NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene

doi:10.1016/j.cjche.2024.09.010

中国化学工程学报 ›› 2024, Vol. 76 ›› Issue (12): 201-210.DOI: 10.1016/j.cjche.2024.09.010

NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene

Yongliang Jia^1,2,3,4,5, Boyang Bai^1,6, Jing Wang^1,2,3,4,5, Yueyi Wang^1,2,3,4,5, Zheng Wang^1,2,3,4,5, Xiaoxun Ma^1,2,3,4,5

1. School of Chemical Engineering, Northwest University, Xi'an 710069, China;
2. International Scientific and Technological Cooperation Base of the Ministry of Science and Technology (MOST) for Clean Utilization of Hydrocarbon Resources, Xi'an 710069, China;
3. Chemical Engineering Research Center of the Ministry of Education (MOE) for Advanced Use Technology of Shanbei Energy, Xi'an 710069, China;
4. Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi'an 710069, China;
5. Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China;
6. College of Chemistry and Materials Science, Weinan Normal University, Weinan 714000, China

收稿日期:2024-03-13 修回日期:2024-09-20 接受日期:2024-09-22 出版日期:2024-12-28 发布日期:2024-10-11
通讯作者: Xiaoxun Ma,E-mail:maxym@nwu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (21536009), Science and Technology Plan Projects of Shaanxi Province (2017ZDCXL-GY-10-03), and National Natural Science Foundation of China (22008198) and the Special Scientific Research Plan Project of Education Ministry of Shaanxi Province, China (19JK0854).

NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene

Yongliang Jia^1,2,3,4,5, Boyang Bai^1,6, Jing Wang^1,2,3,4,5, Yueyi Wang^1,2,3,4,5, Zheng Wang^1,2,3,4,5, Xiaoxun Ma^1,2,3,4,5

1. School of Chemical Engineering, Northwest University, Xi'an 710069, China;
2. International Scientific and Technological Cooperation Base of the Ministry of Science and Technology (MOST) for Clean Utilization of Hydrocarbon Resources, Xi'an 710069, China;
3. Chemical Engineering Research Center of the Ministry of Education (MOE) for Advanced Use Technology of Shanbei Energy, Xi'an 710069, China;
4. Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi'an 710069, China;
5. Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China;
6. College of Chemistry and Materials Science, Weinan Normal University, Weinan 714000, China

Received:2024-03-13 Revised:2024-09-20 Accepted:2024-09-22 Online:2024-12-28 Published:2024-10-11
Contact: Xiaoxun Ma,E-mail:maxym@nwu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21536009), Science and Technology Plan Projects of Shaanxi Province (2017ZDCXL-GY-10-03), and National Natural Science Foundation of China (22008198) and the Special Scientific Research Plan Project of Education Ministry of Shaanxi Province, China (19JK0854).

摘要/Abstract

摘要： A series of Ni-based catalysts were prepared via structural topological transformation from the Ni@Al₂O₃ layered double hydroxides (LDHs) precursors, and applied for the deep catalytic hydrogenation saturation of pyrene in a high-pressure reactor. The pore structures, active species dispersion, surface morphology, amount and type of acid of the prepared catalysts were characterized by BET, XRD, SEM, TEM, XPS, SEM, NH₃-TPD and Py-IR. We studied the influence of physicochemical properties of Ni-based catalysts on the regularity and mechanism of deep hydrogenation of pyrene. Meanwhile, the synergy between Ni and Mo, and the interaction between active metals and support were discussed to further reveal the constitutive relationship during the hydrogenation reaction of pyrene. The results of the evaluation of the catalytic hydrogenation of pyrene show that the as-prepared NiMo mixed metal oxide (MMO) catalyst showed excellent catalytic activity: ~95% pyrene conversion, 90.12% for the selectivity of deep hydrogenation products (hexahydropyrene, decahydropyrene and hexadecahydropyrene). It was expected that the successfully preparation and utilization of NiMo-MMO catalyst could provide a theoretical basis for the design of this kind of catalysts for deep catalytic hydrogenation of polycyclic aromatic hydrocarbons (PAHs).

