An integrated technology for the absorption and utilization of CO2 in alkanolamine solution for the preparation of BaCO3 in a high-gravity environment

doi:10.1016/j.cjche.2024.04.012

中国化学工程学报 ›› 2024, Vol. 72 ›› Issue (8): 117-125.DOI: 10.1016/j.cjche.2024.04.012

An integrated technology for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment

Kangrui Nie, Ruize Shang, Fuming Miao, Liuxiang Wang, Youzhi Liu, Weizhou Jiao

Shanxi Province Key Laboratory of Chemical Process Intensification and School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China

收稿日期:2023-11-30 修回日期:2024-02-28 出版日期:2024-08-28 发布日期:2024-10-17
通讯作者: Weizhou Jiao,E-mail:zbdxjwz@nuc.edu.cn
基金资助:
This research was supported by Research Project Supported by Horizon Europe Framework Programme (101183092), Shanxi Scholarship Council of China (2023-128), National Natural Science Foundation of China (22208328) and Fundamental Research Program of Shanxi Province (20210302124618), Small and medium-sized oriented scientific and technological enterprises innovation ability improvement project of Shandong Province (2023TSGC0004).

An integrated technology for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment

Kangrui Nie, Ruize Shang, Fuming Miao, Liuxiang Wang, Youzhi Liu, Weizhou Jiao

Shanxi Province Key Laboratory of Chemical Process Intensification and School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China

Received:2023-11-30 Revised:2024-02-28 Online:2024-08-28 Published:2024-10-17
Contact: Weizhou Jiao,E-mail:zbdxjwz@nuc.edu.cn
Supported by:
This research was supported by Research Project Supported by Horizon Europe Framework Programme (101183092), Shanxi Scholarship Council of China (2023-128), National Natural Science Foundation of China (22208328) and Fundamental Research Program of Shanxi Province (20210302124618), Small and medium-sized oriented scientific and technological enterprises innovation ability improvement project of Shandong Province (2023TSGC0004).

摘要/Abstract

摘要： In this study, an integrated technology is proposed for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment. The effects of absorbent type, high-gravity factor, gas/liquid ratio, and initial BaCl₂ concentration on the absorption rate and amount of CO₂ and the preparation of BaCO₃ are investigated. The results reveal that the absorption rate and amount of CO₂ follow the order of ethyl alkanolamine (MEA) > diethanol amine (DEA) > N-methyldiethanolamine (MDEA), and thus MEA is the most effective absorbent for CO₂ absorption. The absorption rate and amount of CO₂ under high gravity are higher than that under normal gravity. Notably, the absorption rate at 75 min under high gravity is approximately 2 times that under normal gravity. This is because the centrifugal force resulting from the high-speed rotation of the packing can greatly increase gas-liquid mass transfer and micromixing. The particle size of BaCO₃ prepared in the rotating packed bed is in the range of 57.2-89 nm, which is much smaller than that prepared in the bubbling reactor (>100.3 nm), and it also has higher purity (99.6%) and larger specific surface area (14.119 m²·g^-1). It is concluded that the high-gravity technology has the potential to increase the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃. This study provides new insights into carbon emissions reduction and carbon utilization.

关键词: High-gravity technology, Wet absorption, CO₂ capture, Enhanced mass transfer, CO₂ utilization, Barium carbonate

Abstract: In this study, an integrated technology is proposed for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment. The effects of absorbent type, high-gravity factor, gas/liquid ratio, and initial BaCl₂ concentration on the absorption rate and amount of CO₂ and the preparation of BaCO₃ are investigated. The results reveal that the absorption rate and amount of CO₂ follow the order of ethyl alkanolamine (MEA) > diethanol amine (DEA) > N-methyldiethanolamine (MDEA), and thus MEA is the most effective absorbent for CO₂ absorption. The absorption rate and amount of CO₂ under high gravity are higher than that under normal gravity. Notably, the absorption rate at 75 min under high gravity is approximately 2 times that under normal gravity. This is because the centrifugal force resulting from the high-speed rotation of the packing can greatly increase gas-liquid mass transfer and micromixing. The particle size of BaCO₃ prepared in the rotating packed bed is in the range of 57.2-89 nm, which is much smaller than that prepared in the bubbling reactor (>100.3 nm), and it also has higher purity (99.6%) and larger specific surface area (14.119 m²·g^-1). It is concluded that the high-gravity technology has the potential to increase the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃. This study provides new insights into carbon emissions reduction and carbon utilization.

