Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

doi:10.1016/j.cjche.2024.03.015

中国化学工程学报 ›› 2024, Vol. 70 ›› Issue (6): 269-279.DOI: 10.1016/j.cjche.2024.03.015

Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

Shuyi Shen¹, Song Guo¹, Sining Chen², Jinhua Zhao¹

1. Nanjing University of Science & Technology, Nanjing 210094, China;
2. China Academy of Safety Science and Technology, Beijing 100012, China

收稿日期:2023-11-24 修回日期:2024-03-08 出版日期:2024-06-28 发布日期:2024-08-05
通讯作者: Song Guo,Tel.:+8613951836507.E-mail:guosong@njust.edu.cn;Sining Chen,E-mail:chensn@chinasafety.ac.cn
基金资助:
This work was supported by National Natural Science Foundation of China (51974166).

Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

Shuyi Shen¹, Song Guo¹, Sining Chen², Jinhua Zhao¹

1. Nanjing University of Science & Technology, Nanjing 210094, China;
2. China Academy of Safety Science and Technology, Beijing 100012, China

Received:2023-11-24 Revised:2024-03-08 Online:2024-06-28 Published:2024-08-05
Contact: Song Guo,Tel.:+8613951836507.E-mail:guosong@njust.edu.cn;Sining Chen,E-mail:chensn@chinasafety.ac.cn
Supported by:
This work was supported by National Natural Science Foundation of China (51974166).

摘要/Abstract

摘要： Recently, azobenzene-4,4'-dicarboxylic acid (ADCA) has been produced gradually for use as an organic synthesis or pharmaceutical intermediate due to its eminent performance. With large quantities put into application in the future, the thermal stability of this substance during storage, transportation, and use will become quite important. Thus, in this work, the thermal decomposition behavior, thermal decomposition kinetics, and thermal hazard of ADCA were investigated. Experiments were conducted by using a SENSYS evo DSC device. A combination of differential iso-conversion method, compensation parameter method, and nonlinear fitting evaluation were also used to analyze thermal kinetics and mechanism of ADCA decomposition. The results show that when conversion rate α increases, the activation energies of ADCA's first and main decomposition peaks fall. The amount of heat released during decomposition varies between 182.46 and 231.16 J·g^-1. The proposed kinetic equation is based on the Avrami-Erofeev model, which is consistent with the decomposition progress. Applying the Frank-Kamenetskii model, a calculated self-accelerating decomposition temperature of 287.0 ℃ is obtained.

关键词: Azobenzene-4,4′-dicarboxylic acid, Thermal decomposition behavior, Kinetic mechanism, Thermal hazard evaluation, Compensation parameter effect

Abstract: Recently, azobenzene-4,4'-dicarboxylic acid (ADCA) has been produced gradually for use as an organic synthesis or pharmaceutical intermediate due to its eminent performance. With large quantities put into application in the future, the thermal stability of this substance during storage, transportation, and use will become quite important. Thus, in this work, the thermal decomposition behavior, thermal decomposition kinetics, and thermal hazard of ADCA were investigated. Experiments were conducted by using a SENSYS evo DSC device. A combination of differential iso-conversion method, compensation parameter method, and nonlinear fitting evaluation were also used to analyze thermal kinetics and mechanism of ADCA decomposition. The results show that when conversion rate α increases, the activation energies of ADCA's first and main decomposition peaks fall. The amount of heat released during decomposition varies between 182.46 and 231.16 J·g^-1. The proposed kinetic equation is based on the Avrami-Erofeev model, which is consistent with the decomposition progress. Applying the Frank-Kamenetskii model, a calculated self-accelerating decomposition temperature of 287.0 ℃ is obtained.

Key words: Azobenzene-4,4′-dicarboxylic acid, Thermal decomposition behavior, Kinetic mechanism, Thermal hazard evaluation, Compensation parameter effect

Shuyi Shen, Song Guo, Sining Chen, Jinhua Zhao. Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation[J]. 中国化学工程学报, 2024, 70(6): 269-279.

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Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

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