Transport of Indium, Gallium and Thallium Metal Ions Through Chromatographic Fiber Supported Solid Membrane in Acetylacetone Containing Mixed Solvents

摘要/Abstract

摘要： The transport of metal ions of indium, gallium and thallium from source solution to receiving phase through the chromatographic fiber supported solid membrane in the acetylacetone (HAA) containing mixed solvent system has been explored. The fibers supported solid membranes were prepared with chemical synthesis from cellulose fibers and citric acid with the carboxylic acid ion exchange groups introduced. The experimental variables, such as concentration of metal ions (10^-2 to 10^-4 mol·L^-1) in the source solution, mixed solvent composition [for example, acetylacetone, (2,4-pentanedione), (HAA) 20% (by volume), 1,4-dioxane 10% to 60% and HCl 0.25 to 2 mol·L^-1] in the receiving phase and stirring speed (50-130 r·min^-1) of the bulk source and receiving phase, were explored. The efficiency of mixed solvents for the transport of metal ions from the source to receiving phase through the fiber supported solid membrane was evaluated. The combined ion exchange solvent extraction (CIESE) was observed effective for the selective transport of thallium, indium and gallium metal ions through fiber supported solid membrane in mixed solvents. The oxonium salt formation in the receiving phase enhances thallium, indium and gallium metal ion transport through solid membrane phase. The selective transport of thallium metal ions from source phase was observed from indium and gallium metal ions in the presence of hydrochloric acid in organic solvents in receiving phase. The separation of thallium metal ions from the binary mixtures of Be(II), Ti(IV), Al(III), Ca(II), Mg(II), K (I), La(III) and Y(III) was carried out in the mixed solvent system using cellulose fiber supported solid membrane.

关键词: metal ions transfer, fiber supported solid membrane, acetylacetone, extraction, stripping

Abstract: The transport of metal ions of indium, gallium and thallium from source solution to receiving phase through the chromatographic fiber supported solid membrane in the acetylacetone (HAA) containing mixed solvent system has been explored. The fibers supported solid membranes were prepared with chemical synthesis from cellulose fibers and citric acid with the carboxylic acid ion exchange groups introduced. The experimental variables, such as concentration of metal ions (10^-2 to 10^-4 mol·L^-1) in the source solution, mixed solvent composition [for example, acetylacetone, (2,4-pentanedione), (HAA) 20% (by volume), 1,4-dioxane 10% to 60% and HCl 0.25 to 2 mol·L^-1] in the receiving phase and stirring speed (50-130 r·min^-1) of the bulk source and receiving phase, were explored. The efficiency of mixed solvents for the transport of metal ions from the source to receiving phase through the fiber supported solid membrane was evaluated. The combined ion exchange solvent extraction (CIESE) was observed effective for the selective transport of thallium, indium and gallium metal ions through fiber supported solid membrane in mixed solvents. The oxonium salt formation in the receiving phase enhances thallium, indium and gallium metal ion transport through solid membrane phase. The selective transport of thallium metal ions from source phase was observed from indium and gallium metal ions in the presence of hydrochloric acid in organic solvents in receiving phase. The separation of thallium metal ions from the binary mixtures of Be(II), Ti(IV), Al(III), Ca(II), Mg(II), K (I), La(III) and Y(III) was carried out in the mixed solvent system using cellulose fiber supported solid membrane.

Key words: metal ions transfer, fiber supported solid membrane, acetylacetone, extraction, stripping

Abaji Gaikwad. Transport of Indium, Gallium and Thallium Metal Ions Through Chromatographic Fiber Supported Solid Membrane in Acetylacetone Containing Mixed Solvents[J]. , 2011, 19(6): 955-963.