Key words: High-gravity technology, Wet absorption, CO₂ capture, Enhanced mass transfer, CO₂ utilization, Barium carbonate

Kangrui Nie, Ruize Shang, Fuming Miao, Liuxiang Wang, Youzhi Liu, Weizhou Jiao. An integrated technology for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment[J]. 中国化学工程学报, 2024, 72(8): 117-125.

参考文献

[1] Y. Yoo, I. Kim, D. Lee, W. Yong Choi, J. Choi, K. Jang, J. Park, D. Kang, Review of contemporary research on inorganic CO₂ utilization via CO₂ conversion into metal carbonate-based materials, J. Ind. Eng. Chem. 116 (2022) 60-74.
[2] J.F.D. Tapia, J.Y. Lee, R.E.H. Ooi, D.C.Y. Foo, R.R. Tan, A review of optimization and decision-making models for the planning of CO₂ capture, utilization and storage (CCUS) systems, Sustain. Prod. Consum. 13 (2018) 1-15.
[3] E. Oko, C. Ramshaw, M.H. Wang, Study of intercooling for rotating packed bed absorbers in intensified solvent-based CO₂ capture process, Appl. Energy 223 (2018) 302-316.
[4] H. Cheng, Y. Fan, D. Tarlet, L. Luo, Z. Fan, Microfluidic-based chemical absorption technology for CO₂ capture: Mass transfer dynamics, operating factors and performance intensification, Renewable and Sustainable Energy Reviews. 181 (2023) 113357.
[5] Q. Ye, Y. Shen, Q. Zhang, X. Wu, W.B. Guo, Life-cycle assessment of flue gas CO₂ fixation from coal-fired power plant and coal chemical plant by microalgae, Sci. Total Environ. 848 (2022) 157728.
[6] J.M. Zeng, L.D. Liu, X. Liang, S.H. Chen, J. Yuan, Evaluating fuel consumption factor for energy conservation and carbon neutral on an industrial thermal power unit, Energy 232 (2021) 120887.
[7] H.R. Zhou, W.L. Meng, D.L. Wang, G.X. Li, H.W. Li, Z.Q. Liu, S. Yang, A novel coal chemical looping gasification scheme for synthetic natural gas with low energy consumption for CO₂ capture: modelling, parameters optimization, and performance analysis, Energy 225 (2021) 120249.
[8] F. Liu, M.X. Fang, W.F. Dong, T. Wang, Z.X. Xia, Q.H. Wang, Z.Y. Luo, Carbon dioxide absorption in aqueous alkanolamine blends for biphasic solvents screening and evaluation, Appl. Energy 233-234 (2019) 468-477.
[9] W.F. Zhang, Y.L. Xu, Q.H. Wang, Coupled CO₂ absorption and mineralization with low-concentration monoethanolamine, Energy 241 (2022) 122524.
[10] S. Park, J.H. Bang, K. Song, C.W. Jeon, J. Park, Barium carbonate precipitation as a method to fix and utilize carbon dioxide, Chem. Eng. J. 284 (2016) 1251-1258.
[11] J.W. Lu, Z.H. Wang, S. Su, H. Liu, Z.W. Ma, Q.Q. Ren, K. Xu, Y. Wang, S. Hu, J. Xiang, Single-step integrated CO₂ absorption and mineralization using fly ash coupled mixed amine solution: Mineralization performance and reaction kinetics, Energy 286 (2024) 129615.
[12] Z. Yan, Y. Wang, H.R. Yue, C.J. Liu, S. Zhong, K. Ma, W.J. Liao, S.Y. Tang, B. Liang, Integrated process of monoethanolamine-based CO₂ absorption and CO₂ mineralization with SFGD slag: Process simulation and life-cycle assessment of CO₂ emission, ACS Sustainable Chem. Eng. 9 (24) (2021) 8238-8248.
[13] M. Arti, M.H. Youn, K.T. Park, H.J. Kim, Y.E. Kim, S.K. Jeong, Single process for CO₂ capture and mineralization in various alkanolamines using calcium chloride, Energy Fuels 31 (1) (2017) 763-769.
[14] A.V. Mader, L. Helmbrecht, W.L. Noorduin, Multi-layered Barium and Strontium Carbonate Structures Induced by the Small Organic Dye Acid Orange 7, Crystal Growth & Design. 21 (2021) 6349-6356.
[15] A. Gaur, J. Park, J. Jang, H. Song, Precipitation of barium carbonate from alkanolamine solution-Study of CO₂ absorption from landfill gas (LFG), J of Chemical Tech & Biotech. 86 (2011) 153-156.
