[1] G.B. Liu, G.H. Yang, X.B. Peng, J.H. Wu, N. Tsubaki, Recent advances in the routes and catalysts for ethanol synthesis from syngas, Chem. Soc. Rev. 51 (13) (2022) 5606-5659. [2] A.E. Farrell, R.J. Plevin, B.T. Turner, A.D. Jones, M. O'Hare, D.M. Kammen, Ethanol can contribute to energy and environmental goals, Science 311 (5760) (2006) 506-508. [3] H.T. Luk, C. Mondelli, D.C. Ferrt, J.A. Stewart, J. Ptrez-Ramirez, Status and prospects in higher alcohols synthesis from syngas, Chem. Soc. Rev. 46 (5) (2017) 1358 - 1426. [4] M. Ni, D.Y.C. Leung, M.K.H.Leung, A review on reforming bio-ethanol for hydrogen production, Int. J. Hydrog. Energy 32 (15) (2007) 3238-3247. [5] H. Aitchison, R.L. Wingad, D.F.Wass, Homogeneous ethanol to butanol catalysis—guerbet renewed, ACS Catal. 6 (10) (2016) 7125-7132. [6] A. Mohsenzadeh, A. Zamani, M.J.Taherzadeh, Bioethylene production from ethanol: A review and techno-economical evaluation, Chembioeng Rev. 4 (2) (2017) 75-91. [7] D.U. Pascoli, A. Suko, R. Gustafson, H.L. Gough, R. Bura, Novel ethanol production using biomass preprocessing to increase ethanol yield and reduce overall costs, Biotechnol Biofuels 14 (1) (2021) 9. [8] C.T. Wang, J. Zhang, G.Q. Qin, L. Wang, E. Zuidema, Q. Yang, S.S. Dang, C.G. Yang, J.P. Xiao, X.J. Meng, C. Mesters, F.S.Xiao, Direct conversion of syngas to ethanol within zeolite crystals, Chem 6 (3) (2020) 646-657. [9] C. Huang, C. Zhu, M.W. Zhang, Y.W. Lu, Q.H. Wang, H.M. Qian, J.G. Chen, K.G.Fang, Direct conversion of syngas to higher alcohols over a CuCoAl|t-ZrO2 multifunctional catalyst, ChemCatChem 13 (13) (2021) 3184-3197. [10] Y.Y. Liu, K. Murata, M. Inaba, I. Takahara, K.Okabe, Mixed alcohols synthesis from syngas over cs- and Ni-modified Cu/CeO2 catalysts, Fuel 104 (2013) 62-69. [11] H. Du, H.J. Zhu, X.K. Chen, W.D. Dong, W. Lu, W.T. Luo, M. Jiang, T. Liu, Y.J.Ding, Study on CaO-promoted Co/AC catalysts for synthesis of higher alcohols from syngas, Fuel 182 (2016) 42-49. [12] R.G. Zhang, G.X. Wen, H. Adidharma, A.G. Russell, B.J. Wang, M. Radosz, M.H.Fan, C2 oxygenate synthesis via Fischer-Tropsch synthesis on Co2C and Co/Co2C interface catalysts: How to control the catalyst crystal facet for optimal selectivity, ACS Catal. 7 (12) (2017) 8285-8295. [13] Chen, Yang, Composition control of CuFeZn catalyst derived by PDA and its effect on synthesis of C2+ alcohols from CO2, Fuel 327 (2022) 125055. [14] Y.Z. Yang, T.J. Lin, X.Z. Qi, F. Yu, Y.L. An, Z.J. Li, Y.Y. Dai, L.S. Zhong, H. Wang, Y.H.Sun, Direct synthesis of long-chain alcohols from syngas over CoMn catalysts, Appl. Catal. A Gen. 549 (2018) 179-187. [15] M.M. Lv, W. Xie, S. Sun, G.M. Wu, L.R. Zheng, S.Q. Chu, C. Gao, J. Bao, Activated-carbon-supported K-Co-Mo catalysts for synthesis of higher alcohols from syngas, Catal. Sci. Technol. 5 (5) (2015) 2925-2934. [16] J.K. Hasty, S. Ponnurangam, S. Turn, P. Somasundaran, T. Kim, D.Mahajan, Catalytic synthesis of mixed alcohols mediated with nano-MoS2 microemulsions, Fuel 164 (2016) 339-346. [17] E.T. Liakakou, E. Heracleous, Transition metal promoted K/Mo2C as efficient catalysts for CO hydrogenation to higher alcohols, Catal. Sci. Technol. 6 (4) (2016) 1106-1119. [18] P. Preikschas, M. Plodinec, J. Bauer, R. Kraehnert, R. Naumann d’Alnoncourt, R. Schlögl, M. Driess, F.Rosowski, Tuning the Rh-FeOx interface in ethanol synthesis through formation phase studies at high pressures of synthesis gas, ACS Catal. 11 (7) (2021) 4047-4060. [19] L. Zhao, X.L. Mu, T.S. Liu, K.G. Fang, Bimetallic Ni-Co catalysts supported on Mn-Al oxide for selective catalytic CO hydrogenation to higher alcohols, Catal. Sci. Technol. 