Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO2 particles prepared by facile spraying technique

doi:10.1016/j.cjche.2025.03.021

中国化学工程学报 ›› 2025, Vol. 85 ›› Issue (9): 335-347.DOI: 10.1016/j.cjche.2025.03.021

Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO₂ particles prepared by facile spraying technique

Mengyuan Peng¹, Qi Wang², Min Sha³, Biao Jiang^1,4, Ding Zhang^1,4

1. School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;
2. Xi'an Aerospace Chemical Propulsion Co., Ltd., Xi'an 710025, China;
3. School of Management Science & Engineering, Nanjing University of Finance & Economics, Jiangsu 210046, China;
4. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Origanic Chemistry, Chinese Academy Sciences, Shanghai 200032, China

收稿日期:2024-11-22 修回日期:2025-02-21 接受日期:2025-03-06 出版日期:2025-09-28 发布日期:2025-05-30
通讯作者: Ding Zhang,E-mail:zhangdingkathy@njust.edu.cn
基金资助:
This work was supported by the National Key Research and Development Program of China (2022YFC3004901-3), the National Natural Science Foundation of China (21908109), the Open Project of Key Laboratory of Fire Emergency Rescue Equipment of Ministry of Emergency Management of People's Republic of China (2020XFZB05), the Fundamental Research Funds for the Central Universities (30919011272), the Natural Science Foundation of Jiangsu Province (BK20180816). And the properties characterization process was supported by Analysis and Testing Center of Nanjing University of Science and Technology.

Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO₂ particles prepared by facile spraying technique

Mengyuan Peng¹, Qi Wang², Min Sha³, Biao Jiang^1,4, Ding Zhang^1,4

1. School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;
2. Xi'an Aerospace Chemical Propulsion Co., Ltd., Xi'an 710025, China;
3. School of Management Science & Engineering, Nanjing University of Finance & Economics, Jiangsu 210046, China;
4. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Origanic Chemistry, Chinese Academy Sciences, Shanghai 200032, China

Received:2024-11-22 Revised:2025-02-21 Accepted:2025-03-06 Online:2025-09-28 Published:2025-05-30
Contact: Ding Zhang,E-mail:zhangdingkathy@njust.edu.cn
Supported by:
This work was supported by the National Key Research and Development Program of China (2022YFC3004901-3), the National Natural Science Foundation of China (21908109), the Open Project of Key Laboratory of Fire Emergency Rescue Equipment of Ministry of Emergency Management of People's Republic of China (2020XFZB05), the Fundamental Research Funds for the Central Universities (30919011272), the Natural Science Foundation of Jiangsu Province (BK20180816). And the properties characterization process was supported by Analysis and Testing Center of Nanjing University of Science and Technology.

摘要/Abstract

摘要： Superhydrophobicity endows various substrates with astonishing multifunctional properties and has received widespread praise in industrial production. However, the fragile connection between the coating and the substrate not only limits the service life of superhydrophobic coatings, but also poses limitations. To address this issue, this study used 3-(perfluorooctyl) propanol and organic polysilazane (OPSZ) with universal anchoring properties as starting materials to obtain fluorine modified OPSZ through a one-step synthesis method, and then doped SiO₂ micro nano particles to produce superhydrophobic coatings that can be widely applied to various substrates. Investigating the relationship between the hydrophobic properties of the coatings and the amounts of SiO₂ microparticles and nanoparticles used to create the microscopic rough structure of the superhydrophobic coatings, it was discovered that the hydrophobic properties of the coatings tended to increase as the number of nanoparticles increased. The water contact angle of prepared coatings was still over 157° after 48 h of UV exposure or 180 days of exposure to air. The heat resistance of the created superhydrophobic coatings was tested in a muffle furnace at 400 ℃ for 2 h. The results revealed that the coatings maintained their water contact angle of 155.1°±3.01° and water sliding angle of 6.4°±1.98°, demonstrating their excellent heat resistance and suitability for use in a variety of high-temperature environments. The work provided a practical way for creating superhydrophobic composite coatings with excellent mechanical stability, acid and alkali corrosion resistance, and heat resistance, and had potential application in antifouling and anti-corrosion.

关键词: Superhydrophobic coatings, Polysilazane polymers, Fluorine-modified, Composites, Nanoparticles, Self-cleaning

Abstract: Superhydrophobicity endows various substrates with astonishing multifunctional properties and has received widespread praise in industrial production. However, the fragile connection between the coating and the substrate not only limits the service life of superhydrophobic coatings, but also poses limitations. To address this issue, this study used 3-(perfluorooctyl) propanol and organic polysilazane (OPSZ) with universal anchoring properties as starting materials to obtain fluorine modified OPSZ through a one-step synthesis method, and then doped SiO₂ micro nano particles to produce superhydrophobic coatings that can be widely applied to various substrates. Investigating the relationship between the hydrophobic properties of the coatings and the amounts of SiO₂ microparticles and nanoparticles used to create the microscopic rough structure of the superhydrophobic coatings, it was discovered that the hydrophobic properties of the coatings tended to increase as the number of nanoparticles increased. The water contact angle of prepared coatings was still over 157° after 48 h of UV exposure or 180 days of exposure to air. The heat resistance of the created superhydrophobic coatings was tested in a muffle furnace at 400 ℃ for 2 h. The results revealed that the coatings maintained their water contact angle of 155.1°±3.01° and water sliding angle of 6.4°±1.98°, demonstrating their excellent heat resistance and suitability for use in a variety of high-temperature environments. The work provided a practical way for creating superhydrophobic composite coatings with excellent mechanical stability, acid and alkali corrosion resistance, and heat resistance, and had potential application in antifouling and anti-corrosion.

Key words: Superhydrophobic coatings, Polysilazane polymers, Fluorine-modified, Composites, Nanoparticles, Self-cleaning

Mengyuan Peng, Qi Wang, Min Sha, Biao Jiang, Ding Zhang. Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO₂ particles prepared by facile spraying technique[J]. 中国化学工程学报, 2025, 85(9): 335-347.

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Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO₂ particles prepared by facile spraying technique

Durable self-cleaning superhydrophobic composite coatings based on fluorine-modified organic polysilazane and SiO₂ particles prepared by facile spraying technique

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