SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2021, Vol. 29 ›› Issue (2): 4-13.DOI: 10.1016/j.cjche.2020.12.009

• Synthetic Biotechnology and Metabolic Engineering • 上一篇    下一篇

The production of biobased diamines from renewable carbon sources: Current advances and perspectives

Xin Wang1,2, Siyuan Gao1, Jing Wang1, Sheng Xu1, Hui Li1, Kequan Chen1, Pingkai Ouyang1   

  1. 1 State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China;
    2 Zhejiang Zhongshan Chemical Industry Group Co. Ltd, Huzhou 313100, China
  • 收稿日期:2020-10-15 修回日期:2020-12-05 出版日期:2021-02-28 发布日期:2021-05-15
  • 通讯作者: Pingkai Ouyang
  • 基金资助:
    This work was supported by the National Key Research and Development Program of China (Grant No. 2018YFA0901500), National Nature Science Foundation of China (Grant No. 21606127, Grant No. 21706126), and Jiangsu synergetic innovation center for advanced bio-manufacture (Grant No. XTB1802, Grant No. XTE1844).

The production of biobased diamines from renewable carbon sources: Current advances and perspectives

Xin Wang1,2, Siyuan Gao1, Jing Wang1, Sheng Xu1, Hui Li1, Kequan Chen1, Pingkai Ouyang1   

  1. 1 State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China;
    2 Zhejiang Zhongshan Chemical Industry Group Co. Ltd, Huzhou 313100, China
  • Received:2020-10-15 Revised:2020-12-05 Online:2021-02-28 Published:2021-05-15
  • Contact: Pingkai Ouyang
  • Supported by:
    This work was supported by the National Key Research and Development Program of China (Grant No. 2018YFA0901500), National Nature Science Foundation of China (Grant No. 21606127, Grant No. 21706126), and Jiangsu synergetic innovation center for advanced bio-manufacture (Grant No. XTB1802, Grant No. XTE1844).

摘要: Bio-based diamines are considered to be a promising alternative to traditional fossil-fuel-based diamines, the important platform chemical for the synthesis of polymer materials. In this review, the current status of the art of the synthesis of aliphatic and aromatic diamines from renewable biomass are considered. In the case of aliphatic diamines, we describe strategies for biologically producing diamines with different carbon numbers including 1,3-diaminopropane, 1,4-butanediamine, 1,5-pentanediamine, 1,6-diaminohexane, 1,8-diaminooctane, 1,10-diaminodecane, and 1,12-diaminododecane. In addition, aromatic diamines produced from various kinds of renewable biomass, including lignin, cashew nut shell, and terpenoids, are reviewed here. Furthermore, the application of typical diamines in synthesis of polyurethane and polyamide are also reviewed.

关键词: Aliphatic diamines, Aromatic diamines, Polyamide, Polyurethane

Abstract: Bio-based diamines are considered to be a promising alternative to traditional fossil-fuel-based diamines, the important platform chemical for the synthesis of polymer materials. In this review, the current status of the art of the synthesis of aliphatic and aromatic diamines from renewable biomass are considered. In the case of aliphatic diamines, we describe strategies for biologically producing diamines with different carbon numbers including 1,3-diaminopropane, 1,4-butanediamine, 1,5-pentanediamine, 1,6-diaminohexane, 1,8-diaminooctane, 1,10-diaminodecane, and 1,12-diaminododecane. In addition, aromatic diamines produced from various kinds of renewable biomass, including lignin, cashew nut shell, and terpenoids, are reviewed here. Furthermore, the application of typical diamines in synthesis of polyurethane and polyamide are also reviewed.

Key words: Aliphatic diamines, Aromatic diamines, Polyamide, Polyurethane