SCI和EI收录∣中国化工学会会刊

›› 2011, Vol. 19 ›› Issue (6): 983-989.

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Simulation and Analysis on Multiple Steady States of an Industrial Acetic Acid Dehydration System

李绍军, 黄定伟   

  1. Key Laboratory of Advanced Control and Optimization for Chemical Processes (East China University of Science and Technology), Ministry of Education, Shanghai 200237, China
  • 收稿日期:2010-09-15 修回日期:2011-06-07 出版日期:2011-12-28 发布日期:2012-04-24
  • 通讯作者: LI Shaojun, E-mail: lishaojun@ecust.edu.cn
  • 基金资助:
    Supported by the National Natural Science Foundation of China (20976048);Shanghai Leading Academic Discipline Project (B504)

Simulation and Analysis on Multiple Steady States of an Industrial Acetic Acid Dehydration System

LI Shaojun, HUANG Dingwei   

  1. Key Laboratory of Advanced Control and Optimization for Chemical Processes (East China University of Science and Technology), Ministry of Education, Shanghai 200237, China
  • Received:2010-09-15 Revised:2011-06-07 Online:2011-12-28 Published:2012-04-24
  • Supported by:
    Supported by the National Natural Science Foundation of China (20976048);Shanghai Leading Academic Discipline Project (B504)

摘要: In this work, an industrial acetic acid dehydration system via heterogeneous azeotropic distillation is simulated by Aspen Plus software. Residue curves are used to analyze the distillating behavior, and appropriate operating region of the system is determined. Based on steady states simulation, a sensitivity analysis is carried out to detect the output multiple steady states in the system. Different solution branches are observered when the flow rates of the feed stream and the organic reflux stream are selected as manipulated variables. The performance of the column under different steady states is different. A method is proposed to achieve the desired steady state.

关键词: acetic acid dehydration, heterogeneous azeotropic distillation, residue curve, multiple steady states

Abstract: In this work, an industrial acetic acid dehydration system via heterogeneous azeotropic distillation is simulated by Aspen Plus software. Residue curves are used to analyze the distillating behavior, and appropriate operating region of the system is determined. Based on steady states simulation, a sensitivity analysis is carried out to detect the output multiple steady states in the system. Different solution branches are observered when the flow rates of the feed stream and the organic reflux stream are selected as manipulated variables. The performance of the column under different steady states is different. A method is proposed to achieve the desired steady state.

Key words: acetic acid dehydration, heterogeneous azeotropic distillation, residue curve, multiple steady states