High-temperature CO2 sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

doi:10.1016/j.cjche.2022.09.005

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 177-184.DOI: 10.1016/j.cjche.2022.09.005

• Separation Science and Engineering • 上一篇下一篇

High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

Tao Jiang, Fei Xiao, Yujun Zhao, Shengping Wang, Xinbin Ma

Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China

收稿日期:2022-03-31 修回日期:2022-09-23 出版日期:2022-10-28 发布日期:2023-01-04
通讯作者: Shengping Wang,E-mail:spwang@tju.edu.cn
基金资助:
Financial support by National Key Research and Development Program of China (2017YFB0603300), the Program for New Century Excellent Talents in University (NCET-13-0411) and the Program of Introducing Talents of Discipline to Universities (B06006) is gratefully acknowledged.

High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

Tao Jiang, Fei Xiao, Yujun Zhao, Shengping Wang, Xinbin Ma

Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China

Received:2022-03-31 Revised:2022-09-23 Online:2022-10-28 Published:2023-01-04
Contact: Shengping Wang,E-mail:spwang@tju.edu.cn
Supported by:
Financial support by National Key Research and Development Program of China (2017YFB0603300), the Program for New Century Excellent Talents in University (NCET-13-0411) and the Program of Introducing Talents of Discipline to Universities (B06006) is gratefully acknowledged.

摘要/Abstract

摘要： CO₂, one of the main components of greenhouse gases, increased rapidly because of the growing use of fossil fuels. And CaO sorbents possess the capability to be used in capture of CO₂ at high temperature. In the work, Ca—Al complex oxides derived from citrate and stearate intercalated layered double hydroxides were fabricated and their CO₂ adsorption capacity was compared with that from CO₃^2- intercalated layered double hydroxides. The results presented that the sorbents (Ca/Al = 5) with Ca—Al—citrate layered double hydroxides as precursors performed best and displayed remarkable CO₂ capture capacity of 52.0% (mass) at the carbonization temperature of 600 ℃ without distinct recession during cycling adsorption/desorption tests. The excellent CO₂ adsorption capacity of the sorbent was ascribed to its smaller crystallite size of calcinated particles, optimized pore size distribution as well as homogeneous distributed Ca and Al in the sorbent.

关键词: Layered double hydroxides, CO₂ capture, CaO-based, Organic ions

Abstract: CO₂, one of the main components of greenhouse gases, increased rapidly because of the growing use of fossil fuels. And CaO sorbents possess the capability to be used in capture of CO₂ at high temperature. In the work, Ca—Al complex oxides derived from citrate and stearate intercalated layered double hydroxides were fabricated and their CO₂ adsorption capacity was compared with that from CO₃^2- intercalated layered double hydroxides. The results presented that the sorbents (Ca/Al = 5) with Ca—Al—citrate layered double hydroxides as precursors performed best and displayed remarkable CO₂ capture capacity of 52.0% (mass) at the carbonization temperature of 600 ℃ without distinct recession during cycling adsorption/desorption tests. The excellent CO₂ adsorption capacity of the sorbent was ascribed to its smaller crystallite size of calcinated particles, optimized pore size distribution as well as homogeneous distributed Ca and Al in the sorbent.

Key words: Layered double hydroxides, CO₂ capture, CaO-based, Organic ions

Tao Jiang, Fei Xiao, Yujun Zhao, Shengping Wang, Xinbin Ma. High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor[J]. 中国化学工程学报, 2022, 50(10): 177-184.

Tao Jiang, Fei Xiao, Yujun Zhao, Shengping Wang, Xinbin Ma. High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor[J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 177-184.

