Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO2 capture

doi:10.1016/j.cjche.2021.07.010

中国化学工程学报 ›› 2022, Vol. 42 ›› Issue (2): 104-111.DOI: 10.1016/j.cjche.2021.07.010

• Recent Advances in Adsorptive Separation Materials and Technologies • 上一篇下一篇

Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO₂ capture

Peng Tan¹, Yao Jiang¹, Qiurong Wu¹, Chen Gu¹, Shichao Qi¹, Qiang Zhang², Xiaoqin Liu¹, Linbing Sun¹

1. State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China;
2. Department of Chemistry, Washington State University, Pullman, WA 99163, United States

收稿日期:2021-05-18 修回日期:2021-07-14 出版日期:2022-02-28 发布日期:2022-03-30
通讯作者: Linbing Sun,E-mail:lbsun@njtech.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (22078155, 21808110, 21878149, and 21676138), and China Postdoctoral Science Foundation (2020M681567). We are also grateful to the High Performance Computing Center of Nanjing Tech University for supporting the computational resources.

Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO₂ capture

Peng Tan¹, Yao Jiang¹, Qiurong Wu¹, Chen Gu¹, Shichao Qi¹, Qiang Zhang², Xiaoqin Liu¹, Linbing Sun¹

1. State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China;
2. Department of Chemistry, Washington State University, Pullman, WA 99163, United States

Received:2021-05-18 Revised:2021-07-14 Online:2022-02-28 Published:2022-03-30
Contact: Linbing Sun,E-mail:lbsun@njtech.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (22078155, 21808110, 21878149, and 21676138), and China Postdoctoral Science Foundation (2020M681567). We are also grateful to the High Performance Computing Center of Nanjing Tech University for supporting the computational resources.

摘要/Abstract

摘要： Amines in porous materials have been employed as active species for the selective CO₂ adsorption from natural gas because of their target-specific interactions. Nevertheless, it is difficult to modulate such strong interactions to reach a high efficiency in the adsorption processes. Herein, we fabricated light-responsive adsorbents with tunable adsorbent-adsorbate interactions for CO₂ capture. The adsorbents were synthesized by introducing primary and secondary amines into a mesoporous silica that had been grafted with azobenzene groups on the surfaces. The target-specific amine sites render the adsorbents significantly selective in the uptake of CO₂ over CH₄, and the azobenzene groups were used as light-responsive switches to influence the adsorbent-adsorbate interactions. The adsorbents can freely adsorb CO₂ when the azobenzene groups are in the trans state. Ultraviolet-light irradiation makes the azobenzene groups transform to the cis configuration, which greatly hinders amines in the uptake of CO₂. The caused difference of adsorption capacity can reach 34.9%. The alternative irradiation by ultraviolet- and visible-light can lead to a recyclable regulation on adsorption performance. The changes of the electrostatic potentials of amines are responsible for the light-induced regulation on adsorption.

关键词: Adsorbents, CO₂ capture, Selectivity, Light responsiveness, Azobenzene

Abstract: Amines in porous materials have been employed as active species for the selective CO₂ adsorption from natural gas because of their target-specific interactions. Nevertheless, it is difficult to modulate such strong interactions to reach a high efficiency in the adsorption processes. Herein, we fabricated light-responsive adsorbents with tunable adsorbent-adsorbate interactions for CO₂ capture. The adsorbents were synthesized by introducing primary and secondary amines into a mesoporous silica that had been grafted with azobenzene groups on the surfaces. The target-specific amine sites render the adsorbents significantly selective in the uptake of CO₂ over CH₄, and the azobenzene groups were used as light-responsive switches to influence the adsorbent-adsorbate interactions. The adsorbents can freely adsorb CO₂ when the azobenzene groups are in the trans state. Ultraviolet-light irradiation makes the azobenzene groups transform to the cis configuration, which greatly hinders amines in the uptake of CO₂. The caused difference of adsorption capacity can reach 34.9%. The alternative irradiation by ultraviolet- and visible-light can lead to a recyclable regulation on adsorption performance. The changes of the electrostatic potentials of amines are responsible for the light-induced regulation on adsorption.

Key words: Adsorbents, CO₂ capture, Selectivity, Light responsiveness, Azobenzene

Peng Tan, Yao Jiang, Qiurong Wu, Chen Gu, Shichao Qi, Qiang Zhang, Xiaoqin Liu, Linbing Sun. Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO₂ capture[J]. 中国化学工程学报, 2022, 42(2): 104-111.

