SCI和EI收录∣中国化工学会会刊

›› 2008, Vol. 16 ›› Issue (2): 247-255.

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Density and Excess Molar Volume of Binary Mixtures of p-Xylene+Acetic Acid and o-Xylene+Acetic Acid at Different Temperatures and Pressures

杨天宇, 夏淑倩, 邸志国, 马沛生   

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 收稿日期:2007-04-23 修回日期:2007-08-30 出版日期:2008-04-28 发布日期:2008-04-28
  • 通讯作者: MA Peisheng,E-mail:mapeisheng@tju.edu.cn
  • 基金资助:
    Supported by China Petrochemical Corporation(X505012)

Density and Excess Molar Volume of Binary Mixtures of p-Xylene+Acetic Acid and o-Xylene+Acetic Acid at Different Temperatures and Pressures

YANG Tianyu, XIA Shuqian, DI Zhiguo, MA Peisheng   

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2007-04-23 Revised:2007-08-30 Online:2008-04-28 Published:2008-04-28
  • Supported by:
    Supported by China Petrochemical Corporation(X505012)

摘要: A new apparatus was designed with a thick-walled glass capillary,electric heater tube with red copper and heat preservation.The thick-walled glass capillary was used for its advantages of resistance to acid corrosion and pressure,and ease of observation.The experimental densities over the entire range of mole fraction for the binary mixture of p-xylene+acetic acid and o-xylene+acetic acid were measured using the new apparatus at temperatures ranging from 313.15K to 473.15K and pressure ranging from 0.20 to 2.0 MPa.The density values were used in the determination of excess molar volumes,VE.The Redlich-Kister equation was used to fit the excess molar volume values,and the coefficients and estimate of the standard error values were presented.The experimental results prove that the density measurement apparatus is successful.

关键词: density, excess molar volume, p-xylene, o-xylene, acetic acid

Abstract: A new apparatus was designed with a thick-walled glass capillary,electric heater tube with red copper and heat preservation.The thick-walled glass capillary was used for its advantages of resistance to acid corrosion and pressure,and ease of observation.The experimental densities over the entire range of mole fraction for the binary mixture of p-xylene+acetic acid and o-xylene+acetic acid were measured using the new apparatus at temperatures ranging from 313.15K to 473.15K and pressure ranging from 0.20 to 2.0 MPa.The density values were used in the determination of excess molar volumes,VE.The Redlich-Kister equation was used to fit the excess molar volume values,and the coefficients and estimate of the standard error values were presented.The experimental results prove that the density measurement apparatus is successful.

Key words: density, excess molar volume, p-xylene, o-xylene, acetic acid