[16] H. Jo, M.G. Lee, J. Park, K.D. Jung, Preparation of high-purity nano-CaCO₃ from steel slag, Energy 120 (2017) 884-894.
[17] B.T. Zhao, W.W. Tao, M. Zhong, Y.X. Su, G.M. Cui, Process, performance and modeling of CO₂ capture by chemical absorption using high gravity: A review, Renew. Sustain. Energy Rev. 65 (2016) 44-56.
[18] A. Zahir, P. Kumar, A. Saptoro, M. Shah, A.N.T. Tiong, S. Hameed, Parametric study of experimental and CFD simulation based hydrodynamics and mass transfer of rotating packed bed: A review, Arch. Comput. Meth. Eng. 30 (6) (2023) 4001-4031.
[19] A. Zahir, P. Kumar, A. Saptoro, M. Shah, A.N.T. Tiong, J.C. Kurnia, S. Hameed, Prediction and optimization of liquid dispersion of monoethanolamine in a rotating packed bed for CO₂ absorption, Chem. Eng. Res. Des. 199 (2023) 252-267.
[20] Z. Qian, L.B. Xu, H.B. Cao, K. Guo, Modeling study on absorption of CO₂ by aqueous solutions of N-methyldiethanolamine in rotating packed bed, Ind. Eng. Chem. Res. 48 (20) (2009) 9261-9267.
[21] C.Y. Tai, C.T. Tai, H.S. Liu, Synthesis of submicron Barium carbonate using a high-gravity technique, Chem. Eng. Sci. 61 (22) (2006) 7479-7486.
[22] A. Schaffer, K. Brechtel, G. Scheffknecht, Comparative study on differently concentrated aqueous solutions of MEA and TETA for CO₂ capture from flue gases, Fuel 101 (2012) 148-153.
[23] L.J. Feng, R.R. Zhai, Y.X. Zhao, Z.H. Qian, Q. Wei, Integrated optimization of coal-fired power plant and CO₂ capture system coupled with membrane condenser for recovering flue gas hydrothermal energy, Energy Convers. Manag. 278 (2023) 116689.
[24] F.O. Ochedi, J.L. Yu, H. Yu, Y.X. Liu, A. Hussain, Carbon dioxide capture using liquid absorption methods: A review, Environ. Chem. Lett. 19 (1) (2021) 77-109. [LinkOut].
[25] P.V. Danckwerts, The reaction of CO₂ with ethanolamines, Chem. Eng. Sci. 34 (4) (1979) 443-446.
[26] T.L. Donaldson, Y.N. Nguyen, Carbon dioxide reaction kinetics and transport in aqueous amine membranes, Ind. Eng. Chem. Fund. 19 (3) (1980) 260-266.
[27] Y.J. Qin, S. Luo, S. Geng, W.Z. Jiao, Y.Z. Liu, Degradation and mineralization of aniline by O₃/Fenton process enhanced using high-gravity technology, Chin. J. Chem. Eng. 26 (7) (2018) 1444-1450.
[28] B.C. Sun, X.M. Wang, J.M. Chen, G.W. Chu, J.F. Chen, L. Shao, Synthesis of nano-CaCO₃ by simultaneous absorption of CO₂ and NH₃ into CaCl₂ solution in a rotating packed bed, Chem. Eng. J. 168 (2) (2011) 731-736.
[29] F.M. Miao, S. Zhang, X.L. Sun, Y.M. Li, R.Z. Shang, W.L. Wu, W.Z. Jiao, Y.Z. Liu, Degradation of phenol with Mn-CoO_X/γ-Al₂O₃ catalytic ozonation enhanced by high gravity technology, Chem. Eng. Sci. 280 (2023) 119036.
[30] Z. Li, J. Jing, K. Gao, G. Ren, J. Zhang, W. Jiao, Y. Liu, Degradation of nitrobenzene by high-gravity intensified heterogeneous catalytic ozonation with Mn-Fe/ZSM-5 catalysts, Chem. Eng. Proces. 169 (2021) 108642.
[31] W.Z. Jiao, Y.J. Qin, S. Luo, Z. He, Z.R. Feng, Y.Z. Liu, Simultaneous formation of nanoscale zero-valent iron and degradation of nitrobenzene in wastewater in an impinging stream-rotating packed bed reactor, Chem. Eng. J. 321 (2017) 564-571.

An integrated technology for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment

An integrated technology for the absorption and utilization of CO₂ in alkanolamine solution for the preparation of BaCO₃ in a high-gravity environment

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