace slag as possible modification for improving sorption properties of heavy metals, Inzynieria Miner. 1(2017) 59-64.
[12] S.K. Srivastava, V.K. Gupta, D. Mohan, Removal of lead and chromium, Environ. Eng. 23(1997) 461-468.
[13] S. Bae, F. Hikaru, M. Kanematsu, C. Yoshizawa, Removal of hexavalent chromium in portland cement using ground granulated, Materials 11(1) (2017) 11.
[14] C. Han, Y. Jiao, Q. Wu, W. Yang, H. Yang, X. Xue, Kinetics and mechanism of hexavalent chromium removal by basic oxygen furnace slag, J. Environ. Sci. 46(2016) 63-71.
[15] T.C. Nguyen, P. Loganathan, T.V. Nguyen, Adsorptive removal of five heavy metals from water using blast furnace slag and fly ash, Environ Sci Pollut Res Int 25(21) (2018) 20430-20438.
[16] D. Dupont, E. Renders, S. Raiguel, K. Binnemans, New metal extractants and super-acidic ionic liquids derived from sulfamic acid, Chem. Commun. 52(2016) 7032-7035.
[17] S.A. El-hakam, S.E. Samra, S.M. El-dafrawy, A.A. Ibrahim, R.S. Salama, A.I. Ahmed, Synthesis of sulfamic acid supported on Cr-MIL-101 as a heterogeneous acid catalyst and efficient adsorbent for methyl orange dye, Rsc Adv 8(37) (2018) 20511-20533.
[18] N. Zahra, M. Z. Kassaee, E. Eidi, Homopiperazine sulfamic acid functionalized mesoporous silica nanoparticles (MSNs-HPZ-SO₃H) as an efficient catalyst for one-pot synthesis of 1-amidoalkyl-2-naphthols, New J. Chem. 40(2016) 4720-4726.
[19] S. Gomez-GonZalez, S. Efrain, C.A., Gregorio Guadalupe, Manriquez-Gonzalez, Ricardo, Cruz-Hernandez, Wencel De la, Gomez-Salazar, Trivalent chromium removal from aqueous solutions by a sol-gel.pdf, Materials Research Bulletin. 59(2014) 394-404.
[20] L. Yang, X. Qian, Z. Wang, Steel slag as low-cost adsorbent for the removal of phenanthrene and naphthalene, Adsorpt. Sci. Technol. 36(3-4) (2018) 1160-1177.
[21] J. Safari, M. Ahmadzadeh, Zwitterionic sulfamic acid functionalized nanoclay: A novel nanocatalyst for the synthesis of dihydropyrano[2,3-c]pyrazoles and spiro[indoline-3,4′ -pyrano[2,3-c]pyrazole] derivatives, J. Taiwan Inst. Chem. Eng. 74(2017) 14-24.
[22] A. Ghorbani-choghamarani, G. Azadi, Synthesis and characterization of sulfamic acid-functionalized nanoparticles and study of its catalytic activity for the oxidation of sulfides to sulfoxides, Chem Inforrn 89(2016) 49-54.
[23] L. Shiri, H. Narimani, M. Kazemi, Synthesis and characterization of sulfamic acid supported on Fe₃O₄ nanoparticles: A green, versatile and magnetically separable acidic catalyst for oxidation reactions and Knoevenagel condensation, Appl. Organomet. Chem. 32(2018) 1-12.
[24] M.M. Kaid, A. Gebreil, S.A. El-Hakam, A.I. Ahmed, A.A. Ibrahim, Sulfamic acid incorporated HKUST-1: A highly active catalyst and efficient adsorbent, RSC Adv. 10(26) (2020) 15586-15597.
[25] R.H. Myers, D.C. Montgomery, C.M. Anderson-Cook, Response Surface Methodology, third ed., John Wiley Son, Inc, New Jersey, 2009.
[26] M.H. Essa, N.D. Mu’azu, S. Lukman, A. Bukhari, Integrated electrokineticsadsorption remediation of saline-sodic soils: Effects of voltage gradient and contaminant concentration on soil electrical conductivity, Sci. World J. 2013(2013) 618495.
[27] M. Manohar, J. Joseph, T. Selvaraj, D. Sivakumar, Application of desirabilityfunction and RSM to optimize the multi-objectives while turning Inconel 718 using coated carbide tools, Int. J. Manuf. Technol. Manage. 27(4-6) (2013) 218.
[28] S. Dubey, S.N. Upadhyay, Y.C. Sharma, Optimization of removal of Cr by calumina nano-adsorbent using response surface methodology, Ecol. Eng. 97(2016) 272-283.