参考文献

1 Vibhute, C.P., Khopkar, S.M., “Solvent extraction separation of gallium, indium and thallium with high relative molecular mass amine from citrate solutions”, Analyst, 111, 435-439(1986).
2 Fritz, J.S., Prazee, R.T., Latwesen, G.L., “Column chromatographic separation of gallium, indium and thallium”, Talanta, 17(9), 857-864(1970)
3 Korkisch, J., “Combined ion exchange-solvent extraction: A new dimension in inorganic separation chemistry”, Nature, 210, 626-627(1966).
4 Gaikwad, A.G., Khopkar, S.M., “Cation exchange chromatographic separation of lead from mixed solvents”, J. Liquid Chromatogr., 89(14), 2705-2718(1985).
5 Dworecki, K., Wasik, S., “The investigation of time-dependent solute transport through a horizontally situated membrane: the effect of a configuration membrane system”, J. Biol. Phys., 23, 181-195(1997).
6 Yu, M.Q., Sun, D.W., Huang, R., Tian, W., Shen, W.B., Zhang, H.C., Xu, N., “Determination of ultra-trace gold in natural water by graphite furnace atomic absorption spectrophotometry after in situ enrichment with thiol cotton fiber”, Anal. Chim. Acta., 479(2), 225-231(2003).
7 Yu, M.Q., Sun, D.W.,Tian, W., Shen, W.B., Zhang, H.C., Xu, N., “Systematic studies on adsorption of trace elements Pt, Pd, Au, Se, Te, As, Hg, Sb on thiol cotton fiber”, Anal. Chim. Acta., 456(1), 147-155(2002).
8 Yu, M.Q., Tian, W., Sun, D.W., Shen, W.B., Zhang, H.C., Xu, N., “Systematic studies on adsorption of 11 trace heavy metals on thiol cotton fiber”, Anal Chim. Acta, 428(2), 209-218(2002).
9 Kaewprasit, C., Hequet, E., Noureddine, A.A., Jean, P.G., “Application of methylene blue adsorption to cotton fiber specific surface area measurement, Part I, methodology”, J. Cotton. Sci., 2, 164-173(1998).
10 Jinno, K., Watanabe, H., Saito, Y., Takeichi, T., “Capillary electrochromatography using fibers as stationary phases”, Electrophoresis, 22, 3371-3376(2001).
11 Saito, Y., Ueta, I., Ogawa, M., Abe, A., Yogo, K., Shirai, S., Jinno, K., “Fiber-packed needle-type sample preparation device designed for gas chromatographic analysis”, Anal. Bioanal. Chem., 393, 861-869(2009).
12 Jinno, K., Wu, J., Sawada, H., “Cellulose acetate fiber as stationary phase in capillary electrochromatography”, J. High Resol. Chromatogr., 21(11), 617-619(1998).
13 Saito, Y., Nakao, Y., Imaizumi, M., Takeichi, T., Kiso, Y., Jinno, K., “Fiber-in-tube solid-phase micro-extraction: a fibrous rigid-rod heterocyclic polymer as the extraction medium”, Fresenius J. Anal. Chem., 368, 641-643(2000).
14 Kataoka, H., “Recent developments and applications of microextraction techniques in drug analysis”, Anal. Bioanal. Chem., 396, 339-364(2010).
15 Nada, A.M.A., El-Wakil, N.A., Hassan, M.L., Adel, A.M., “Differential adsorption of heavy metal ions by cotton stalk cation-exchangers containing multiple functional groups”, J. Appl. Polym. Sci., 101, 4124-4132(2006).
16 Dietz, G., Seshadri, T., Haupt, H.J., Kettrup, A., “Preparation, characterization and application of a cellulose ion-exchanger with acetoacetamide functional groups”, Fresenius J. Anal. Chem., 322, 491-494(1985).