8 (8) (2018) 2066-2076. [20] Jiaqian, Yang, Insights into the one-step ethanol synthesis through CO hydrogenation over surfactant-assisted preparation of CuCo/SiO2 catalyst, Fuel 327 (2022) 125078. [21] P.F. Song, J.M. Wang, G.L. Liu, Z.Y. Zhang, N.Y. Li, X.T. Wang, W. Zhou, Y.Liu, Self-optimized and renewable Ni-Co alloy@Co-Co2C catalyst for higher alcohols synthesis from syngas, Int. J. Hydrog. Energy 47 (38) (2022) 16933-16948. [22] X.Z. Zhu, Y.S. Shang, J.Y. Chen, H. Wei, D.P. Xu, X.C. Lin, Y.G. wang, Insight into the role of lanthanum-modified CuCo based catalyst for higher alcohol synthesis from syngas, Fuel Process. Technol. 235 (2022) 107378 [23] T.Y. Chen, J.J. Su, Z.P. Zhang, C.X. Cao, X. Wang, R. Si, X.L. Liu, B.F. Shi, J. Xu, Y.F.Han, Structure evolution of Co-CoOx interface for higher alcohol synthesis from syngas over Co/CeO2 catalysts, ACS Catal. 8 (9) (2018) 8606-8617. [24] M. Blanchard, H. Derule, P. Canesson, Cobalt catalysts for the production of alcohols in the F.T. synthesis, Catal Lett 2 (5) (1989) 319-322. [25] Zhe, An, Ga-promoted CO insertion and C-C coupling on Co catalysts for the synthesis of ethanol and higher alcohols from syngas, J. Catal. 356 (2017) 157-164. [26] Pengfei, Song, The active pairs of Co-Co2C adjusted by La-doped CaTiO3 with perovskite phase for higher alcohol synthesis from syngas, Chem. Eng. J. 439 (2022) 135635. [27] J.M. Wang, G.L. Liu, H.X. Zhong, P.F. Song, K. An, Z.Y. Zhang, A. Cao, Y.Liu, in situ topochemical carbonization derivative Co-Ni alloy@Co-Co2C for direct ethanol synthesis from syngas, Appl. Surf. Sci. 557 (2021) 149826. [28] Q.L. Yang, G.L. Liu, Y.Liu, Perovskite-type oxides as the catalyst precursors for preparing supported metallic nanocatalysts: A review, Ind. Eng. Chem. Res. 57 (1) (2018) 1-17. [29] Lin, Zhao, Ni-Co alloy catalyst from LaNi1-xCoxO3 perovskite supported on zirconia for steam reforming of ethanol, Appl. Catal. B Environ. 187 (2016) 19-29. [30] D. Chen, C. Chen, Z.M. Baiyee, Z. Shao, F. Ciucci, Nonstoichiometric oxides as low-cost and highly-efficient oxygen reduction/evolution catalysts for low-temperature electrochemical devices, Chem. Rev. 115 (18) (2015) 9869-9921. [31] Y.Z. Fang, Y. Liu, L.H. Zhang, LaFeO3-supported nano Co-Cu catalysts for higher alcohol synthesis from syngas, Appl. Catal. A Gen. 397 (1-2) (2011) 183-191. [32] Q.Q. Ji, L. Bi, J.T. Zhang, H.J. Cao, X.S. Zhao, The role of oxygen vacancies of ABO3 perovskite oxides in the oxygen reduction reaction, Energy Environ. Sci. 13 (5) (2020) 1408-1428. [33] S. Gao, N. Liu, J. Liu, W.K. Chen, X.L. Liang, Y.Z. Yuan, Synthesis of higher alcohols by CO hydrogenation over catalysts derived from LaCo1-xMnxO3 perovskites: Effect of the partial substitution of Co by Mn, Fuel 261 (2020) 116415. [34] Tae-Wan, Kim, Catalytic conversion of syngas to higher alcohols over mesoporous perovskite catalysts, J. Ind. Eng. Chem. 51 (2017) 196-205. [35] Zijun, Wang, Co-Ni bimetal catalyst supported on perovskite-type oxide for steam reforming of ethanol to produce hydrogen, Int. J. Hydrog. Energy 39 (11) (2014) 5644-5652. [36] J.M. Wang, H.X. Zhong, K. An, Q. Liu, W. Jin, Y.Liu, Co-Ni alloy nanoparticles on La-doped SiO2 for direct ethanol synthesis from syngas, Ind. Eng. Chem. Res. 59 (44) (2020) 19539-19552. [37] Min, Ao, Perovskite-derived trimetallic Co-Ni-Cu catalyst for higher alcohol synthesis from syngas, Fuel Process. Technol. 