[29] U.J. Etim, S.A. Umoren, U.M. Eduok, Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution, J. Saudi Chem. Soc. 20(2016) S67-S76.
[30] M.H. Essa, N.D. Mu’azu, S. Lukman, A. Bukhari, Application of box-behnken design to hybrid electrokinetic-adsorption removal of mercury from contaminated saline-sodic clay soil, Soil Sediment Contam. 24(2015) 30-48.
[31] J. Kyzioł, Effect of physical properties and cation exchange capacity on sorption of heavy metals onto peats, Polish J. Environ. Stud. 11(6) (2002) 713.
[32] L. Mouni, L. Belkhiri, J.C. Bollinger, A. Bouzaza, A. Assadi, A. Tirri, F. Dahmoune, K. Madani, H. Remini, Removal of methylene blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies, Appl. Clay Sci. 153(2018) 38-45.
[33] M.H. Al-Malack, M. Dauda, Competitive adsorption of cadmium and phenol on activated carbon produced from municipal sludge, J. Environ. Chem. Eng. 5(2017) 2718-2729.
[34] S. Liu, J. Li, S. Xu, M. Wang, Y. Zhang, X. Xue, A modified method for enhancing adsorption capability of banana pseudostem biochar towards methylene blue at low temperature, Bioresour. Technol. 282(2019) 48-55.
[35] A.L. Arim, M.J. Quina, L.M. Gando-Ferreira, Uptake of trivalent chromium from aqueous solutions by xanthate pine bark: Characterization, batch and column studies, Process Saf. Environ. Prot. 121(2019) 374-386.
[36] H. Panda, N. Tiadi, M. Mohanty, C.R. Mohanty, Studies on adsorption behavior of an industrial waste for removal of chromium from aqueous solution, South Afr. J. Chem. Eng. 23(2017) 132-138.
[37] I. Ahmad, N. Ahmad, N. Iqbal, M. Zahid, M. Iqbal, Journal of Environmental Chemical Engineering Chromium adsorption using waste tire and conditions optimization by response surface methodology, J. Environ. Chem. Eng. 5(2017) 2740-2751.
[38] TC. Nguyen, P. Loganathan, T.V. Nguyen, Adsorptive removal of five heavy metals from water using blast furnace slag and fly ash, Chem. Eng. J. 156(1) (2018) 20430-20438.
[39] J. Sren, U. Narkiewicz, A.W. Morawski, J. Wro, B. Michalkiewicz, Comparison of optimized isotherm models and error functions for carbon dioxide adsorption on activated carbon, J. Chem. Eng. Data 60(11) (2015) 3148-3158.
[40] S.S.H. Babazadeh, Isotherms for the sorption of zinc and copper onto kaolinite: comparison of various error functions, Int. J. Environ. Sci. Technol. 11(1) (2014) 111-118.
[41] I. Tosun, Ammonium removal from aqueous solutions by clinoptilolite: _ Determination of isotherm and thermodynamic parameters and comparison of kinetics by the double exponential model and conventional kinetic models, Int J Enriron Res Pubic Health 9(3) (2012) 970-984.
[42] L. Meili, P.V. Lins, C.L.P.S. Zanta, J.I. Soletti, L.M.O. Ribeiro, C.B. Dornelas, T.L. Silva, M.G.A. Vieira, Applied clay science MgAl-LDH/Biochar composites for methylene blue removal by adsorption, Appl. Clay Sci. 168(2019) 11-20.
[43] D.S. Tong, C.W. Wu, M.O. Adebajo, G.C. Jin, W.H. Yu, S.F. Ji, C.H. Zhou, Adsorption of methylene blue from aqueous solution onto porous cellulosederived carbon/montmorillonite nanocomposites, Appl. Clay Sci. 161(2018) 256-264.
[44] H.S. Mohamed, N.K. Soliman, D.A. Abdelrheem, A.A. Ramadan, A.H. Elghandour, S.A. Ahmed, Adsorption of Cd²⁺ and Cr³⁺ ions from aqueous solutions by using residue of Padina gymnospora waste as promising low-cost adsorbent, Heliyon 5(3) (2019) e01287.
[45] Z. Li, X. Meng, Z. Zhang, Equilibrium and kinetic modelling of adsorption of Rhodamine B on MoS₂, Mater. Res. Bull. 111(2019) 238-244.
[46] R. Elangovan, L. Philip, K. Chandraraj, Biosorption of hexavalent and trivalent chromium by palm flower (Borassus aethiopum), Chem. Eng. J. 141(2008) 99-111.