参考文献

[1] H. Lu, E.P. Reddy, P.G. Smirniotis, Calcium oxide based sorbents for capture of carbon dioxide at high temperatures, Ind. Eng. Chem. Res. 45 (11) (2006) 3944-3949
[2] W. Liu, Y. Wu, T.Y. Cai, X.P. Chen, D. Liu, Use of nanoparticles Cu/TiO(OH)2 for CO₂ removal with K₂CO₃/KHCO₃ based solution:Enhanced thermal conductivity and reaction kinetics enhancing the CO₂ sorption/desorption performance of K₂CO₃/KHCO₃, Greenh. Gases Sci. Technol. 9 (1) (2019) 10-18
[3] T. Luo, S.L. Liu, C. Luo, X.L. Qi, B.W. Lu, L.Q. Zhang, Effect of different organic compounds on the preparation of CaO-based CO₂ sorbents derived from wet mixing combustion synthesis, Chin. J. Chem. Eng. 36 (2021) 157-169
[4] X.Y. Zhang, Z.G. Li, Y. Peng, W.K. Su, X.X. Sun, J.H. Li, Investigation on a novel CaO-Y₂O₃ sorbent for efficient CO₂ mitigation, Chem. Eng. J. 243 (2014) 297-304
[5] Q.L. Zhao, Q.Y. Wang, C. Zhang, Z.J. Du, M. Tian, J.G. Mi, Effect of chain topology of polyethylenimine on physisorption and chemisorption of carbon dioxide, ChemPhysChem 16 (7) (2015) 1480-1490
[6] H.X. Guo, X. Wang, H. Wang, W.Q. Cui, M. Li, W.L. Xie, Double-exchange-induced effective increased CO₂ capture of CaO by doping bimetallic oxides with variable valence state, Chem. Eng. J. 433 (2022) 134490
[7] L.J. Nie, L. Bai, J. Chen, J.S. Jin, J.G. Mi, Grafting poly(ethyleneimine) on the pore surface of poly(glycidyl methacrylate-trimethylolpropane triacrylate) for preparation of the CO₂ sorbent, Energy Fuels 33 (12) (2019) 12610-12620
[8] A.K. Mishra, S. Ramaprabhu, Nanostructured polyaniline decorated graphene sheets for reversible CO₂ capture, J. Mater. Chem. 22 (9) (2012) 3708-3712
[9] C.C. Li, J.Y. Cheng, W.H. Liu, C.M. Huang, H.W. Hsu, H.P. Lin, Enhancement in cyclic stability of the CO₂ adsorption capacity of CaO-based sorbents by hydration for the calcium looping cycle, J. Taiwan Inst. Chem. Eng. 45 (1) (2014) 227-232
[10] S.F. Wu, T.H. Beum, J.I. Yang, J.N. Kim, Properties of Ca-base CO₂ sorbent using Ca(OH)2 as precursor, Ind. Eng. Chem. Res. 46 (24) (2007) 7896-7899
[11] K.S. Sultana, D. Chen, Enhanced hydrogen production by in situ CO₂ removal on CaCeZrOx nanocrystals, Catal. Today 171 (1) (2011) 43-51
[12] H.X. Guo, J.Q. Feng, Y.J. Zhao, S.P. Wang, X.B. Ma, Effect of micro-structure and oxygen vacancy on the stability of (Zr-Ce)-additive CaO-based sorbent in CO₂ adsorption, J. CO₂ Util. 19 (2017) 165-176
[13] G.K. Reddy, S. Quillin, P. Smirniotis, Influence of the synthesis method on the structure and CO₂ adsorption properties of Ca/Zr sorbents, Energy Fuels 28 (5) (2014) 3292-3299
[14] S.P. Wang, L.J. Fan, C. Li, Y.J. Zhao, X.B. Ma, Porous spherical CaO-based sorbents via PSS-assisted fast precipitation for CO₂ capture, ACS Appl. Mater. Interfaces 6 (20) (2014) 18072-18077