193 (2019) 141-148. [38] Manman, Zhang, Effects of cobalt promoter and reduction temperature on the surface species and syngas adsorption of K-Co-Mo/C catalyst for mixed alcohols synthesis, J. Mol. Catal. A Chem. 395 (2014) 269-275. [39] J.X. Yong, X.B. Luan, X.P. Dai, X. Zhang, Y. Yang, H.H. Zhao, M.L. Cui, Z.T. Ren, F. Nie, X.L. Huang, Alkaline-etched NiMgAl trimetallic oxide-supported KMoS-based catalysts for boosting higher alcohol selectivity in CO hydrogenation, ACS Appl. Mater. Interfaces 11 (21) (2019) 19066-19076. [40] Yishuang, Wang, Influence of CoAl2O4 spinel and Co-phyllosilicate structures derived from Co/sepiolite catalysts on steam reforming of bio-oil for hydrogen production, Fuel 279 (2020) 118449. [41] T. Majima, E. Kono, S. Ogo, Y. Sekine, Pre-reduction and K loading effects on noble metal free Co-system catalyst for water gas shift reaction, Appl. Catal. A Gen. 523 (2016) 92-96. [42] M.Y. Wang, C.J. Jiang, X.W. Wang, P.F. Xian, H.G. Wang, Y. Yang, Existing form of Mo(VI) in acidic sulfate solution, Rare Met. 36 (7) (2017) 612-616. [43] Wenwen, Zhang, Effective promotion of oxygen reduction activity by rare earth doping in simple perovskite cathodes for intermediate-temperature solid oxide fuel cells, J. Power Sources 446 (2020) 227360. [44] Y.L. Zhu, W. Zhou, J. Yu, Y.B. Chen, M.L. Liu, Z.P.Shao, Enhancing electrocatalytic activity of perovskite oxides by tuning cation deficiency for oxygen reduction and evolution reactions, Chem. Mater. 28 (6) (2016) 1691-1697. [45] D.Y. Feng, Y.B. Dong, L.L. Zhang, X. Ge, W. Zhang, S. Dai, Z.A.Qiao, Holey lamellar high-entropy oxide as an ultra-high-activity heterogeneous catalyst for solvent-free aerobic oxidation of benzyl alcohol, Angewandte Chemie Int. Ed. 59 (44) (2020) 19503-19509. [46] Shaoxia, Guo, Oxygen vacancies boosted Co-Co2C catalysts for higher alcohols synthesis from syngas, Appl. Surf. Sci. 576 (2022) 151846. [47] T. Namiki, S. Yamashita, H. Tominaga, M.Nagai, Dissociation of CO and H2O during water-gas shift reaction on carburized Mo/Al2O3 catalyst, Appl. Catal. A Gen. 398 (1-2) (2011) 155-160. [48] V.M. Lebarbier, D.H. Mei, D.H. Kim, A. Andersen, J.L. Male, J.E. Holladay, R. Rousseau, Y.Wang, Effects of La2O3 on the mixed higher alcohols synthesis from syngas over Co catalysts: A combined theoretical and experimental study, J. Phys. Chem. C 115 (35) (2011) 17440-17451. [49] Z.L. Fan, W. Chen, X.l. Pan, X.H. Bao, Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts—effect of carbon supports, Catal. Today 147 (2) (2009) 86-93. [50] Z.Y. Song, X.P. Shi, H.Y. Ning, G.L. Liu, H.X. Zhong, Y.Liu, Loading clusters composed of nanoparticles on ZrO2 support via a perovskite-type oxide of La0.95Ce0.05Co0.7Cu0.3O3 for ethanol synthesis from syngas and its structure variation with reaction time, Appl. Surf. Sci. 405 (2017) 1-12. [51] Jingjuan, Wang, Structure and catalytic performance of alumina-supported copper-cobalt catalysts for carbon monoxide hydrogenation, J. Catal. 286 (2012) 51-61. [52] Z.S. Li, G.Y. Luo, T. Chen, Z. Zeng, S.X. Guo, J. Lv, S.Y. Huang, Y. Wang, X.B.Ma, Bimetallic CoCu catalyst derived from in situ grown Cu-ZIF-67 encapsulated inside KIT-6 for higher alcohol synthesis from syngas, Fuel 278 (2020) 118292. [53] K. Sun, M.H. Tan, Y.X. Bai, X.F. Gao, P. Wang, N.N. Gong, T. Zhang, G.H. Yang, Y.S.Tan, Design and synthesis of spherical-platelike ternary copper-cobalt-Manganese catalysts for direct conversion of syngas to ethanol and higher alcohols, J. Catal. 378 (2019) 1-16. [54] S.X. Guo, S.S. Li, H.X. Zhong, D.D. Gong, J.M. Wang, N. Kang, L.H. Zhang, G.L. Liu, Y.Liu, Mixed oxides confined and tailored cobalt nanocatalyst for direct ethanol synthesis from syngas: A catalyst designing by using perovskite-type oxide as the precursor, Ind. Eng. Chem. Res. 57 (6) (2018) 2404-2415. [55] V.V. Praveen Kumar, N. Prasad, S.Dey, Influence of metakaolin on strength and durability characteristics of ground granulated blast furnace slag based geopolymer concrete, Struct. Concr. 21 (3) (2020) 1040-1050. |