[47] R. Fonseca-correa, L. Giraldo, J.C. Moreno-piraján, Journal of analytical and applied pyrolysis trivalent chromium removal from aqueous solution with physically and chemically modified corncob waste, J. Anal. Appl. Pyrolysis 101(2013) 132-141.
[48] D. Pathania, S. Sharma, P. Singh, Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast, Arab. J. Chem. 10(2017) S1445-S1451.
[49] J. Yang, M. Yu, T. Qiu, Journal of industrial and engineering chemistry adsorption thermodynamics and kinetics of Cr (VI) on KIP210 resin, J. Ind. Eng. Chem. 20(2014) 480-486.
[50] Y. Cantu, A. Remes, A. Reyna, D. Martinez, J. Villarreal, H. Ramos, S. Trevino, C. Tamez, A. Martinez, T. Eubanks, J.G. Parsons, Thermodynamics, kinetics, and activation energy studies of the sorption of chromium (III) and chromium (VI) to a Mn₃O₄ nanomaterial, Chem. Eng. J. 254(2014) 374-383.
[51] A.A. Inyinbor, F.A. Adekola, G.A. Olatunji, Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp, Water Resour. Ind. 15(2016) 14-27.
[52] R. Khosravi, G. Moussavi, M. Taghi, M. Hassan, Chromium adsorption from aqueous solution using novel green nanocomposite: Adsorbent characterization, isotherm, kinetic and thermodynamic investigation, J. Mol. Liq. 256(2018) 163-174.
[53] R. Hasan, C.C. Chong, H.D. Setiabudi, R. Jusoh, A.A. Jalil, Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash, Environ. Technol. Innov. 13(2019) 62-73.
[54] D. Durano, A.W. Trochimczuk, U. Beker, Kinetics and thermodynamics of hexavalent chromium adsorption onto activated carbon derived from acrylonitrile-divinylbenzene copolymer, Chem. Eng. J. 187(2012) 193-202.
[55] S. Cheng, L. Zhang, H. Xia, J. Peng, J. Shu, C. Li, X. Jiang, Q. Zhang, Adsorption behavior of methylene blue onto waste-derived adsorbent and exhaust gases recycling, RSC Adv. 7(44) (2017) 27331-27341.
[56] M. Cheng, G. Zeng, D. Huang, C. Lai, Y. Liu, C. Zhang, R. Wang, L. Qin, W. Xue, B. Song, S. Ye, H. Yi, High adsorption of methylene blue by salicylic acid-methanol modified steel converter slag and evaluation of its mechanism, J. Colloid Interface Sci. 515(2018) 232-239.
[57] S.N.M. Suhaimy, L.C. Abdullah, Removal of methylene blue from aqueous solution by using electrical arc furnace (EAF) slag, Indones. J. Chem. 20(1) (2020) 113.
[58] A.S. Dhmees, N.M. Khaleel, S.A. Mahmoud, Synthesis of silica nanoparticles from blast furnace slag as cost-effective adsorbent for efficient azo-dye removal, Egypt. J. Pet. 27(4) (2018) 1113-1121.
[59] Y.J.C. Martins, A.C.M. Almeida, B.M. Viegas, R.A. do Nascimento, N.F.D.P. Ribeiro, Use of red mud from amazon region as an adsorbent for the removal of methylene blue: process optimization, isotherm and kinetic studies, Int. J. Environ. Sci. Technol. 17(10) (2020) 4133-4148.
[60] C.H. Weng, Y.F. Pan, Adsorption characteristics of methylene blue from aqueous solution by sludge ash, Colloids Surf. A Physicochem. Eng. Asp. 274(1-3) (2006) 154-162.
[61] F.T. Senberber, M. Yildirim, N.K. Mermer, E.M. Derun, Adsorption of Cr(III) from aqueous solution using borax sludge, Acta Chim. Slov. 64(2017) 654-660.
[62] A.I. Ferraz, C. Amorim, T. Tavares, J.A. Teixeira, Chromium(III) biosorption onto spent grains residual from brewing industry: equilibrium, kinetics and column studies, Int. J. Environ. Sci. Technol. 12(5) (2015) 1591-1602.
[63] Z.H. Yang, S. Xiong, B. Wang, Q. Li, W.C. Yang, Cr(III) adsorption by sugarcane pulp residue and biochar, J. Cent. South Univ. 20(5) (2013) 1319-1321.
