Study on Kinetics of Iron Oxide Reduction by Hydrogen

›› 2012, Vol. 20 ›› Issue (1): 10-17.

Study on Kinetics of Iron Oxide Reduction by Hydrogen

侯宝林, 张海英, 李洪钟, 朱庆山

State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2011-06-17 修回日期:2011-12-06 出版日期:2012-02-28 发布日期:2012-05-03
通讯作者: LI Hongzhong,E-mail:hzli@home.ipe.ac.cn;ZHU Qingshan,E-mail:qszhu@home.ipe.ac.cn
基金资助:
Supported by the National Natural Science Foundation of China (20736004);the State Key Development Program for Basic Research of China (2007CB613502)

Study on Kinetics of Iron Oxide Reduction by Hydrogen

HOU Baolin, ZHANG Haiying, LI Hongzhong, ZHU Qingshan

State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2011-06-17 Revised:2011-12-06 Online:2012-02-28 Published:2012-05-03
Supported by:
Supported by the National Natural Science Foundation of China (20736004);the State Key Development Program for Basic Research of China (2007CB613502)

摘要/Abstract

摘要： Kinetics parameters of iron oxide reduction by hydrogen were evaluated by the isothermal method in a differential micro-packed bed.Influence of external diffusion,internal diffusion and heat transfer on the intrinsic reaction rate was investigated and the conditions free of internal and external diffusion resistance have been determined.In the experiments,in order to correctly evaluate the intrinsic kinetics parameters for reducing Fe₂O₃ to Fe₃O₄,the reaction temperatures were set between 440℃ and 490℃.However,in order to distinguish the reduction of Fe₃O₄ to FeO from that of FeO to Fe,the reaction temperature in the experiment was set to be greater than 570℃.Intrinsic kinetics of iron oxide reduction by hydrogen was established and the newly established kinetic models were validated by the experimental data.

关键词: isothermal method, reduction kinetics, iron oxide, packed bed, hydrogen reduction

Abstract: Kinetics parameters of iron oxide reduction by hydrogen were evaluated by the isothermal method in a differential micro-packed bed.Influence of external diffusion,internal diffusion and heat transfer on the intrinsic reaction rate was investigated and the conditions free of internal and external diffusion resistance have been determined.In the experiments,in order to correctly evaluate the intrinsic kinetics parameters for reducing Fe₂O₃ to Fe₃O₄,the reaction temperatures were set between 440℃ and 490℃.However,in order to distinguish the reduction of Fe₃O₄ to FeO from that of FeO to Fe,the reaction temperature in the experiment was set to be greater than 570℃.Intrinsic kinetics of iron oxide reduction by hydrogen was established and the newly established kinetic models were validated by the experimental data.

Key words: isothermal method, reduction kinetics, iron oxide, packed bed, hydrogen reduction

中图分类号:

O643.12

侯宝林, 张海英, 李洪钟, 朱庆山. Study on Kinetics of Iron Oxide Reduction by Hydrogen[J]. , 2012, 20(1): 10-17.

HOU Baolin, ZHANG Haiying, LI Hongzhong, ZHU Qingshan. Study on Kinetics of Iron Oxide Reduction by Hydrogen[J]. , 2012, 20(1): 10-17.

参考文献

1 Tsay,Q.T.,Ray,W.H.,Szekely,J.,"The modeling of hematite reduction with hydrogen plus carbon monoxide mixtures:Part Ⅱ.The direct reduction process in a shaft furnace arrangement",AIChE J.,22,1072-1079(1976).
2 Tsay,Q.T.,Ray,W.H.,Szekely,J.,"The modeling of hematite reduction with hydrogen plus carbon monoxide mixtures:Part Ⅰ.The behavior of single pellets",AIChE J.,22,1064-1072(1976).
3 Warner,N.A.,"Reduction kinetics of hematite and the influence of gaseous diffusion",Trans.Metall.Soc.AIME,230,1631-1676(1964).
4 Spitzer,R.H.,Manning,F.S.,Philbrook,W.O.,"Generalized model for the gaseous,topochemical reduction of porous hematite spheres",Trans.Metall.Soc.AIME,236,1715-1723(1966).
5 Jozwiak,W.K.,Kaczmarek,E.,Maniecki,T.P.,Ignaczak,W.,Maniukiewic,W.Z.,"Reduction behavior of iron oxides in hydrogen and carbon monoxide atmospheres",Appl.Catal.A,326,17-27(2007).
6 Srinivasan,N.S.,Staffansson,L.,"A theoretical analysis of the fluidized-bed process for the reduction of iron ores",Chem Eng Sci,45,1253-1265(1990).
7 Pineau,A.,Kanari,N.,Gaballah,I.,"Kinetics of reduction of iron oxides by H₂:Part Ⅰ:Low temperature reduction of hematite",Thermochim.Acta,447,89-100(2006).
8 Pineau,A.,Kanari,N.,Gaballah,I.,"Kinetics of reduction of iron oxides by H₂:Part Ⅱ.Low temperature reduction of magnetite",Thermochim.Acta,456,75-88(2007).
9 9 Piotrowski,K.,Mondal,K.,Lorethova,H.,Stonawski,L.,Szymanski,T.,Wiltowski,T.,"Effect of gas composition on the kinetics of iron oxide reduction in a hydrogen production process",Int. J.Hydrogen Energy,30,1543-1554(2005).
10 Heidebrecht,P.,Galvita,V.,Sundmacher,K.,"An alternative method for parameter identification from temperature programmed reduction (TPR)data",Chem Eng Sci,63,4776-4788(2008).
11 Lin,H.Y.,Chen,Y.W.,Li,C.,"The mechanism of reduction of iron oxide by hydrogen",Thermochim Acta,400,61-67(2003).
12 Szekely,J.,Evans,J.W.,Sohn,H.Y.,Gas-Solid Reactions,Academic Press,London,100-110(1976).
13 Ortega,A.,"Some successes and failures of the methods based on several experiments",Thermochim Acta,284,379-387(1996).
14 Bohn,C.D.,Cleeton,J.P.,Müller,C.R.,Davidson,J.F.,Hayhurst,A.N.,Scott,S.A.,"The kinetics of the reduction of iron oxide by carbon monoxide mixed with carbon dioxide",AIChE J,56,1016-1029(2010).
15 Srinivasan,N.S.,"Reduction of iron oxides by carbon in a circulating fluidized bed reactor",Powder Technol,124,28-29(2002).
16 Zhao,Y.,Shadman,F.,"Reduction of ilmenite with hydrogen",Ind. Eng.Chem.Res.,30,2080-2087(1991).
17 Sun,K.,Lu,W.K.,"Mathematical modeling of the kinetics of carbothermic reduction of iron oxides in ore-coal composite pellets",Metall.Mater.Trans.B,40,91-103(2009).
18 Fogler,H.S.,Elements of Chemical Reaction Engineering,Prentice Hall Press,New York(2005).

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Study on Kinetics of Iron Oxide Reduction by Hydrogen

Study on Kinetics of Iron Oxide Reduction by Hydrogen

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