参考文献

[1] B.M. Connolly, M. Aragones-Anglada, J. Gandara-Loe, N.A. Danaf, D.C. Lamb, J.P. Mehta, D. Vulpe, S. Wuttke, J. Silvestre-Albero, P.Z. Moghadam, A.E.H. Wheatley, D. Fairen-Jimenez, Tuning porosity in macroscopic monolithic metal-organic frameworks for exceptional natural gas storage, Nat. Commun. 10 (1) (2019) 2345
[2] K.V. Kumar, K. Preuss, M.M. Titirici, F. Rodríguez-Reinoso, Nanoporous materials for the onboard storage of natural gas, Chem. Rev. 117 (3) (2017) 1796-1825
[3] Y. Belmabkhout, P.M. Bhatt, K. Adil, R.S. Pillai, A. Cadiau, A. Shkurenko, G. Maurin, G.P. Liu, W.J. Koros, M. Eddaoudi, Natural gas upgrading using a fluorinated MOF with tuned H₂S and CO₂ adsorption selectivity, Nat. Energy 3 (12) (2018) 1059-1066
[4] S.J. Luo, Q.N. Zhang, L.X. Zhu, H.Q. Lin, B.A. Kazanowska, C.M. Doherty, A.J. Hill, P.Y. Gao, R.L. Guo, Highly selective and permeable microporous polymer membranes for hydrogen purification and CO₂ removal from natural gas, Chem. Mater. 30 (15) (2018) 5322-5332
[5] B. Dutcher, M.H. Fan, A.G. Russell, Amine-basedCO₂capture technology development from the beginning of 2013-A review, ACS Appl. Mater. Interfaces 7 (4) (2015) 2137-2148
[6] T. Filburn, J.J. Helble, R.A. Weiss, Development of supported ethanolamines and modified ethanolamines for CO₂ capture, Ind. Eng. Chem. Res. 44 (5) (2005) 1542-1546
[7] G.T. Rochelle, Amine scrubbing for CO₂ capture, Science 325 (5948) (2009) 1652-1654
[8] M. Wriedt, J.P. Sculley, A.A. Yakovenko, Y.G. Ma, G.J. Halder, P.B. Balbuena, H.C. Zhou, Low-energy selective capture of carbon dioxide by a pre-designed elastic single-molecule trap, Angew. Chem. Int. Ed. 51 (39) (2012) 9804-9808
[9] X. Liu, C.G. Sun, H. Liu, W.H. Tan, W.L. Wang, C. Snape, Developing hierarchically ultra-micro/mesoporous biocarbons for highly selective carbon dioxide adsorption, Chem. Eng. J. 361 (2019) 199-208
[10] Y.Y. You, X.J. Liu, Modeling of CO₂adsorption and recovery from wet flue gas by using activated carbon, Chem. Eng. J. 369 (2019) 672-685
[11] D.W. Wu, J. Liu, Y.J. Yang, Y. Zheng, Nitrogen/oxygen Co-doped porous carbon derived from biomass for low-pressure CO₂ capture, Ind. Eng. Chem. Res. 59 (31) (2020) 14055-14063
[12] Z.N. Song, Q.B. Dong, W.L. Xu, F.L. Zhou, X.H. Liang, M. Yu, Molecular layer deposition-modified 5A zeolite for highly efficient CO₂ capture, ACS Appl. Mater. Interfaces 10 (1) (2018) 769-775
[13] H.J. Choi, D. Jo, J.G. Min, S.B. Hong, The origin of selective adsorption of CO₂ on merlinoite zeolites, Angew. Chem. Int. Ed. 60 (8) (2021) 4307-4314
[14] S.J. Chen, M. Zhu, Y.C. Tang, Y. Fu, W.L. Li, B. Xiao, Molecular simulation and experimental investigation of CO₂ capture in a polymetallic cation-exchanged 13X zeolite, J. Mater. Chem. A 6(40) (2018) 19570-19583
[15] M.S. Khan, H. Kitayama, Y. Yamada, S. Gohda, H. Ono, D. Umeda, K. Abe, K. Hata, T. Ohba, High CO₂ sensitivity and reversibility on nitrogen-containing polymer by remarkable CO₂ adsorption on nitrogen sites, J. Phys. Chem. C 122 (42) (2018) 24143-24149