[15] R.Y. Sun, H.L. Zhu, R. Xiao, Enhancement of CO₂ capture and microstructure evolution of the spent calcium-based sorbent by the self-reactivation process, Chin. J. Chem. Eng. 29 (2021) 160-166
[16] Z.H. Xu, T. Jiang, H. Zhang, Y.J. Zhao, X.B. Ma, S.P. Wang, Efficient MgO-doped CaO sorbent pellets for high temperature CO₂ capture, Front. Chem. Sci. Eng. 15 (3) (2021) 698-708
[17] S.B. Zeng, X.L. Xu, S.K. Wang, Q.K. Gong, R.J. Liu, Y. Yu, Sand flower layered double hydroxides synthesized by co-precipitation for CO₂ capture:Morphology evolution mechanism, agitation effect and stability, Mater. Chem. Phys. 140 (1) (2013) 159-167
[18] S. Walspurger, L. Boels, P.D. Cobden, G.D. Elzinga, W.G. Haije, R.W. van den Brink, The crucial role of the K+-aluminium oxide interaction in K+-promoted alumina- and hydrotalcite-based materials for CO₂ sorption at high temperatures, ChemSusChem 1 (7) (2008) 643-650
[19] J.Y. Wang, L. Huang, R.Y. Yang, Z. Zhang, J.W. Wu, Y.S. Gao, Q. Wang, D. O'Hare, Z.Y. Zhong, Recent advances in solid sorbents for CO₂ capture and new development trends, Energy Environ. Sci. 7 (11) (2014) 3478-3518
[20] J.M. Lee, Y.J. Min, K.B. Lee, S.G. Jeon, J.G. Na, H.J. Ryu, Enhancement of CO₂ sorption uptake on hydrotalcite by impregnation with K₂CO₃, Langmuir 26 (24) (2010) 18788-18797
[21] H.J. Jang, C.H. Lee, S. Kim, S.H. Kim, K.B. Lee, Hydrothermal synthesis of K₂CO₃-promoted hydrotalcite from hydroxide-form precursors for novel high-temperature CO₂ sorbent, ACS Appl. Mater. Interfaces 6 (9) (2014) 6914-6919
[22] H.B. Zhang, J.W. Wang, Q. Yan, W.G. Zheng, C. Chen, Z.Z. Yu, Vacuum-assisted synthesis of graphene from thermal exfoliation and reduction of graphite oxide, J. Mater. Chem. 21 (14) (2011) 5392-5397
[23] P.H. Chang, Y.P. Chang, S.Y. Chen, C.T. Yu, Y.P. Chyou, Ca-rich Ca-Al-oxide, high-temperature-stable sorbents prepared from hydrotalcite precursors:Synthesis, characterization, and CO₂ capture capacity, ChemSusChem 4 (12) (2011) 1844-1851
[24] P.H. Chang, T.J. Lee, Y.P. Chang, S.Y. Chen, CO₂ sorbents with scaffold-like Ca-Al layered double hydroxides as precursors for CO₂ capture at high temperatures, ChemSusChem 6 (6) (2013) 1076-1083
[25] Y.P. Chang, Y.C. Chen, P.H. Chang, S.Y. Chen, Synthesis, characterization, and CO₂ adsorptive behavior of mesoporous AlOOH-supported layered hydroxides, ChemSusChem 5 (7) (2012) 1249-1257
[26] P.H. Chang, Y.P. Chang, Y.H. Lai, S.Y. Chen, C.T. Yu, Y.P. Chyou, Synthesis, characterization and high temperature CO₂ capture capacity of nanoscale Ca-based layered double hydroxides via reverse microemulsion, J. Alloys Compd. 586 (2014) S498-S505
[27] T. Kameda, H. Uchida, S. Kumagai, Y. Saito, K. Mizushina, I. Itou, T.Y. Han, T. Yoshioka, Desorption of Cl- from Mg-Al layered double hydroxide intercalated with Cl- using CO₂ gas and water, Chin. J. Chem. Eng. 29 (2021) 131-134
