A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

doi:10.1016/S1004-9541(13)60573-X

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (9): 1007-1014.DOI: 10.1016/S1004-9541(13)60573-X

• 催化、动力学与反应工程 • 上一篇下一篇

A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

Abolfazl Gharibi Kharaji¹, Ahmad Shariati¹, Mohammad Ali Takassi²

1 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Chemical Engineering Department, Ahwaz, Iran;
2 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Science Department, Ahwaz, Iran

收稿日期:2012-01-21 修回日期:2012-06-03 出版日期:2013-09-28 发布日期:2013-10-01
通讯作者: Ahmad Shariati
基金资助:
Supported by the Iranian Nano Technology Initiative Council and Petroleum University of Technology

A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

Abolfazl Gharibi Kharaji¹, Ahmad Shariati¹, Mohammad Ali Takassi²

1 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Chemical Engineering Department, Ahwaz, Iran;
2 Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Science Department, Ahwaz, Iran

Received:2012-01-21 Revised:2012-06-03 Online:2013-09-28 Published:2013-10-01
Contact: Ahmad Shariati
Supported by:
Supported by the Iranian Nano Technology Initiative Council and Petroleum University of Technology

摘要/Abstract

摘要： In reverse water gas shift (RWGS) reaction CO₂ is converted to CO which in turn can be used to produce beneficial chemicals such as methanol. In the present study, Mo/Al₂O₃, Fe/Al₂O₃ and Fe-Mo/Al₂O₃ catalysts were synthesised using impregnation method. The structures of catalysts were studied using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) method, inductively coupled plasma atomic emission spectrometer (ICP-AES), temperature programmed reduction (H₂-TPR), CO chemisorption, energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. Kinetic properties of all catalysts were investigated in a batch reactor for RWGS reaction. The results indicated that Mo existence in structure of Fe-Mo/Al₂O₃ catalyst enhances its activity as compared to Fe/Al₂O₃. This enhancement is probably due to better Fe dispersion and smaller particle size of Fe species. Stability test of Fe-Mo/Al₂O₃ catalyst was carried out in a fixed bed reactor and a high CO yield for 60 h of time on stream was demonstrated. Fe₂(MoO₄)₃ phase was found in the structures of fresh and used catalysts. TPR results also indicate that Fe₂(MoO₄)₃ phase has low reducibility, therefore the Fe₂(MoO₄)₃ phase signifificantly inhibits the reduction of the remaining Fe oxides in the catalyst, resulted in high stability of Fe-Mo/Al₂O₃ catalyst. Overall, this study introduces Fe-Mo/Al₂O₃ as a novel catalyst with high CO yield, almost no by-products and fairly stable for RWGS reaction.

关键词: reverse water gas shift reaction, Fe-Mo/Al₂O₃ catalyst, selectivity, stability, reducibility

Abstract: In reverse water gas shift (RWGS) reaction CO₂ is converted to CO which in turn can be used to produce beneficial chemicals such as methanol. In the present study, Mo/Al₂O₃, Fe/Al₂O₃ and Fe-Mo/Al₂O₃ catalysts were synthesised using impregnation method. The structures of catalysts were studied using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) method, inductively coupled plasma atomic emission spectrometer (ICP-AES), temperature programmed reduction (H₂-TPR), CO chemisorption, energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. Kinetic properties of all catalysts were investigated in a batch reactor for RWGS reaction. The results indicated that Mo existence in structure of Fe-Mo/Al₂O₃ catalyst enhances its activity as compared to Fe/Al₂O₃. This enhancement is probably due to better Fe dispersion and smaller particle size of Fe species. Stability test of Fe-Mo/Al₂O₃ catalyst was carried out in a fixed bed reactor and a high CO yield for 60 h of time on stream was demonstrated. Fe₂(MoO₄)₃ phase was found in the structures of fresh and used catalysts. TPR results also indicate that Fe₂(MoO₄)₃ phase has low reducibility, therefore the Fe₂(MoO₄)₃ phase significantly inhibits the reduction of the remaining Fe oxides in the catalyst, resulted in high stability of Fe-Mo/Al₂O₃ catalyst. Overall, this study introduces Fe-Mo/Al₂O₃ as a novel catalyst with high CO yield, almost no by-products and fairly stable for RWGS reaction.

Key words: reverse water gas shift reaction, Fe-Mo/Al₂O₃ catalyst, selectivity, stability, reducibility

Abolfazl Gharibi Kharaji, Ahmad Shariati, Mohammad Ali Takassi. A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction[J]. Chinese Journal of Chemical Engineering, 2013, 21(9): 1007-1014.

Abolfazl Gharibi Kharaji, Ahmad Shariati, Mohammad Ali Takassi. A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction[J]. Chin.J.Chem.Eng., 2013, 21(9): 1007-1014.

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A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

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