[16] M. Maruthapandi, L. Eswaran, R. Cohen, N. Perkas, J.H.T. Luong, A. Gedanken, Silica-supported nitrogen-enriched porous benzimidazole-linked and triazine-based polymers for the adsorption of CO₂, Langmuir 36 (16) (2020) 4280-4288
[17] B. Zhang, J. Yan, G. Li, Z.G. Wang, Cost-effective preparation of microporous polymers from formamide derivatives and adsorption of CO₂ under dry and humid conditions, Polym. Chem.10(24) (2019) 3371-3379
[18] D.K. Yoo, T.U. Yoon, Y.S. Bae, S.H. Jhung, Metal-organic framework MIL-101 loaded with polymethacrylamide with or without further reduction:Effective and selective CO₂ adsorption with amino or amide functionality, Chem. Eng. J. 380 (2020) 122496
[19] M. Oschatz, M. Antonietti, A search for selectivity to enable CO₂ capture with porous adsorbents, Energy Environ. Sci. 11 (1) (2018) 57-70
[20] C.A. Trickett, A. Helal, B.A. Al-Maythalony, Z.H. Yamani, K.E. Cordova, O.M. Yaghi, The chemistry of metal-organic frameworks for CO₂ capture, regeneration and conversion, Nat. Rev. Mater. 2 (8) (2017) 1-16
[21] Z.S. Campbell, S.Y. Han, S. Marre, M. Abolhasani, Continuous flow solar desorption of CO₂ from aqueous amines, ACS Sustain. Chem. Eng.9(6) (2021) 2570-2579
[22] X.W. Zhang, X. Zhang, H.L. Liu, W.S. Li, M. Xiao, H.X. Gao, Z.W. Liang, Reduction of energy requirement of CO₂ desorption from a rich CO₂-loaded MEA solution by using solid acid catalysts, Appl. Energy 202 (2017) 673-684
[23] H.C. Liu, S.N. Zhao, F. Zhou, C.Q. Yao, G.W. Chen, Ultrasonic enhancement of CO₂ desorption from MDEA solution in microchannels, Ind. Eng. Chem. Res. 58 (4) (2019) 1711-1719
[24] P. Tan, Y. Jiang, X.Q. Liu, L.B. Sun, Making porous materials respond to visible light, ACS Energy Lett. 4 (11) (2019) 2656-2667
[25] J.J. Ding, J. Zhu, Y.X. Li, X.Q. Liu, L.B. Sun, Smart adsorbents functionalized with thermoresponsive polymers for selective adsorption and energy-saving regeneration, Ind. Eng. Chem. Res. 56 (15) (2017) 4341-4349
[26] Y. Jiang, X.C. Shi, P. Tan, S.C. Qi, C. Gu, T. Yang, S.S. Peng, X.Q. Liu, L.B. Sun, Controllable CO₂ capture in metal-organic frameworks:Making targeted active sites respond to light, Ind. Eng. Chem. Res. 59 (50) (2020) 21894-21900
[27] Y. Jiang, J. Park, P. Tan, L. Feng, X.Q. Liu, L.B. Sun, H.C. Zhou, Maximizing photoresponsive efficiency by isolating metal-organic polyhedra into confined nanoscaled spaces, J. Am. Chem. Soc. 141 (20) (2019) 8221-8227
[28] Q.R. Wu, P. Tan, C. Gu, R. Zhou, S.C. Qi, X.Q. Liu, Y. Jiang, L.B. Sun, Smart adsorbents for CO₂ capture:Making strong adsorption sites respond to visible light, Sci. China Mater. 64 (2)(2021) 383-392
[29] L. Qin, W. Gu, J. Wei, Y.L. Yu, Piecewise phototuning of self-organized helical superstructures, Adv. Mater. 30 (2017) 1704941
[30] C.B. Fan, L.L. Gong, L. Huang, F. Luo, R. Krishna, X.F. Yi, A.M. Zheng, L. Zhang, S.Z. Pu, X.F. Feng, M.B. Luo, G.C. Guo, Significant enhancement of C₂H₂/C₂H₄ separation by a photochromic diarylethene unit:A temperature- and light-responsive separation switch, Angew. Chem. Int. Ed. 56 (27) (2017) 7900-7906
[31] A. Knebel, L. Sundermann, A. Mohmeyer, I. Strauß, S. Friebe, P. Behrens, J. Caro, Azobenzene guest molecules as light-switchable CO₂ valves in an ultrathin UiO-67 membrane, Chem. Mater. 29 (7) (2017) 3111-3117