[28] Q. Wang, H.H. Tay, Z.Y. Zhong, J.Z. Luo, A. Borgna, Synthesis of high-temperature CO₂ adsorbents from organo-layered double hydroxides with markedly improved CO₂ capture capacity, Energy Environ. Sci. 5 (6) (2012) 7526-7530
[29] N.D. Hutson, B.C. Attwood, High temperature adsorption of CO₂ on various hydrotalcite-like compounds, Adsorption 14 (6) (2008) 781-789
[30] X.C. Kou, H.X. Guo, E.G. Ayele, S. Li, Y.J. Zhao, S.P. Wang, X.B. Ma, Adsorption of CO₂ on MgAl-CO₃ LDHs-derived sorbents with 3D nanoflower-like structure, Energy Fuels 32 (4) (2018) 5313-5320
[31] X.C. Zhu, C.P. Chen, Y.X. Shi, D. O'Hare, N.S. Cai, Aqueous miscible organic-layered double hydroxides with improved CO₂ adsorption capacity, Adsorption 26 (7) (2020) 1127-1135
[32] N. Dutta, P. Newar, M. Narzary, T.K. Maji, Preparation and characterization of biobased hybrid nanocomposite of polyvinyl chloride/thermoplastic starch with Mg-Al layered double hydroxide and waste rice husk ash, J. Polym. Res. 29 (9) (2022) 375
[33] T. Kameda, H. Takeuchi, T. Yoshioka, Hybrid inorganic/organic composites of Mg-Al layered double hydroxides intercalated with citrate, malate, and tartrate prepared by co-precipitation, Mater. Res. Bull. 44 (4) (2009) 840-845
[34] M. Ghiasi, A. Malekzadeh, Synthesis of CaCO₃ nanoparticles via citrate method and sequential preparation of CaO and Ca(OH)2 nanoparticles, Cryst. Res. Technol. 47 (4) (2012) 471-478
[35] J. Perera, M. Weerasekera, N. Kottegoda, Slow release anti-fungal skin formulations based on citric acid intercalated layered double hydroxides nanohybrids, Chem. Cent. J. 9 (2015) 27
[36] M. Eili, K. Shameli, N.A. Ibrahim, M.B. Ahmad, W.M.Z. Wan Yunus, The effect of the divalent metal on the intercalation capacity of stearate anions into layered double hydroxide nanolayers, J. Ind. Eng. Chem. 22 (2015) 63-69
[37] J. Tronto, M.J.D. Reis, F. Silvério, V.R. Balbo, J.M. Marchetti, J.B. Valim, In vitro release of citrate anions intercalated in magnesium aluminium layered double hydroxides, J. Phys. Chem. Solids 65 (2-3) (2004) 475-480
[38] S.P. Wang, H. Shen, S.S. Fan, Y.J. Zhao, X.B. Ma, J.L. Gong, Enhanced CO₂ adsorption capacity and stability using CaO-based adsorbents treated by hydration, AIChE J. 59 (10) (2013) 3586-3593
[39] D.L. He, Z.L. Ou, C.L. Qin, T. Deng, J.J. Yin, G. Pu, Understanding the catalytic acceleration effect of steam on CaCO₃ decomposition by density function theory, Chem. Eng. J. 379 (2020) 122348
[40] A. Lalaut, C. Courson, K. Gallucci, Development of a high temperature CO₂ sorbent based on hydrotalcite for a H₂-rich syngas production, Waste Biomass Valori. 13 (1) (2022) 117-133
[41] H.R. Radfarnia, A. Sayari, A highly efficient CaO-based CO₂ sorbent prepared by a citrate-assisted sol-gel technique, Chem. Eng. J. 262 (2015) 913-920

