SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2021, Vol. 35 ›› Issue (7): 17-43.DOI: 10.1016/j.cjche.2020.11.028

• Review • 上一篇    下一篇

The latest development on amine functionalized solid adsorbents for post-combustion CO2 capture: Analysis review

Peiyu Zhao1,2, Guojie Zhang2, Huangyu Yan2, Yuqiong Zhao2   

  1. 1. Heze Branch, Qilu University of Technology (Shandong Academy of Sciences), Biological Engineering Technology Innovation Center of Shandong Province, Heze 274000, China;
    2. Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China
  • 收稿日期:2020-06-07 修回日期:2020-10-06 出版日期:2021-07-28 发布日期:2021-09-30
  • 通讯作者: Guojie Zhang
  • 基金资助:
    This work was supported by the National Natural Science Foundation of China (21878200 and 21676174), International S&T Cooperation Program of Shanxi province (201703D421038), Shanxi Scholarship Council of China (2017-036), and Joint Fund of Shanxi Provincial Coal Seam Gas (2015012019).

The latest development on amine functionalized solid adsorbents for post-combustion CO2 capture: Analysis review

Peiyu Zhao1,2, Guojie Zhang2, Huangyu Yan2, Yuqiong Zhao2   

  1. 1. Heze Branch, Qilu University of Technology (Shandong Academy of Sciences), Biological Engineering Technology Innovation Center of Shandong Province, Heze 274000, China;
    2. Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China
  • Received:2020-06-07 Revised:2020-10-06 Online:2021-07-28 Published:2021-09-30
  • Contact: Guojie Zhang
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (21878200 and 21676174), International S&T Cooperation Program of Shanxi province (201703D421038), Shanxi Scholarship Council of China (2017-036), and Joint Fund of Shanxi Provincial Coal Seam Gas (2015012019).

摘要: Global warming and associated global climate change have led to serious efforts towards reducing CO2 emissions through the CO2 capture from the major emission sources. CO2 capture using the amine functionalized adsorbents is regard as a direct and effective way to reducing CO2 emissions due to their large CO2 adsorption amount, excellent CO2 adsorption selectivity and lower energy requirements for adsorbent regeneration. Moreover, large number of achievements on the amine functionalized solid adsorbent have been recorded for the enhanced CO2 capture in the past few years. In view of this, we review and analyze the recent advances in amine functionalized solid adsorbents prepared with different supporting materials including mesoporous silica, zeolite, porous carbon materials, metal organic frameworks(MOF) and other composite porous materials. In addition, amine functionalized solid adsorbents derived from waste resources are also reviewed because of the large number demand for cost-effective carbon dioxide adsorbents and the processing needs of waste resources. Considering the importance of the stability of the adsorbent in practical applications, advanced research in the capture cycle stability has also been summarized and analyzed. Finally, we summarize the review and offer the recommendations for the development of amine-based solid adsorbents for carbon dioxide capture.

关键词: Solid adsorbents, Amine functionalized, CO2 capture, Adsorption, Review

Abstract: Global warming and associated global climate change have led to serious efforts towards reducing CO2 emissions through the CO2 capture from the major emission sources. CO2 capture using the amine functionalized adsorbents is regard as a direct and effective way to reducing CO2 emissions due to their large CO2 adsorption amount, excellent CO2 adsorption selectivity and lower energy requirements for adsorbent regeneration. Moreover, large number of achievements on the amine functionalized solid adsorbent have been recorded for the enhanced CO2 capture in the past few years. In view of this, we review and analyze the recent advances in amine functionalized solid adsorbents prepared with different supporting materials including mesoporous silica, zeolite, porous carbon materials, metal organic frameworks(MOF) and other composite porous materials. In addition, amine functionalized solid adsorbents derived from waste resources are also reviewed because of the large number demand for cost-effective carbon dioxide adsorbents and the processing needs of waste resources. Considering the importance of the stability of the adsorbent in practical applications, advanced research in the capture cycle stability has also been summarized and analyzed. Finally, we summarize the review and offer the recommendations for the development of amine-based solid adsorbents for carbon dioxide capture.

Key words: Solid adsorbents, Amine functionalized, CO2 capture, Adsorption, Review