[32] H.B. Huang, H. Sato, T. Aida, Crystalline nanochannels with pendant azobenzene groups:Steric or polar effects on gas adsorption and diffusion? J. Am. Chem. Soc. 139 (26) (2017) 8784-8787
[33] Z.Y. Liu, H.I. Wang, A. Narita, Q. Chen, Z. Mics, D. Turchinovich, M. Kläui, M. Bonn, K. Müllen, Photoswitchable micro-supercapacitor based on a diarylethene-graphene composite film, J. Am. Chem. Soc. 139 (28) (2017) 9443-9446
[34] P.K. Kundu, D. Samanta, R. Leizrowice, B. Margulis, H. Zhao, M. Börner, T. Udayabhaskararao, D. Manna, R. Klajn, Light-controlled self-assembly of non-photoresponsive nanoparticles, Nat. Chem. 7 (8) (2015) 646-652
[35] N. Huang, X.S. Ding, J. Kim, H. Ihee, D.L. Jiang, A photoresponsive smart covalent organic framework, Angew. Chem.Int. Ed. 54 (2015) 8704-8707
[36] E. Aznar, M. Oroval, L. Pascual, J.R. Murguía, R. Martínez-Máñez, F. Sancenón, Gated materials for on-command release of guest molecules, Chem. Rev. 116 (2) (2016) 561-718
[37] L.Q. Dong, Y.Y. Feng, L. Wang, W. Feng, Azobenzene-based solar thermal fuels:Design, properties, and applications, Chem. Soc. Rev. 47 (19) (2018) 7339-7368
[38] M. Grzelczak, L.M. Liz-Marzán, R. Klajn, Stimuli-responsive self-assembly of nanoparticles, Chem. Soc. Rev. 48 (5) (2019) 1342-1361
[39] I. Cobo, M. Li, B.S. Sumerlin, S. Perrier, Smart hybrid materials by conjugation of responsive polymers to biomacromolecules, Nat. Mater. 14 (2) (2015) 143-159
[40] Y. Jiang, P. Tan, S.C. Qi, X.Q. Liu, J.H. Yan, F. Fan, L.B. Sun, Metal-organic frameworks with target-specific active sites switched by photoresponsive motifs:Efficient adsorbents for tailorable CO₂ capture, Angew. Chem. Int. Ed. 58 (20) (2019) 6600-6604
[41] J. Zhu, P. Tan, P.P. Yang, X.Q. Liu, Y. Jiang, L.B. Sun, Smart adsorbents with reversible photo-regulated molecular switches for selective adsorption and efficient regeneration, Chem. Commun.52 (77) (2016) 11531-11534
[42] L. Cheng, Y. Jiang, S.C. Qi, W. Liu, S.F. Shan, P. Tan, X.Q. Liu, L.B. Sun, Controllable adsorption of CO₂ on smart adsorbents:An interplay between amines and photoresponsive molecules, Chem. Mater. 30 (10) (2018) 3429-3437
[43] J. Park, D.Q. Yuan, K.T. Pham, J.R. Li, A. Yakovenko, H.C. Zhou, Reversible alteration of CO₂ adsorption upon photochemical or thermal treatment in a metal-organic framework, J. Am. Chem. Soc. 134 (1) (2012) 99-102
[44] R. Lyndon, K. Konstas, B.P. Ladewig, P.D. Southon, P.C. Kepert, M.R. Hill, Dynamic photo-switching in metal-organic frameworks as a route to low-energy carbon dioxide capture and release, Angew. Chem. Int. Ed. 52 (13) (2013) 3695-3698
[45] J.J. Sun, Q.R. Wu, W.Q. Weng, X.Q. Liu, P. Tan, L.B. Sun, Smart light-responsive CO₂ adsorbents for regulating strong active sites, Acta Chim. Sinica 78 (10) (2020) 1082-1088
[46] L. Cheng, Y. Jiang, N. Yan, S.F. Shan, X.Q. Liu, L.B. Sun, Smart adsorbents with photoregulated molecular gates for both selective adsorption and efficient regeneration, ACS Appl. Mater. Interfaces 8 (35) (2016) 23404-23411

Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO₂ capture

Light-responsive adsorbents with tunable adsorbent-adsorbate interactions for selective CO₂ capture

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Qunfeng Zhang, Bingcheng Li, Yuan Zhou, Deshuo Zhang, Chunshan Lu, Feng Feng, Jinghui Lv, Qingtao Wang, Xiaonian Li. Regulation of the selective hydrogenation performance of sulfur-doped carbon-supported palladium on chloronitrobenzene[J]. 中国化学工程学报, 2023, 58(6): 69-75.
[2]	Jian Wang, Yuanhui Shen, Donghui Zhang, Zhongli Tang, Wenbin Li. Integrated vacuum pressure swing adsorption and Rectisol process for CO₂ capture from underground coal gasification syngas[J]. 中国化学工程学报, 2023, 57(5): 265-279.
[3]	Shanshan Mao, Tao Shen, Qing Zhao, Tong Han, Fan Ding, Xin Jin, Manglai Gao. Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets[J]. 中国化学工程学报, 2023, 57(5): 319-328.
[4]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[5]	Tutuk Djoko Kusworo, Monica Yulfarida, Andri Cahyo Kumoro, Dani Puji Utomo. Purification of bioethanol fermentation broth using hydrophilic PVA crosslinked PVDF-GO/TiO₂ membrane[J]. 中国化学工程学报, 2023, 55(3): 123-136.
[6]	Zhongqi Ren, Jie Wang, Hewei Zhang, Fan Zhang, Shichao Tian, Zhiyong Zhou. Adsorption of rubidium ion from aqueous solution by surface ion imprinted materials[J]. 中国化学工程学报, 2023, 54(2): 1-10.
[7]	Guolang Zhou, Xiaowei Li, Linlin Chen, Guiling Luo, Jun Gu, Jie Zhu, Jiangtao Yu, Jingzhou Yin, Yanhong Chao, Wenshuai Zhu. Construction of porous disc-like lithium manganate for rapid and selective electrochemical lithium extraction from brine[J]. 中国化学工程学报, 2023, 54(2): 316-322.
[8]	Monique Juna L. Leite, Ingrid Ramalho Marques, Mariane Carolina Proner, Pedro H.H. Araújo, Alan Ambrosi, Marco Di Luccio. Catalytically active membranes for esterification: A review[J]. 中国化学工程学报, 2023, 53(1): 142-154.
[9]	Yuanyuan Jin, Siping Ding, Peiyun Li, Xuefen Wang. Coordination of thin-film nanofibrous composite dialysis membrane and reduced graphene oxide aerogel adsorbents for elimination of indoxyl sulfate[J]. 中国化学工程学报, 2022, 49(9): 111-121.
[10]	Fengfeng Gao, Jinhua Luo, Xuefeng Zhang, Xiaogang Hao, Guoqing Guan, Zhong Liu, Jun Li, Qinglong Luo. Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions[J]. 中国化学工程学报, 2022, 49(9): 161-169.
[11]	Zhong Ma, Guofu Liu, Hui Zhang, Yonggang Lu. Investigation of the redox performance of pyrite cinder calcined at different temperature in chemical looping combustion[J]. 中国化学工程学报, 2022, 48(8): 98-105.
[12]	Wenjian Zhu, Xuhua Shen, Rui Ou, Manoj Murugesan, Aihua Yuan, Jianfeng Liu, Xiaocai Hu, Zhen Yang, Ming Shen, Fu Yang. Superhigh selective capture of volatile organic compounds exploiting cigarette butts-derived engineering carbonaceous adsorbent[J]. 中国化学工程学报, 2022, 46(6): 194-206.
[13]	Jipeng Dong, Fei Wang, Guanghui Chen, Shougui Wang, Cailin Ji, Fei Gao. Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture[J]. 中国化学工程学报, 2022, 46(6): 207-213.
[14]	Ding-Ming Xue, Wen-Juan Zhang, Xiao-Qin Liu, Shi-Chao Qi, Lin-Bing Sun. Fabrication of azobenzene-functionalized porous polymers for selective CO₂ capture[J]. 中国化学工程学报, 2022, 43(3): 24-30.
[15]	Xiaobin Chen, Yuting Tang, Chuncheng Ke, Chaoyue Zhang, Sichun Ding, Xiaoqian Ma. CO₂ capture by double metal modified CaO-based sorbents from pyrolysis gases[J]. 中国化学工程学报, 2022, 43(3): 40-49.