关键词: Ni@Al₂O₃LDHs, Structural topological transformation method, NiMo-MMO catalyst, Pyrene deep hydrogenation

Abstract: A series of Ni-based catalysts were prepared via structural topological transformation from the Ni@Al₂O₃ layered double hydroxides (LDHs) precursors, and applied for the deep catalytic hydrogenation saturation of pyrene in a high-pressure reactor. The pore structures, active species dispersion, surface morphology, amount and type of acid of the prepared catalysts were characterized by BET, XRD, SEM, TEM, XPS, SEM, NH₃-TPD and Py-IR. We studied the influence of physicochemical properties of Ni-based catalysts on the regularity and mechanism of deep hydrogenation of pyrene. Meanwhile, the synergy between Ni and Mo, and the interaction between active metals and support were discussed to further reveal the constitutive relationship during the hydrogenation reaction of pyrene. The results of the evaluation of the catalytic hydrogenation of pyrene show that the as-prepared NiMo mixed metal oxide (MMO) catalyst showed excellent catalytic activity: ~95% pyrene conversion, 90.12% for the selectivity of deep hydrogenation products (hexahydropyrene, decahydropyrene and hexadecahydropyrene). It was expected that the successfully preparation and utilization of NiMo-MMO catalyst could provide a theoretical basis for the design of this kind of catalysts for deep catalytic hydrogenation of polycyclic aromatic hydrocarbons (PAHs).

Key words: Ni@Al₂O₃LDHs, Structural topological transformation method, NiMo-MMO catalyst, Pyrene deep hydrogenation

Yongliang Jia, Boyang Bai, Jing Wang, Yueyi Wang, Zheng Wang, Xiaoxun Ma. NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene[J]. 中国化学工程学报, 2024, 76(12): 201-210.

Yongliang Jia, Boyang Bai, Jing Wang, Yueyi Wang, Zheng Wang, Xiaoxun Ma. NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene[J]. Chinese Journal of Chemical Engineering, 2024, 76(12): 201-210.

