Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling

doi:10.1016/j.cjche.2022.11.014

中国化学工程学报 ›› 2023, Vol. 59 ›› Issue (7): 105-117.DOI: 10.1016/j.cjche.2022.11.014

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Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling

Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang

Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, China

收稿日期:2022-08-26 修回日期:2022-11-14 出版日期:2023-07-28 发布日期:2023-10-14
通讯作者: Yunfei Gao,E-mail:yunfeigao@ecust.edu.cn;Fuchen Wang,E-mail:wfch@ecust.edu.cn
基金资助:
The project was supported by the National Natural Science Foundation of China (21978092), Chenguang Program by Educational Administration of Shanghai (21CGA35), and Yangfan Program by Scientifical Administration of Shanghai (22YF1410300).

Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling

Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang

Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, China

Received:2022-08-26 Revised:2022-11-14 Online:2023-07-28 Published:2023-10-14
Contact: Yunfei Gao,E-mail:yunfeigao@ecust.edu.cn;Fuchen Wang,E-mail:wfch@ecust.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (21978092), Chenguang Program by Educational Administration of Shanghai (21CGA35), and Yangfan Program by Scientifical Administration of Shanghai (22YF1410300).

摘要/Abstract

摘要： CO₂ is an important component in the acid gas and it is necessary to study the effect of CO₂ presence on the oxy-fuel combustion of H₂S with particular focus on the formation of carbonyl sulfide (COS). The oxy-fuel combustion of acid gas was conducted in a coaxial jet double channel burner. The distribution of flame temperature and products under stoichiometric condition along axial (R = 0.0) and radial at about 3.0 mm (R = 0.75) were analyzed, respectively. The Chemkin-Pro software was used to analyze the rate of production (ROP) for gas products and the reaction pathway of acid gas combustion. Both experimental and simulation results showed that acid gas combustion experienced the H₂S chemical decomposition, H₂S oxidation and accompanied by H₂ oxidation. The CO₂ presence reduced the peak flame temperature and triggered the formation of COS in the flame area. COS formation at R = 0.0 was mainly through the reaction of CO₂ and CO with sulfur species, whereas at R = 0.75 it was through the reaction of CO with sulfur species. The ROP results indicated that H₂ was mainly from H₂O decomposition in the H₂S oxidation stage, and COS was formed by the reaction of CO₂ with H₂S. ROP and other detailed analysis further revealed the role of H, OH and SH radicals in each stage of H₂S conversion. This study revealed the COS formation mechanisms with CO₂ presence in the oxy-fuel combustion of H₂S and could offer important insights for pollutant control.

关键词: Carbon dioxide, Oxy-fuel combustion of H₂S, Reaction pathway, Kinetics, Oxidation

Abstract: CO₂ is an important component in the acid gas and it is necessary to study the effect of CO₂ presence on the oxy-fuel combustion of H₂S with particular focus on the formation of carbonyl sulfide (COS). The oxy-fuel combustion of acid gas was conducted in a coaxial jet double channel burner. The distribution of flame temperature and products under stoichiometric condition along axial (R = 0.0) and radial at about 3.0 mm (R = 0.75) were analyzed, respectively. The Chemkin-Pro software was used to analyze the rate of production (ROP) for gas products and the reaction pathway of acid gas combustion. Both experimental and simulation results showed that acid gas combustion experienced the H₂S chemical decomposition, H₂S oxidation and accompanied by H₂ oxidation. The CO₂ presence reduced the peak flame temperature and triggered the formation of COS in the flame area. COS formation at R = 0.0 was mainly through the reaction of CO₂ and CO with sulfur species, whereas at R = 0.75 it was through the reaction of CO with sulfur species. The ROP results indicated that H₂ was mainly from H₂O decomposition in the H₂S oxidation stage, and COS was formed by the reaction of CO₂ with H₂S. ROP and other detailed analysis further revealed the role of H, OH and SH radicals in each stage of H₂S conversion. This study revealed the COS formation mechanisms with CO₂ presence in the oxy-fuel combustion of H₂S and could offer important insights for pollutant control.

