Effect of operating parameters on the performance of thermally regenerative ammonia-based battery for low-temperature waste heat recovery

doi:10.1016/j.cjche.2020.09.031

中国化学工程学报 ›› 2021, Vol. 32 ›› Issue (4): 335-340.DOI: 10.1016/j.cjche.2020.09.031

• Energy, Resources and Environmental Technology • 上一篇下一篇

Effect of operating parameters on the performance of thermally regenerative ammonia-based battery for low-temperature waste heat recovery

Yu Shi, Liang Zhang, Jun Li, Qian Fu, Xun Zhu, Qiang Liao, Yongsheng Zhang

Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education, Chongqing 400030, China;Institute of Engineering Thermophysics, School of Energy and Power Engineering, Chongqing University, Chongqing 400030, China

收稿日期:2019-12-02 修回日期:2020-09-09 出版日期:2021-04-28 发布日期:2021-06-19
通讯作者: Liang Zhang
基金资助:
This work was supported by the National Natural Science Foundation of China (No. 51976018), the National Natural Science Foundation for Young Scientists of China (No. 51606022), Natural Science Foundation of Chongqing, China (No. cstc2017jcyjAX0203), Scientific Research Foundation for Returned Overseas Chinese Scholars of Chongqing, China (No. cx2017020), the Fundamental Research Funds for the Central Universities (No. 106112016CDJXY145504) and Research Funds of Key Laboratory of Low-grade Energy Utilization Technologies and Systems (No. LLEUTS-2018005).

Effect of operating parameters on the performance of thermally regenerative ammonia-based battery for low-temperature waste heat recovery

Yu Shi, Liang Zhang, Jun Li, Qian Fu, Xun Zhu, Qiang Liao, Yongsheng Zhang

Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education, Chongqing 400030, China;Institute of Engineering Thermophysics, School of Energy and Power Engineering, Chongqing University, Chongqing 400030, China

Received:2019-12-02 Revised:2020-09-09 Online:2021-04-28 Published:2021-06-19
Contact: Liang Zhang
Supported by:
This work was supported by the National Natural Science Foundation of China (No. 51976018), the National Natural Science Foundation for Young Scientists of China (No. 51606022), Natural Science Foundation of Chongqing, China (No. cstc2017jcyjAX0203), Scientific Research Foundation for Returned Overseas Chinese Scholars of Chongqing, China (No. cx2017020), the Fundamental Research Funds for the Central Universities (No. 106112016CDJXY145504) and Research Funds of Key Laboratory of Low-grade Energy Utilization Technologies and Systems (No. LLEUTS-2018005).

摘要/Abstract

摘要： This study investigated the important factors that affect the operating parameters of thermally regenerative ammonia-based batteries (TRABs), including the metal electrode type, membrane type, electrode surface area, electrode distance, electrolyte concentration, and ammonia concentration. The experimental results showed that the maximum power density of TRABs with a Cu electrode was 40.0 W·m^-2, which was considerably higher than that with Ni (0.34 W·m^-2) and Co (0.14 W·m^-2) electrodes. TRABs with an anion exchange membrane had a 28.6% higher maximum power density than those with a cation exchange membrane. An increased electrode surface resulted in an increased maximum power but a decreased maximum power density. Within a certain range, TRAB performance was enhanced with decreased electrode distance and increased electrolyte concentration. An increased ammonia concentration resulted in enhanced ammonia transfer and improved the TRAB performance.

关键词: Electrochemistry, Thermally regenerative ammonia-based, battery, Recovery, Renewable energy

Abstract: This study investigated the important factors that affect the operating parameters of thermally regenerative ammonia-based batteries (TRABs), including the metal electrode type, membrane type, electrode surface area, electrode distance, electrolyte concentration, and ammonia concentration. The experimental results showed that the maximum power density of TRABs with a Cu electrode was 40.0 W·m^-2, which was considerably higher than that with Ni (0.34 W·m^-2) and Co (0.14 W·m^-2) electrodes. TRABs with an anion exchange membrane had a 28.6% higher maximum power density than those with a cation exchange membrane. An increased electrode surface resulted in an increased maximum power but a decreased maximum power density. Within a certain range, TRAB performance was enhanced with decreased electrode distance and increased electrolyte concentration. An increased ammonia concentration resulted in enhanced ammonia transfer and improved the TRAB performance.

Key words: Electrochemistry, Thermally regenerative ammonia-based, battery, Recovery, Renewable energy

Yu Shi, Liang Zhang, Jun Li, Qian Fu, Xun Zhu, Qiang Liao, Yongsheng Zhang. Effect of operating parameters on the performance of thermally regenerative ammonia-based battery for low-temperature waste heat recovery[J]. 中国化学工程学报, 2021, 32(4): 335-340.