参考文献

[1] BP Statistical Review of World Energy. 2023, https://www.bp.com/en/global/corporate/energy-economics/statistical-review-of-world-energy.html.
[2] X. He, G. Fan G, H. Wu, X. Zhang, T. Ma, Z. Shi, A. Zhou, Y Zhang, Advances in research on hydrogenation saturation of polycyclic aromatic hydrocarbons in coal tar, Coal Geology & Exploration 52 (2024) 1-10.
[3] Z.H. Ma, X.Y. Wei, G.H. Liu, F.J. Liu, Z.M. Zong, Value-added utilization of high-temperature coal tar: A review, Fuel 292 (2021) 119954.
[4] M.L. Wang, X.Q. Qian, L.Q. Xie, H.H. Fang, L.M. Ye, X.P. Duan, Y.Z. Yuan, Synthesis of a Ni phyllosilicate with controlled morphology for deep hydrogenation of polycyclic aromatic hydrocarbons, ACS Sustainable Chem. Eng. 7 (2) (2019) 1989-1997.
[5] J.L. Gu, H. Li, Y.Q. Wu, S. Huang, S.Y. Wu, D.B. Chen, Preliminary investigations on the catalytic hydrogenation of polycyclic aromatic hydrocarbons via WGSR, Mol. Catal. 515 (2021) 111902.
[6] J.J. Liu, H.F. Zhang, N.Y. Lu, X.L. Yan, B.B. Fan, R.F. Li, Influence of acidity of mesoporous ZSM-5-supported Pt on naphthalene hydrogenation, Ind. Eng. Chem. Res. 59 (3) (2020) 1056-1064.
[7] Y. Chen, Z.M. Zhao, Z. Li, J.Y. Jing, W.Y. Li, Enhanced phenanthrene hydrogenation saturation performance of Ni-Co/NiAlOX catalysts and its catalytic mechanism, Fuel Process. Technol. 250 (2023) 107902.
[8] M.H. Stockett, L. Avaldi, P. Bolognesi, J.N. Bull, L. Carlini, E. Carrascosa, J. Chiarinelli, R. Richter, H. Zettergren, Competitive dehydrogenation and backbone fragmentation of superhydrogenated PAHs: A laboratory study, Astrophys. J. 913 (1) (2021) 46.
[9] B.Y. Bai, L.Y. Qiang, Y.L. Jia, X.X. Ma, Effect of nickel-based catalysts with nanolamellar structure on catalytic hydrogenation of pyrene: Combining experiment and calculation, Fuel 365 (2024) 131133.
[10] A.F.S. Zanato, V.C. Silva, D.A. Lima, M.J. Jacinto, Bimetallic magnetic PtPd-nanoparticles as efficient catalyst for PAH removal from liquid media, Appl. Nanosci. 7 (8) (2017) 781-791.
[11] G.Y. Zhang, Y.H. Wang, S.X. Dou, Y.Y. Dong, L.G. Ma, Q.Q. Zhu, X.J. Kong, MoOx regulating Ni-based catalyst anchored on N-doped carbon microspheres for catalytic hydrogenation of nitroarenes, Sep. Purif. Technol. 337 (2024) 126265.
[12] M. Xu, M. Wei, Layered double hydroxide-based catalysts: Recent advances in preparation, structure, and applications, Adv. Funct. Mater. 28 (47) (2018) 1802943.
[13] R.M. Claydon, L.A. Roman-Ramirez, J. Wood, Comparative study on the hydrogenation of naphthalene over both Al₂O₃-supported Pd and NiMo catalysts against a novel LDH-derived Ni-MMO-supported Mo catalyst, ACS Omega 6 (30) (2021) 20053-20067.
[14] X.Y. Meng, Y.S. Yang, L.F. Chen, M. Xu, X. Zhang, M. Wei, A control over hydrogenation selectivity of furfural via tuning exposed facet of Ni catalysts, ACS Catal. 9 (5) (2019) 4226-4235.
[15] H.L. Zhang, J. Dong, X.L. Qiao, J.R. Qin, H.F. Sun, A.Q. Wang, L.B. Niu, G.Y. Bai, In-situ generated highly dispersed nickel nanoclusters confined in MgAl mixed metal oxide platelets for benzoic acid hydrogenation, J. Catal. 372 (2019) 258-265.
[16] Y. Tan, X.Y. Liu, L. Li, L.L. Kang, A.Q. Wang, T. Zhang, Effects of divalent metal ions of hydrotalcites on catalytic behavior of supported gold nanocatalysts for chemoselective hydrogenation of 3-nitrostyrene, J. Catal. 364 (2018) 174-182.
[17] R. Claydon, J. Wood, A mechanistic study of layered-double hydroxide (LDH)-derived nickel-enriched mixed oxide (Ni-MMO) in ultradispersed catalytic pyrolysis of heavy oil and related petroleum coke formation, Energy Fuels 33 (11) (2019) 10820-10832.
[18] S. Intachai, M. Na Nakorn, A. Kaewnok, P. Pankam, P. Sumanatrakul, N. Khaorapapong, Versatile inorganic adsorbent for efficient and practical removal of hexavalent chromium in water, Mater. Chem. Phys. 288 (2022) 126388.
[19] Y.J. Li, T.T. Qi, Y.N. Dong, W.H. Hou, G.W. Chu, L.L. Zhang, B.C. Sun, Synthesized Ni/MMO catalysts via ultrathin Ni-Al-LDH in a rotating packed bed for hydrogenation of maleic anhydride, Fuel 326 (2022) 125035.
[20] W.P. Han, M.X. Tang, J.L. Li, X.K. Li, J.W. Wang, L.G. Zhou, Y. Yang, Y.Q. Wang, H. Ge, Selective hydrogenolysis of 5-hydroxymethylfurfural to 2, 5-dimethylfuran catalyzed by ordered mesoporous alumina supported nickel-molybdenum sulfide catalysts, Appl. Catal. B Environ. 268 (2020) 118748.
