SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 205-214.DOI: 10.1016/j.cjche.2022.05.016

• Catalysis, Kinetics and Reaction Engineering • 上一篇    下一篇

Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

Zhiwei Wang, Jiannan Shi, Xiaonan Liu, Zhikai Cao, Yong Sha   

  1. Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
  • 收稿日期:2022-03-13 修回日期:2022-05-14 出版日期:2022-10-28 发布日期:2023-01-04
  • 通讯作者: Yong Sha,E-mail:ysha@xmu.edu.cn
  • 基金资助:
    The authors acknowledge financial support provided by the National Natural Science Foundation of China (No. 21978243).

Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate

Zhiwei Wang, Jiannan Shi, Xiaonan Liu, Zhikai Cao, Yong Sha   

  1. Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
  • Received:2022-03-13 Revised:2022-05-14 Online:2022-10-28 Published:2023-01-04
  • Contact: Yong Sha,E-mail:ysha@xmu.edu.cn
  • Supported by:
    The authors acknowledge financial support provided by the National Natural Science Foundation of China (No. 21978243).

摘要: In this work, a strategy of “etching-modification filling-graft copolymerization” was proposed to load the acidic ionic polyionic liquid on the smooth ceramic surface. In this way, commercial ceramic Raschig rings were successfully transformed into the supported catalytic packing for the reactive distillation, and were further evaluated with esterification reaction of ethyl acetate by means of the fully mixed reactor, the ultrasonic destruction, the cyclic catalysis reaction and the lab-scale distillation column experiment. This catalyst coating has good adhesion with the substrate. It can withstand 24 h of ultrasound damage and shows good stability in three cycle catalytic experiments. This kind of coated catalyst has better catalytic activity than the commercial Amberlyst 15 dry. In the lab-scale reaction distillation, the supported catalyst Raschig ring can achieve a higher conversion in comparison with the tea bag catalytic packing of Amberlyst 15 dry under some conditions.

关键词: Supported catalytic packing, Ethyl acetate, Reactive distillation, Bonding strength

Abstract: In this work, a strategy of “etching-modification filling-graft copolymerization” was proposed to load the acidic ionic polyionic liquid on the smooth ceramic surface. In this way, commercial ceramic Raschig rings were successfully transformed into the supported catalytic packing for the reactive distillation, and were further evaluated with esterification reaction of ethyl acetate by means of the fully mixed reactor, the ultrasonic destruction, the cyclic catalysis reaction and the lab-scale distillation column experiment. This catalyst coating has good adhesion with the substrate. It can withstand 24 h of ultrasound damage and shows good stability in three cycle catalytic experiments. This kind of coated catalyst has better catalytic activity than the commercial Amberlyst 15 dry. In the lab-scale reaction distillation, the supported catalyst Raschig ring can achieve a higher conversion in comparison with the tea bag catalytic packing of Amberlyst 15 dry under some conditions.

Key words: Supported catalytic packing, Ethyl acetate, Reactive distillation, Bonding strength