参考文献

[1] Y. Yang, S.W. Lee, H. Ghasemi, J. Loomis, X.B. Li, D. Kraemer, G. Zheng, G.Y. Cui, G. Chen, Charging-free electrochemical system for harvesting low-grade thermal energy, Proc. Natl. Acad. Sci. 111(2014) 17011-17016.
[2] S. Chu, A. Majumdar, Opportunities and challenges for a sustainable energy future, Nature 488(2012) 294-303.
[3] M. Imran, F. Haglind, M. Asim, J.Z. Alvi, Recent research trends in organic Rankine cycle technology:A bibliometric approach, Renew. Sust. Energ. Rev. 81(2018) 552-562.
[4] S. Saini, H.S. Yaddanapudi, K. Tian, Y. Yin, D. Magginetti, A. Tiwari, Terbium ion doping in Ca₃Co₄O₉:A step towards high-performance thermoelectric materials, Sci. Rep. 7(2017) 44621.
[5] M. Rahimi, A.P. Straub, F. Zhang, X.P. Zhu, M. Elimelech, C.A. Gorski, B.E. Logan, Emerging electrochemical and membrane-based systems to convert low-grade heat to electricity, Energ Environ. Sci. 11(2018) 276-285.
[6] E. Mu, G. Yang, X. Fu, F. Wang, Z. Hu, Fabrication and characterization of ultrathin thermoelectric device for energy conversion, J. Power Sources 394(2018) 17-25.
[7] F. Zhang, J. Liu, W. Yang, B.E. Logan, A thermally regenerative ammonia-based battery for efficient harvesting of low-grade thermal energy as electrical power, Energ Environ. Sci. 8(2015) 343-349.
[8] F. Zhang, N. LaBarge, W. Yang, J. Liu, B.E. Logan, Enhancing low-grade thermal energy recovery in a thermally regenerative ammonia battery using elevated temperatures, ChemSusChem 8(2015) 1043-1048.
[9] M. Rahimi, L. Zhu, K.L. Kowalski, X.P. Zhu, C.A. Gorski, M.A. Hickner, B.E. Logan, Improved electrical power production of thermally regenerative batteries using a poly(phenylene oxide) based anion exchange membrane, J. Power Sources 342(2017) 956-963.
[10] X.P. Zhu, M. Rahimi, C.A. Gorski, B.E. Logan, A thermally-regenerative ammonia-based flow battery for electrical energy recovery from waste heat, ChemSusChem 9(2016) 873-879.
[11] V.M. Palakkal, T. Nguyen, P. Nguyen, M. Chernova, J.E. Rubio, G. Venugopalan, M. Hatzell, X.P. Zhu, C.G. Arges, High power thermally regenerative ammoniacopper redox flow battery enabled by a zero gap cell design, low-resistant membranes, and electrode coatings, ACS Appl. Energy Mater. 3(2020) 4787-4798.
[12] M. Rahimi, A. D'Angelo, C.A. Gorski, O. Scialdone, B.E. Logan, Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery, J. Power Sources 351(2017) 45-50.
[13] M. Rahimi, T. Kim, C.A. Gorski, B.E. Logan, A thermally regenerative ammonia battery with carbon-silver electrodes for converting low-grade waste heat to electricity, J. Power Sources 373(2018) 95-102.
[14] W.G. Wang, H. Tian, G.Q. Shu, D.Q. Huo, F. Zhang, X.P. Zhu, A bimetallic thermally regenerative ammonia-based battery for high power density and efficiently harvesting low-grade thermal energy, J. Mater Chem A. 7(2019) 5991-6000.
[15] W.G. Wang, G.Q. Shu, H. Tian, D.Q. Huo, X.P. Zhu, A bimetallic thermallyregenerative ammonia-based flow battery for low-grade waste heat recovery, J. Power Sources 424(2019) 184-192.
[16] W.G. Wang, G.Q. Shu, X.P. Zhu, H. Tian, Decoupled electrolytes towards enhanced energy and high temperature performance of thermally regenerative ammonia batteries, J. Mater. Chem. A 8(2020) 12351.
[17] L. Zhang, Y.X. Li, X. Zhu, J. Li, Q. Fu, Q. Liao, Z.D. Wei, Copper foam electrodes for increased power generation in thermally regenerative ammonia-based batteries for low-grade waste heat recovery, Ind. Eng. Chem. Res. 58(2019) 7408-7415.
[18] Y.S. Zhang, L. Zhang, J. Li, X. Zhu, Q. Fu, Q. Liao, Y. Shi, Performance of a thermally regenerative ammonia-based flow battery with 3D porous electrodes:Effect of reactor and electrode design, Electrochim. Acta 331(2020) 135442.
[19] Y. Shi, L. Zhang, J. Li, Q. Fu, X. Zhu, Q. Liao, Y.S. Zhang, 3-D printed gradient porous composite electrodes improve anodic current distribution and performance in thermally regenerative flow battery for low-grade waste heat recovery, J. Power Sources 473(2020), 228525.
[20] Y. Shi, L. Zhang, J. Li, Q. Fu, X. Zhu, Q. Liao, Y.S. Zhang, Cu/Ni composite electrodes for increased anodic coulombic efficiency and electrode operation time in a thermally regenerative ammonia-based battery for converting lowgrade waste heat into electricity, Renew. Energ. 159(2020) 162-171.
[21] R. Wang, Y.S. Li, Twin-cocoon-derived self-standing nitrogen-oxygen-rich monolithic carbon material as the cost-effective electrode for redox flow batteries, J. Power Sources 421(2019) 139-146.
[22] L. Zhang, J. Li, X. Zhu, D.D. Ye, Q. Liao, Anodic current distribution in a literscale microbial fuel cell with electrode arrays, Chem. Eng. J. 223(2013) 623-631.
[23] H. Liu, S.A. Chen, L.P. Huang, B.E. Logan, Scale-up of membrane-free singlechamber microbial fuel cells, J. Power Sources 179(2008) 274-279.
[24] J. Li, L.B. Hu, L. Zhang, D.D. Ye, X. Zhu, Q. Liao, Uneven biofilm and current distribution in three-dimensional macroporous anodes of bio-electrochemical systems composed of graphite electrode arrays, Bioresour. Technol. 228(2017) 25-30.

Effect of operating parameters on the performance of thermally regenerative ammonia-based battery for low-temperature waste heat recovery

Effect of operating parameters on the performance of thermally regenerative ammonia-based battery for low-temperature waste heat recovery

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