Key words: Carbon dioxide, Oxy-fuel combustion of H₂S, Reaction pathway, Kinetics, Oxidation

Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling[J]. 中国化学工程学报, 2023, 59(7): 105-117.

参考文献

[1] A. Raj, Combustion kinetics of H₂S and other sulfurous species with relevance to industrial processes, Prog. Energy Combust. Sci. 80 (2020) 100848.Doi: 10.1016/j.pecs.2020.100848
[2] D. Barba, F. Cammarota, V. Vaiano, E. Salzano, V. Palma, Experimental and numerical analysis of the oxidative decomposition of H₂S, Fuel 198 (2017) 68-75.Doi: 10.1016/j.fuel.2016.12.038
[3] Y. Wang, Z.L. Wang, J.F. Pan, Y.X. Liu, Removal of gaseous hydrogen sulfide using Fenton reagent in a spraying reactor, Fuel 239 (2019) 70-75.Doi: 10.1016/j.fuel.2018.10.143
[4] M. Sassi, N. Amira, Chemical reactor network modeling of a microwave plasma thermal decomposition of H₂S into hydrogen and sulfur, Int. J. Hydrog. Energy 37 (13) (2012) 10010-10019.Doi: 10.1016/j.ijhydene.2012.04.006
[5] S. An, J.C. Jung, Kinetic modeling of thermal reactor in Claus process using CHEMKIN-PRO software, Case Stud. Therm. Eng. 21 (2020) 100694.Doi: 10.1016/j.csite.2020.100694
[6] R. El-Bishtawi, N. Haimour, Claus recycle with double combustion process, Fuel Process. Technol. 86 (3) (2004) 245-260.Doi: 10.1016/j.fuproc.2004.04.001
[7] B. Mahmoodi, S.H. Hosseini, A. Raj, Hooman, K., A new acid gas destruction kinetic model for reaction furnace of an industrial sulfur recovery unit: A CFD study, Chem. Eng. Sci. 256 (2022) 117692.Doi: 10.1016/j.ces.2022.117692
[8] S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Effect of benzene on product evolution in a H₂S/O₂ flame under Claus condition, Appl. Energy 145 (2015) 21-26.Doi: 10.1016/j.apenergy.2015.01.094
[9] S. Ibrahim, R. K. Rahman, A. Raj, A split-flow sulfur recovery process for the destruction of aromatic hydrocarbon contaminants in acid gas, J. Nat. Gas Sci. Eng. 97 (2022) 104378.Doi: 10.1016/j.jngse.2021.104378
[10] N.J. Nabikandi, S.Fatemi, Kinetic modelling of a commercial sulfur recovery unit based on Claus straight through process: Comparison with equilibrium model, J. Ind. Eng. Chem. 30 (2015) 50-63.Doi: 10.1016/j.jiec.2015.05.001
[11] A. Mehmood, An evaluation of kinetic models for the simulation of Claus reaction furnaces in sulfur recovery units under different feed conditions, J. Nat. Gas Sci. Eng. 74 (2020) 103106.Doi: 10.1016/j.jngse.2019.103106
[12] A.Y. Ibrahim,,, Energy and exergy studies of a Sulphur recovery unit in normal and optimized cases: A real starting up plant, Energy Convers. Manag. X 15 (2022) 100241.Doi: 10.1016/j.ecmx.2022.100241
[13] H.R. Mahdipoor, Feasibility study of a sulfur recovery unit containing mercaptans in lean acid gas feed, J. Nat. Gas Sci. Eng. 31 (2016) 585-588.Doi: 10.1016/j.jngse.2016.03.045
[14] N. Abumounshar,,, Novel processes for lean acid gas utilization for sulfur production with high efficiency, Chem. Eng. Sci. 248 (2022) 117194.Doi: 10.1016/j.ces.2021.117194