[64] V.K. Gupta, I. Ali, Removal of lead and chromium from wastewater using bagasse fly ash- A sugar industry waste, J. Colloid Interface Sci. 271(2) (2004) 321-328.
[65] A. Oumani, L. Mandi, F. Berrekhis, N. Ouazzani, Removal of Cr³⁺ from tanning effluents by adsorption onto phosphate mine waste: Key parameters and mechanisms, J. Hazard. Mater. 378(2019) 120718.

Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples

Sulfamic acid functionalized slag for effective removal of organic dye and toxic metal from the aqueous samples

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions[J]. 中国化学工程学报, 2023, 60(8): 26-36.
[2]	Chuang Liang, Zhihao Liu, Baochang Sun, Haikui Zou, Guangwen Chu. Improvement in discharge characteristics and energy yield of ozone generation via configuration optimization of a coaxial dielectric barrier discharge reactor[J]. 中国化学工程学报, 2023, 60(8): 61-68.
[3]	Jing Huang, Honghui Cai, Qian Zhao, Yunpeng Zhou, Haibo Liu, Jing Wang. Dual-functional pyrene implemented mesoporous silicon material used for the detection and adsorption of metal ions[J]. 中国化学工程学报, 2023, 60(8): 108-117.
[4]	Eileen Katherine Coronado-Aldana, Cindy Lizeth Ferreira-Salazar, Nubia Yineth Piñeros-Castro, Rubén Vázquez-Medina, Felipe A. Perdomo. Thermodynamic analysis, synthesis, characterization, and evaluation of 1-ethyl-3-methylimidazolium chloride: Study of its effect on pretreated rice husk[J]. 中国化学工程学报, 2023, 60(8): 143-154.
[5]	Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. 中国化学工程学报, 2023, 60(8): 212-227.
[6]	Alexander Nti Kani, Evans Dovi, Aaron Albert Aryee, Runping Han, Zhaohui Li, Lingbo Qu. Mechanisms and reusability potentials of zirconium-polyaziridine-engineered tiger nut residue towards anionic pollutants[J]. 中国化学工程学报, 2023, 60(8): 275-292.
[7]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework[J]. 中国化学工程学报, 2023, 59(7): 9-15.
[8]	Hui Jiang, Zijian Zhao, Ning Yu, Yi Qin, Zhengwei Luo, Wenhua Geng, Jianliang Zhu. Synthesis, characterization, and performance comparison of boron using adsorbents based on N-methyl-D-glucosamine[J]. 中国化学工程学报, 2023, 59(7): 16-31.
[9]	Yaran Bu, Changchun Wu, Lili Zuo, Qian Chen. The calculation and optimal allocation of transmission capacity in natural gas networks with MINLP models[J]. 中国化学工程学报, 2023, 59(7): 251-261.
[10]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application[J]. 中国化学工程学报, 2023, 59(7): 262-269.
[11]	Shanghong Ma, Haitao Zhang, Jianbo Qu, Xiuzhong Zhu, Qingfei Hu, Jianyong Wang, Peng Ye, Futao Sai, Shiwei Chen. Preparation of waterborne polyurethane/β-cyclodextrin composite nanosponge by ion condensation method and its application in removing of dyes from wastewater[J]. 中国化学工程学报, 2023, 58(6): 124-136.
[12]	Danlei Chen, Yiqing Luo, Xigang Yuan. Cascade refrigeration system synthesis based on hybrid simulated annealing and particle swarm optimization algorithm[J]. 中国化学工程学报, 2023, 58(6): 244-255.
[13]	Haike Li, Xindong Li, Guozai Ouyang, Lang Li, Zhaohuang Zhong, Meng Cai, Wenhao Li, Wanfu Huang. Tannic acid/Fe³⁺ interlayer for preparation of high-permeability polyetherimide organic solvent nanofiltration membranes for organic solvent separation[J]. 中国化学工程学报, 2023, 57(5): 17-29.
[14]	Yueting Shi, Junhai Zhao, Lingli Chen, Hongru Li, Shengtao Zhang, Fang Gao. Double open mouse-like terpyridine parts based amphiphilic ionic molecules displaying strengthened chemical adsorption for anticorrosion of copper in sulfuric acid solution[J]. 中国化学工程学报, 2023, 57(5): 233-246.
[15]	Jian Wang, Yuanhui Shen, Donghui Zhang, Zhongli Tang, Wenbin Li. Integrated vacuum pressure swing adsorption and Rectisol process for CO₂ capture from underground coal gasification syngas[J]. 中国化学工程学报, 2023, 57(5): 265-279.