17 Aoki, N., Fukushima, K., Kurakata, H., Sakamoto, M., Furuhata, K., “6-Deoxy-6-mercapto cellulose and its S-substituted derivatives as sorbents for metal ions”, React. Funct. Polym., 42, 223-233(1999).
18 Gurnani, V., Singh, A.K., Venkataramani, B., “Cellulose based macromolecular chelator having pyrocatechol as an anchored ligand: synthesis and applications as metal extractant prior to their determination by flame atomic absorption spectrometry”, Talanta, 61, 889-903(2003).
19 Gurnani, V., Singh, A.K., Venkataramani, B., “Cellulose functionalized with 8-hydroxyquinoline: new method of synthesis and applications as a solid phase extractant in the determination of metal ions by flame atomic absorption spectrometry”, Anal. Chim. Acta, 485, 221-232(2003).
20 Gennaro, M.C., Sarzanini, C., Mentasti, E., Baiocchi, C., “Use of methylimindiacetic acid bound to cellulose for pre-concentration and determination of trace metal cations”, Talanta, 32, 961-966(1985).
21 Tsysin, G.I., Mikhura, I.V., Formanovsky, A., Yury, AZ., “Cellulose fibrous sorbents with conformationally flexible aminocarboxylic groups for preconcentration of metals”, Mikrochim. Acta, 105, 53-60(1991).
22 Gong, R., Hu, Y., Chen, J., Chen, F., Liu, Z., A cellulose-based carboxyl cotton chelator having citric acid as an anchored ligand: preparation and application as solid phase extractant for copper determination by flame atomic absorption spectrometry”, Microchim. Acta, 158, 315-320(2007).
23 Debashish, R., James, T., Guthrie, S.P., “Graft polymerization: grafting poly(styrene) from cellulose via reversible addition fragmentation chain transfer(RAFT) polymerization”, Macromolecules, 38, 10363-10372(2005).
24 Gong, R., Zhong, K., Hu, Y., Chen, J., Zhu, G., “Thermochemical esterifying citric acid onto lignocellulose for enhancing methylene blue sorption capacity of rice straw”, J. Environ. Manag., 88, 875-880(2008).
25 Sana, S., Sibel, B., “Synthesis of a new cellulose ion exchanger and use for the separation of heavy metals in aqueous solutions”, Sepn. Sci. Technol., 40(10), 2067-2078(2005).
26 Xiong, X.P., Duan, J.J., Zou, W.W., He, X.M., Zheng, W., “A pH-sensitive regenerated cellulose membrane”, J. Membr. Sci., 363, 96-102(2010).
27 Korkisch, J., Ahluwalia, S.S., “Separation of uranium by combined ion exchange-solvent extraction”, Anal. Chem., 38(3), 497-500(1966).
28 Ani1, K.D., Bhattacharyya, C.R., “Combined ion exchange-solvent extraction(CIESE) studies of metal ions on ion exchange papers”, Anal. Chem., 44(9), 1686-1688(1972).
29 Zhang, X., Yin, G., Hu, Z., “Extraction and separation of gallium, indium and thallium with several carboxylic acids from chloride media”, Talanta, 59, 905-912(2003)
30 Danesi, P.R., “Separation of metal species by supported liquid membranes”, Sepn. Sci. Technol., 19, 857-894(1984/1985).
31 Chakrabarty, T., Mahendra, K., Rajesh, K.P., Vinod, K.S., Natarajan, T.S., “Nano-fibrous sulfonated poly(ether ether ketone) membrane for selective electro-transport of ions”, Sepn. Purifn. Technol., 75(2), 165-173(2010).