[15] Y. Li, Equilibrium prediction of acid gas partial oxidation with presence of CH₄ and CO₂ for hydrogen production, Appl. Therm. Eng. 107 (2016) 125-134.Doi: 10.1016/j.applthermaleng.2016.05.076
[16] S. Ibrahim, A. Raj, Kinetic simulation of acid gas (H₂S and CO₂) destruction for simultaneous syngas and sulfur recovery, Ind. Eng. Chem. Res. 55 (24) (2016) 6743-6752.Doi: 10.1021/acs.iecr.6b01176
[17] J.S. Eow, Recovery of sulfur from sour acid gas: A review of the technology, Environ. Prog. 21 (3) (2002) 143-162.Doi: 10.1002/ep.670210312
[18] I. Saanum, M. Ditaranto, Experimental study of oxy-fuel combustion under gas turbine conditions, Energy Fuels 31 (4) (2017) 4445-4451.Doi: 10.1021/acs.energyfuels.6b03114
[19] Q.W. Liu, W.Q. Zhong, R. Tang, H.Q. Yu, J.R. Gu, G.W. Zhou, A.B. Yu, Experimental tests on co-firing coal and biomass waste fuels in a fluidised bed under oxy-fuel combustion, Fuel 286 (2021) 119312.Doi: 10.1016/j.fuel.2020.119312
[20] F.M. Wang, B.X. Shen, J.C. Yang, S. Singh, Review of mercury formation and capture from CO₂-enriched oxy-fuel combustion flue gas, Energy Fuels 31 (2) (2017) 1053-1064.Doi: 10.1021/acs.energyfuels.6b02420
[21] D.K. Hong, X. Guo, C.B. Wang, A reactive molecular dynamics study of HCN oxidation during pressurized oxy-fuel combustion, Fuel Process. Technol. 224 (2021) 107020.Doi: 10.1016/j.fuproc.2021.107020
[22] H. Selim, A.K. Gupta, A. Al Shoaibi, Effect of CO₂ and N₂ concentration in acid gas stream on H₂S combustion, Appl. Energy 98 (2012) 53-58.Doi: 10.1016/j.apenergy.2012.02.072
[23] S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Role of toluene to acid gas (H₂S and CO₂) combustion in H₂/O₂-N₂ flame under Claus condition, Appl. Energy 149 (2015) 62-68.Doi: 10.1016/j.apenergy.2015.03.117
[24] H. Selim, S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Investigation of sulfur chemistry with acid gas addition in hydrogen/air flames, Appl. Energy 113 (2014) 1134-1140.Doi: 10.1016/j.apenergy.2013.08.054
[25] Y. Li, Q.H. Guo, X.L. Yu, Z.H. Dai, Y.F. Wang, G.S. Yu, F.C. Wang, Effect of O₂ enrichment on acid gas oxidation and formation of COS and CS₂ in a rich diffusion flame, Appl. Energy 206 (2017) 947-958.Doi: 10.1016/j.apenergy.2017.07.113
[26] K. Karan, A.K. Mehrotra, L.A. Behie, A high-temperature experimental and modeling study of homogeneous gas-phase COS reactions applied to Claus plants, Chem. Eng. Sci. 54 (15-16) (1999) 2999-3006.Doi: 10.1016/S0009-2509(98)00475-8
[27] P.D. Clark, N.I. Dowling, M. Huang, W.Y. Svrcek, W.D. Monnery, Mechanisms of CO and COS formation in the Claus furnace, Ind. Eng. Chem. Res. 40 (2) (2001) 497-508.Doi: 10.1021/ie990871l
[28] Y. Li, X.L. Yu, H.J. Li, Q.H. Guo, Z.H. Dai, G.S. Yu, F.C. Wang, Detailed kinetic modelling of H₂S oxidation with presence of CO₂ under rich condition, Appl. Energy 190 (2017) 824-834.Doi: 10.1016/j.apenergy.2016.12.150
[29] H. Selim, S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Effect of oxygen enrichment on acid gas combustion in hydrogen/air flames under Claus conditions, Appl. Energy 109 (2013) 119-124.Doi: 10.1016/j.apenergy.2013.03.026
