A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water

doi:10.1016/j.cjche.2021.08.021

中国化学工程学报 ›› 2022, Vol. 42 ›› Issue (2): 424-436.DOI: 10.1016/j.cjche.2021.08.021

A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water

Yang Chen¹, Lanying Jiang^1,2,3

1. School of Metallurgy and Environment, Central South University, Changsha 410083, China;
2. National Engineering Research Center for Control & Treatment of Heavy Metal Pollution, Changsha 410083 China;
3. Key Laboratory of Hunan Province for Water Environment and Agriculture Product Safety, Changsha 410000, China

收稿日期:2021-04-06 修回日期:2021-07-25 出版日期:2022-02-28 发布日期:2022-03-30
通讯作者: Lanying Jiang,E-mail:jianglanyingsme@csu.edu.cn
基金资助:
This work was supported by the Fundamental Research Funds for the Central Universities of Central South University (10400506021718) and Hunan Provincial Science and Technology Project (2018TP1003).

A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water

Yang Chen¹, Lanying Jiang^1,2,3

1. School of Metallurgy and Environment, Central South University, Changsha 410083, China;
2. National Engineering Research Center for Control & Treatment of Heavy Metal Pollution, Changsha 410083 China;
3. Key Laboratory of Hunan Province for Water Environment and Agriculture Product Safety, Changsha 410000, China

Received:2021-04-06 Revised:2021-07-25 Online:2022-02-28 Published:2022-03-30
Contact: Lanying Jiang,E-mail:jianglanyingsme@csu.edu.cn
Supported by:
This work was supported by the Fundamental Research Funds for the Central Universities of Central South University (10400506021718) and Hunan Provincial Science and Technology Project (2018TP1003).

摘要/Abstract

摘要： An affinity membrane was prepared by coaxial electrospinning and amidoxime (AONFA), and it was applied to selectively recovery Au (III) from an aqueous solution. The static adsorption results showed that, when pH at 5, the maximum adsorption capacity of AONFA membrane for Au (III) was 509.3 mg·g^-1. AONFA membrane exhibit much higher affinity and selectivity towards Au (III) than other metal cations. The membrane could be regenerated effectively by mixture solution of thiourea and HCl, and the desorption ratio reached almost 100% after 4 hours desorption. The dead-end filtration results showed that, the membrane utilization efficiency and adsorption capacity can be improved by increasing the flow rate, while increasing the concentration shorted the breakthrough process and had little impact to adsorption capacity. We can flexibly adjust the flow rate and concentration according to the situation to obtain the maximum utilization efficiency of the membrane in filtration process. The dynamic adsorption capacity is higher than the static adsorption capacity. The adsorption mechanism for Au (III) is electrostatic adsorption and reduction. Thus, AONFA membrane filtration was demonstrated to be a promising method for continuous recover Au (III) from wastewater.

关键词: Coaxial electrospinning, Amidoxime, Affinity membrane, Gold recovery

Abstract: An affinity membrane was prepared by coaxial electrospinning and amidoxime (AONFA), and it was applied to selectively recovery Au (III) from an aqueous solution. The static adsorption results showed that, when pH at 5, the maximum adsorption capacity of AONFA membrane for Au (III) was 509.3 mg·g^-1. AONFA membrane exhibit much higher affinity and selectivity towards Au (III) than other metal cations. The membrane could be regenerated effectively by mixture solution of thiourea and HCl, and the desorption ratio reached almost 100% after 4 hours desorption. The dead-end filtration results showed that, the membrane utilization efficiency and adsorption capacity can be improved by increasing the flow rate, while increasing the concentration shorted the breakthrough process and had little impact to adsorption capacity. We can flexibly adjust the flow rate and concentration according to the situation to obtain the maximum utilization efficiency of the membrane in filtration process. The dynamic adsorption capacity is higher than the static adsorption capacity. The adsorption mechanism for Au (III) is electrostatic adsorption and reduction. Thus, AONFA membrane filtration was demonstrated to be a promising method for continuous recover Au (III) from wastewater.

Key words: Coaxial electrospinning, Amidoxime, Affinity membrane, Gold recovery

Yang Chen, Lanying Jiang. A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water[J]. 中国化学工程学报, 2022, 42(2): 424-436.

Yang Chen, Lanying Jiang. A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water[J]. Chinese Journal of Chemical Engineering, 2022, 42(2): 424-436.

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A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water

A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (III) from water

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