[1]	Xiaolin Guo, Zhaoyang Zhang, Pengfei Xing, Shuai Wang, Yibing Guo, Yanxin Zhuang. Kinetic mechanism of copper extraction from methylchlorosilane slurry residue using hydrogen peroxide as oxidant[J]. 中国化学工程学报, 2023, 60(8): 228-234.
[2]	Chaobo Zhang, Xiaoyong Yang, Jian Dai, Wenxia Liu, Hang Yang, Zhishan Bai. Efficient extraction of phenol from wastewater by ionic micro-emulsion method: Anionic and cationic[J]. 中国化学工程学报, 2023, 58(6): 137-145.
[3]	Hui Yi Leong, Xiao-Qian Fu, Xiang-Yu Liu, Shan-Jing Yao, Dong-Qiang Lin. Characterisation and separation of infectious bursal disease virus-like particles using aqueous two-phase systems[J]. 中国化学工程学报, 2023, 57(5): 72-78.
[4]	Yunchang Fan, Chunyan Zhu, Sheli Zhang, Lei Zhang, Qiang Wang, Feng Wang. Efficient and selective extraction of sinomenine by deep eutectic solvents[J]. 中国化学工程学报, 2023, 57(5): 109-117.
[5]	Dandan Ren, Shanshan Xiang, Yuwen Yan, Ruiying Kong, Xingchu Gong. Design and optimization of purification process of sinomenine hydrochloride[J]. 中国化学工程学报, 2023, 55(3): 63-72.
[6]	Qinyan Wang, Yang Jin, Jun Li, Yongbo Zhou, Ming Chen. Study on liquid–liquid two-phase mass transfer characteristics in the microchannel with deformed insert[J]. 中国化学工程学报, 2023, 54(2): 114-126.
[7]	Zhixian Chang, Xiangfeng Zhou, Huihua Bai, Deliang Li, Ling Zhang. Intensified reactive extraction of 4-hydroxypyridine with di(2-ethylhexyl) phosphoric acid in 1-octanol by using tributyl phosphate[J]. 中国化学工程学报, 2023, 54(2): 199-205.
[8]	Yinglin Mai, Xiaoling Xian, Lei Hu, Xiaodong Zhang, Xiaojie Zheng, Shunhui Tao, Xiaoqing Lin. Liquid–liquid extraction of levulinic acid from aqueous solutions using hydrophobic tri-n-octylamine/alcohol-based deep eutectic solvent[J]. 中国化学工程学报, 2023, 54(2): 248-256.
[9]	Yong Niu, Xiaowu Peng, Jinfeng Li, Yuze Zhang, Fugen Song, Dong Shi, Lijuan Li. Recovery of Li₂CO₃ and FePO₄ from spent LiFePO₄ by coupling technics of isomorphic substitution leaching and solvent extraction[J]. 中国化学工程学报, 2023, 54(2): 306-315.
[10]	Ping Zhang, Chao Gong, Tao Zhou, Peng Du, Jieyu Song, Mengyang Shi, Xuerui Wang, Xuehong Gu. Helium extraction from natural gas using DD3R zeolite membranes[J]. 中国化学工程学报, 2022, 49(9): 122-129.
[11]	Fengfeng Gao, Jinhua Luo, Xuefeng Zhang, Xiaogang Hao, Guoqing Guan, Zhong Liu, Jun Li, Qinglong Luo. Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions[J]. 中国化学工程学报, 2022, 49(9): 161-169.
[12]	Dengke Pang, Zhihong Zhang, Yongquan Zhou, Zhenhai Fu, Quan Li, Yongming Zhang, Guangguo Wang, Zhuanfang Jing. The process and mechanism for cesium and rubidium extraction with saponified 4-tert-butyl-2-(α-methylbenzyl) phenol[J]. 中国化学工程学报, 2022, 46(6): 31-39.
[13]	Ye Zhang, Yong Gao, Peng Wang, Duo Na, Zhenming Yang, Jinsong Zhang. Solvent extraction with a three-dimensional reticulated hollow-strut SiC foam microchannel reactor[J]. 中国化学工程学报, 2022, 46(6): 53-62.
[14]	Chao Zhang, Huifang Xing, Liangrong Yang, Pengfei Fei, Huizhou Liu. Development trend and prospect of solid phase extraction technology[J]. 中国化学工程学报, 2022, 42(2): 245-255.
[15]	Zhen Liu, Haiquan An, Jiansheng Zhang. Discharge characteristics of coal and extraction residue from direct coal liquefaction in partial fluidization silo[J]. 中国化学工程学报, 2022, 52(12): 78-87.