[21] N. Wang, K. Shen, L.H. Huang, X.P. Yu, W.Z. Qian, W. Chu, Facile route for synthesizing ordered mesoporous Ni-Ce-Al oxide materials and their catalytic performance for methane dry reforming to hydrogen and syngas, ACS Catal. 3 (7) (2013) 1638-1651.
[22] X.L. Wang, Z. Zhao, Z.T. Chen, J.M. Li, A.J. Duan, C.M. Xu, D.W. Gao, Z.K. Cao, P. Zheng, J.Y. Fan, Effect of synthesis temperature on structure-activity-relationship over NiMo/γ-Al₂O₃ catalysts for the hydrodesulfurization of DBT and 4, 6-DMDBT, Fuel Process. Technol. 161 (2017) 52-61.
[23] A.J. Pamphile-Adrian, F.B. Passos, P.P. Florez-Rodriguez, Systematic study on the properties of nickel aluminate (NiAl₂O₄) as a catalytic precursor for aqueous phase hydrogenolysis of glycerol, Catal. Today 394 (2022) 499-509.
[24] Z.G. Qiu, Q. Li, L. Shi, Z.Q. Li, L. Ding, L.F. Zhao, Effect of Ni loading and impregnation method on the hydrodenitrogenation of coal tar over Ni-Mo/γ-Al₂O₃, Energy Sources Part A Recovery Util. Environ. Eff. (2020) 1-13.
[25] N. Abdel Karim Aramouni, J. Zeaiter, W. Kwapinski, J.J. Leahy, M.N. Ahmad, Molybdenum and nickel-molybdenum nitride catalysts supported on MgO-Al₂O₃ for the dry reforming of methane, J. CO₂ Util. 44 (2021) 101411.
[26] S. Song, S.K. Yao, J.H. Cao, L. Di, G.J. Wu, N.J. Guan, L.D. Li, Heterostructured Ni/NiO composite as a robust catalyst for the hydrogenation of levulinic acid to γ-valerolactone, Appl. Catal. B Environ. 217 (2017) 115-124.
[27] Z.M. Shi, C.S. Wan, M. Huang, J.H. Pan, R.Z. Luo, D.L. Li, L.L. Jiang, Characterization and catalytic behavior of hydrotalcite-derived Ni-Al catalysts for methane decomposition, Int. J. Hydrog. Energy 45 (35) (2020) 17299-17310.
[28] W. Liu, Y.S. Yang, L.F. Chen, E.Z. Xu, J.M. Xu, S. Hong, X. Zhang, M. Wei, Atomically-ordered active sites in NiMo intermetallic compound toward low-pressure hydrodeoxygenation of furfural, Appl. Catal. B Environ. 282 (2021) 119569.
[29] L.H. Zhao, K.G. Fang, D. Jiang, D.B. Li, Y.H. Sun, Sol-gel derived Ni-Mo bimetallic carbide catalysts and their performance for CO hydrogenation, Catal. Today 158 (3-4) (2010) 490-495.
[30] L.L. Ji, J.Y. Wang, L.X. Guo, Z.F. Chen, In situ O₂-emission assisted synthesis of molybdenum carbide nanomaterials as an efficient electrocatalyst for hydrogen production in both acidic and alkaline media, J. Mater. Chem. A 5 (10) (2017) 5178-5186.
[31] D.S. Kim, K. Segawa, T. Soeya, I.E. Wachs, Surface structures of supported molybdenum oxide catalysts under ambient conditions, J. Catal. 136 (2) (1992) 539-553.
[32] P.M. Yeletsky, T.R. Reina, O.A. Bulavchenko, A.A. Saraev, E.Y. Gerasimov, O.O. Zaikina, J.M. Bermudez, P. Arcelus-Arrillaga, V.A. Yakovlev, M. Millan, Phenanthrene catalytic cracking in supercritical water: Effect of the reaction medium on NiMo/SiO₂ catalysts, Catal. Today 329 (2019) 197-205.
[33] R.G. Kukushkin, O.A. Bulavchenko, V.V. Kaichev, V.A. Yakovlev, Influence of Mo on catalytic activity of Ni-based catalysts in hydrodeoxygenation of esters, Appl. Catal. B Environ. 163 (2015) 531-538.
[34] P. Zhang, X.J. Yang, X.L. Hou, J.L. Mi, Z.Z. Yuan, J. Huang, C. Stampfl, Active sites and mechanism of the direct conversion of methane and carbon dioxide to acetic acid over the zinc-modified H-ZSM-5 zeolite, Catal. Sci. Technol. 9 (22) (2019) 6297-6307.
[35] Q. Zhao, W.H. Yang, J.J. Luo, C.H. Liang, Regulation of Ni/Al₂O₃ catalysts by metal deposition procedures for selective hydrogenation of adiponitrile, New J. Chem. 46 (4) (2022) 1498-1506.
[36] R.Y. Zhao, L.Y. Zeng, J. Liang, C.G. Liu, Interaction between Ni promoter and Al₂O₃ support and its effect on the performance of NiMo/γ-Al₂O₃ catalyst in hydrodesulphurization, J. Fuel Chem. Technol. 44 (5) (2016) 564-569.
[37] C.W. Dong, C.L. Yin, T.T. Wu, Z.Y. Wu, D. Liu, C.G. Liu, Study on the modification of unsupported hydrodesulfurization catalysts by the ZSM-5 zeolite nanoclusters, Appl. Catal. A Gen. 582 (2019) 117113.
[38] Y.D. Chen, C.M. Li, J.Y. Zhou, S.T. Zhang, D.M. Rao, S. He, M. Wei, D.G. Evans, X. Duan, Metal phosphides derived from hydrotalcite precursors toward the selective hydrogenation of phenylacetylene, ACS Catal. 5 (10) (2015) 5756-5765.

NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene

NiMo-MMO catalyst derived from LDHs precursors toward the deep hydrogenation of pyrene

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