SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2023, Vol. 60 ›› Issue (8): 235-241.DOI: 10.1016/j.cjche.2023.02.024

• Full Length Article • 上一篇    下一篇

Measurement and correlation of solubility of 9-fluorenone in 11 pure organic solvents from T = 283.15 to 323.15 K

Huiqi Wang1, Jianpo Ren2, Shihao Zhang1, Jiayu Dai1, Yue Niu1, Ketao Shi1, Qiuxiang Yin1,3, Ling Zhou1   

  1. 1. School of Chemical Engineering and Technology, State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300072, China;
    2. Sinochem Hebei Xinbao Chemical Technology Co., Ltd, Handan 056500, China;
    3. The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin University, Tianjin 300072, China
  • 收稿日期:2022-08-02 修回日期:2023-02-06 出版日期:2023-08-28 发布日期:2023-10-28
  • 通讯作者: Ling Zhou,E-mail:zhouling@tju.edu.cn
  • 基金资助:
    The work is supported by Tianjin Municipal Natural Science Foundation (21JCYBJC00600).

Measurement and correlation of solubility of 9-fluorenone in 11 pure organic solvents from T = 283.15 to 323.15 K

Huiqi Wang1, Jianpo Ren2, Shihao Zhang1, Jiayu Dai1, Yue Niu1, Ketao Shi1, Qiuxiang Yin1,3, Ling Zhou1   

  1. 1. School of Chemical Engineering and Technology, State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300072, China;
    2. Sinochem Hebei Xinbao Chemical Technology Co., Ltd, Handan 056500, China;
    3. The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin University, Tianjin 300072, China
  • Received:2022-08-02 Revised:2023-02-06 Online:2023-08-28 Published:2023-10-28
  • Contact: Ling Zhou,E-mail:zhouling@tju.edu.cn
  • Supported by:
    The work is supported by Tianjin Municipal Natural Science Foundation (21JCYBJC00600).

摘要: In this work, the solubility data of 9-fluorenone in 11 pure solvents (methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, acetonitrile, ethyl formate, ethyl acetate, dimethyl sulfoxide, n-hexane) were measured by the gravimetric method from 278.15 K to 318.15 K under atmospheric pressure. The results showed that the solubility of 9-fluorenone in all tested solvents increased with the raised temperature. The solubility data were correlated by the modified Apelblat equation, λh model and NRTL (non-radom two fluid) model. The average relative deviation (ARD) correlated by three thermodynamic models in different solvents was all below 5%, which indicated that the three thermodynamic models fit the solubility data well. Furthermore, the mixing thermodynamic properties of 9-fluorenone in pure solvent systems were calculated via NRTL model. The results indicated the dissolution process of 9-fluorenone is spontaneous and entropically favorable. The solubility and the mixing thermodynamic properties provided in this paper would play an important role in industrial manufacture and follow-up operation of 9-fluorenone.

关键词: 9-Fluorenone, Solubility, Correlation model, Thermodynamic properties

Abstract: In this work, the solubility data of 9-fluorenone in 11 pure solvents (methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, acetonitrile, ethyl formate, ethyl acetate, dimethyl sulfoxide, n-hexane) were measured by the gravimetric method from 278.15 K to 318.15 K under atmospheric pressure. The results showed that the solubility of 9-fluorenone in all tested solvents increased with the raised temperature. The solubility data were correlated by the modified Apelblat equation, λh model and NRTL (non-radom two fluid) model. The average relative deviation (ARD) correlated by three thermodynamic models in different solvents was all below 5%, which indicated that the three thermodynamic models fit the solubility data well. Furthermore, the mixing thermodynamic properties of 9-fluorenone in pure solvent systems were calculated via NRTL model. The results indicated the dissolution process of 9-fluorenone is spontaneous and entropically favorable. The solubility and the mixing thermodynamic properties provided in this paper would play an important role in industrial manufacture and follow-up operation of 9-fluorenone.

Key words: 9-Fluorenone, Solubility, Correlation model, Thermodynamic properties