High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

High-temperature CO₂ sorbents with citrate and stearate intercalated Ca—Al hydrotalcite-like as precursor

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Jian Wang, Yuanhui Shen, Donghui Zhang, Zhongli Tang, Wenbin Li. Integrated vacuum pressure swing adsorption and Rectisol process for CO₂ capture from underground coal gasification syngas[J]. 中国化学工程学报, 2023, 57(5): 265-279.
[2]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[3]	Zhong Ma, Guofu Liu, Hui Zhang, Yonggang Lu. Investigation of the redox performance of pyrite cinder calcined at different temperature in chemical looping combustion[J]. 中国化学工程学报, 2022, 48(8): 98-105.
[4]	Qunhong Liu, Jiangtao Yang, Hongwei Zhang, Hongming Sun, Shuzheng Wu, Bingqing Ge, Rong Wang, Pei Yuan. Tuning the properties of Ni-based catalyst via La incorporation for efficient hydrogenation of petroleum resin[J]. 中国化学工程学报, 2022, 45(5): 41-50.
[5]	Ding-Ming Xue, Wen-Juan Zhang, Xiao-Qin Liu, Shi-Chao Qi, Lin-Bing Sun. Fabrication of azobenzene-functionalized porous polymers for selective CO₂ capture[J]. 中国化学工程学报, 2022, 43(3): 24-30.
[6]	Xiaobin Chen, Yuting Tang, Chuncheng Ke, Chaoyue Zhang, Sichun Ding, Xiaoqian Ma. CO₂ capture by double metal modified CaO-based sorbents from pyrolysis gases[J]. 中国化学工程学报, 2022, 43(3): 40-49.
[7]	Wanqiao Liang, Jihuan Huang, Penny Xiao, Ranjeet Singh, Jining Guo, Leila Dehdari, Gang Kevin Li. Amine-immobilized HY zeolite for CO₂ capture from hot flue gas[J]. 中国化学工程学报, 2022, 43(3): 335-342.
[8]	Xiuxin Yu, Bing Liu, Yuanhui Shen, Donghui Zhang. Design and experiment of high-productivity two-stage vacuum pressure swing adsorption process for carbon capturing from dry flue gas[J]. 中国化学工程学报, 2022, 43(3): 378-391.
[9]	Xionghui Liu, Jianfeng Du, Yu Ye, Yuchuan Liu, Shun Wang, Xianyu Meng, Xiaowei Song, Zhiqiang Liang, Wenfu Yan. Boosting selective C₂H₂/CH₄, C₂H₄/CH₄ and CO₂/CH₄ adsorption performance via 1,2,3-triazole functionalized triazine-based porous organic polymers[J]. 中国化学工程学报, 2022, 42(2): 64-72.
[10]	Jiajia Wang, Lizhi Wang, You Wang, Du Zhang, Qin Xiao, Jianhan Huang, You-Nian Liu. Recent progress in porous organic polymers and their application for CO₂ capture[J]. 中国化学工程学报, 2022, 42(2): 91-103.
[11]	Peng Tan, Yao Jiang, Qiurong Wu, Chen Gu, Shichao Qi, Qiang Zhang, Xiaoqin Liu, Linbing Sun. Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO₂ capture[J]. 中国化学工程学报, 2022, 42(2): 104-111.
[12]	Baowen Wang, Zhongyuan Cai, Heyu Li, Yanchen Liang, Tao Jiang, Ning Ding, Haibo Zhao. Reaction characteristics investigation of CeO₂-enhanced CaSO₄ oxygen carrier with lignite[J]. 中国化学工程学报, 2022, 42(2): 319-328.
[13]	Fangqi Mao, Peipei Hao, Yuquan Zhu, Xianggui Kong, Xue Duan. Layered double hydroxides: Scale production and application in soil remediation as super-stable mineralizer[J]. 中国化学工程学报, 2022, 41(1): 42-48.
[14]	Yu Dong, Tiantian Ping, Shufeng Shen. Solubility of CO₂ in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol: Experimental data and model representation[J]. 中国化学工程学报, 2022, 41(1): 441-448.
[15]	Wan Zhang, Yingjie Li, Yuqi Qian, Boyu Li, Jianli Zhao, Zeyan Wang. NO removal performance of CO in carbonation stage of calcium looping for CO₂ capture[J]. 中国化学工程学报, 2021, 37(9): 30-38.