SCI和EI收录∣中国化工学会会刊

›› 2010, Vol. 18 ›› Issue (2): 351-354.

• • 上一篇    

Effect of the Interference Instant of Zeolite HY Catalyst on the Pyrolysis of Pubescens

刘文武, 胡常伟, 杨宇, 祝良芳, 童冬梅   

  1. Key Laboratory of Green Chemistry and Technology, Minister of Education, College of Chemistry, Sichuan University, Chengdu 610064, China
  • 收稿日期:2009-06-13 修回日期:2009-11-09 出版日期:2010-04-28 发布日期:2010-04-28
  • 通讯作者: HU Changwei,E-mail:Changweihu@scu.edu.cn
  • 基金资助:
    Supported by the State Key Development Program for Basic Research of China(2007CB210203);the Special Research Fund for the Doctoral Program of Higher Education of China(20050610013)

Effect of the Interference Instant of Zeolite HY Catalyst on the Pyrolysis of Pubescens

LIU Wenwu, HU Changwei, YANG Yu, ZHU Liangfang, TONG Dongmei   

  1. Key Laboratory of Green Chemistry and Technology, Minister of Education, College of Chemistry, Sichuan University, Chengdu 610064, China
  • Received:2009-06-13 Revised:2009-11-09 Online:2010-04-28 Published:2010-04-28
  • Supported by:
    Supported by the State Key Development Program for Basic Research of China(2007CB210203);the Special Research Fund for the Doctoral Program of Higher Education of China(20050610013)

摘要: A laboratory reactor was designed to test the effect of the interference instant of HY on the pyrolysis of pubescens.The time instant for intermediate species from pyrolysis to contact HY was controlled by varying the position of the catalyst bed relative to the pyrolytic cell.It was found that the effect of the interference instant was significant on the variation of different intermediate species,and the yield and quality of the products.The results also showed that,with the increase in the distance between the pyrolytic cell and the catalyst bed,the yield of liquid and relative content of the organics such as aldehyde,phenols,etc.,decreased,while the yield of residue and relative content of acetic acid increased.The deoxygenation of the intermediate species was favored when the catalyst exerted its performance on them immediately after their formation.

关键词: zeolite HY, catalytic pyrolysis, pubescens, acetic acid, intermediate conversion

Abstract: A laboratory reactor was designed to test the effect of the interference instant of HY on the pyrolysis of pubescens.The time instant for intermediate species from pyrolysis to contact HY was controlled by varying the position of the catalyst bed relative to the pyrolytic cell.It was found that the effect of the interference instant was significant on the variation of different intermediate species,and the yield and quality of the products.The results also showed that,with the increase in the distance between the pyrolytic cell and the catalyst bed,the yield of liquid and relative content of the organics such as aldehyde,phenols,etc.,decreased,while the yield of residue and relative content of acetic acid increased.The deoxygenation of the intermediate species was favored when the catalyst exerted its performance on them immediately after their formation.

Key words: zeolite HY, catalytic pyrolysis, pubescens, acetic acid, intermediate conversion