Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent

doi:10.1016/S1004-9541(13)60512-1

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (5): 558-563.DOI: 10.1016/S1004-9541(13)60512-1

• 能源、资源与环境技术 • 上一篇下一篇

Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent

杨磊¹, 王胜强¹, 王瑞聪², 于宏兵¹

1 College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China;
2 Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China

收稿日期:2011-12-26 修回日期:2012-05-02 出版日期:2013-05-28 发布日期:2013-05-31
通讯作者: WANG Shengqiang
基金资助:
Supported by the National Natural Science Foundation of China (21006053), the Fundamental Research Funds for the Central Universities (65010551) and the Research Funds of Humanistic Social Science for Cyclic Economy and Low-Carbon Developments (951004).

Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent

YANG Lei¹, WANG Shengqiang¹, WANG Ruicong², YU Hongbing¹

1 College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China;
2 Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China

Received:2011-12-26 Revised:2012-05-02 Online:2013-05-28 Published:2013-05-31
Supported by:
Supported by the National Natural Science Foundation of China (21006053), the Fundamental Research Funds for the Central Universities (65010551) and the Research Funds of Humanistic Social Science for Cyclic Economy and Low-Carbon Developments (951004).

摘要/Abstract

摘要： This paper presents a new selective adsorbent to remove nitrogen-containing heterocyclic compounds from model and commercial transportation diesel fuels based on characteristic reaction designed to occur in the pores of substrate. This reactive adsorbent is composed of formaldehyde, phosphotungstic acid and Santa Barbara USA (SBA)-15. The experiment was based on assumed hydroxymethylation reaction of nitrogen-containing heterocyclic compounds with formaldehyde using phosphotungstic acid as catalyst in batch and fixed-bed systems. The nitrogen concentration in the model fuel was 237.33 ng·μl^-1, carbazole and toluene were used as model nitrogen-containing heterocyclic compound and solvent, respectively. The effectiveness of reactive adsorbent for removal of nitrogen-containing heterocyclic compounds from commercial 0^# diesel fuel containing 224.86 ng·μl^-1 nitrogen was examined in a fixed-bed reactor at 70 ℃. The results showed that nitrogen in the model fuel was very low and the nitrogen concentration in the commercial diesel reduced to 2.44 ng·μl^-1. The demand for transportation fuel with ultra-low nitrogen is satisfied.

关键词: denitrogenation, fuel, carbazole, adsorption, SBA-15

Abstract: This paper presents a new selective adsorbent to remove nitrogen-containing heterocyclic compounds from model and commercial transportation diesel fuels based on characteristic reaction designed to occur in the pores of substrate. This reactive adsorbent is composed of formaldehyde, phosphotungstic acid and Santa Barbara USA (SBA)-15. The experiment was based on assumed hydroxymethylation reaction of nitrogen-containing heterocyclic compounds with formaldehyde using phosphotungstic acid as catalyst in batch and fixed-bed systems. The nitrogen concentration in the model fuel was 237.33 ng·μl^-1, carbazole and toluene were used as model nitrogen-containing heterocyclic compound and solvent, respectively. The effectiveness of reactive adsorbent for removal of nitrogen-containing heterocyclic compounds from commercial 0^# diesel fuel containing 224.86 ng·μl^-1 nitrogen was examined in a fixed-bed reactor at 70 ℃. The results showed that nitrogen in the model fuel was very low and the nitrogen concentration in the commercial diesel reduced to 2.44 ng·μl^-1. The demand for transportation fuel with ultra-low nitrogen is satisfied.

Key words: denitrogenation, fuel, carbazole, adsorption, SBA-15

杨磊, 王胜强, 王瑞聪, 于宏兵. Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent[J]. Chinese Journal of Chemical Engineering, 2013, 21(5): 558-563.

YANG Lei, WANG Shengqiang, WANG Ruicong, YU Hongbing. Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent[J]. Chin.J.Chem.Eng., 2013, 21(5): 558-563.

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Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent

Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent

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