[30] Y. Li, Q.H. Guo, Z.H. Dai, Y.C. Dong, G.S. Yu, F.C. Wang, Study of oxidation for gas mixture of H₂S and CH₄ in a non-premixed flame under oxygen deficient condition, Appl. Therm. Eng. 117 (2017) 659-667.Doi: 10.1016/j.applthermaleng.2016.10.168
[31] S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Xylene addition effects to H₂S combustion under Claus condition, Fuel 150 (2015) 1-7.Doi: 10.1016/j.fuel.2015.02.001
[32] S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Role of toluene in hydrogen sulfide combustion under Claus condition, Appl. Energy 112 (2013) 60-66.Doi: 10.1016/j.apenergy.2013.05.065
[33] H. Selim, A. Al Shoaibi, A.K. Gupta, Effect of H₂S in methane/air flames on sulfur chemistry and products speciation, Appl. Energy 88 (8) (2011) 2593-2600.Doi: 10.1016/j.apenergy.2011.02.032
[34] B.A. Rabee, The effect of inverse diffusion flame burner-diameter on flame characteristics and emissions, Energy 160 (2018) 1201-1207.Doi: 10.1016/j.energy.2018.07.061
[35] Y.A. Cengel, Heat Transfer: A Practical Approach, 2nd ed, Mc-Graw Hill, 2003.
[36] W. Don, R.H. Green, Perry’s chemical engineers, Eighth Edition, McGraw-Hill, 2008
[37] S. Whitaker, Forced convection heat transfer correlations for flow in pipes, past flat plates, single cylinders, single spheres, and for flow in packed beds and tube bundles, AIChE J. 18 (2) (1972) 361-371.Doi: 10.1002/aic.690180219
[38] H. Xiao,,, Study on counterflow premixed flames using high concentration ammonia mixed with methane, Fuel 275 (2020) 117902.Doi: 10.1016/j.fuel.2020.117902
[39] H.W. Zhu, S Lai, A Valera-Medina, J Li, H Fu, Effects of CO and H₂ addition on OH* chemiluminescence characteristics in laminar rich inverse diffusion flames, Fuel 254 (2019) 115554.
[40] S.R. Lee, S.H. Chung, On the structure of hydrogen diffusion flames with reduced kinetic mechanisms, Combust. Sci. Technol. 96 (4-6) (1994) 247-277.Doi: 10.1080/00102209408935358
[41] R.J. Kee, A computational model of the structure and extinction of strained, opposed flow, premixed methane-air flames, Symp. Int. Combust. 22 (1) (1989) 1479-1494.Doi: 10.1016/S0082-0784(89)80158-4
[42] A.E. Lutz, R.J. Kee, J.F. Grcar, F.M. Rupley, OPPDIF: A Fortran program for computing opposed-flow diffusion flames, National Technical Information Service, (1997). https://www.researchgate.net/publication/239888329_OPPDIF_A_Fortran_program_for_computing_opposed-flow_diffusion_flames.
[43] P.X. Wang,,, Study on the effect of H₂O on the formation of CO in the counterflow diffusion flame of H₂/CO syngas in O₂/H₂O, Fuel 234 (2018) 516-525.Doi: 10.1016/j.fuel.2018.07.020
[44] V.V. Azatyan, Investigation of low-pressure flames of a number of compounds containing sulfur by the ESR method, Symp. Int. Combust. 12 (1) (1969) 989-994.Doi: 10.1016/S0082-0784(69)80477-7
[45] H. Selim, A. Al Shoaibi, A.K. Gupta, Experimental examination of flame chemistry in hydrogen sulfide-based flames, Appl. Energy 88 (8) (2011) 2601-2611.Doi: 10.1016/j.apenergy.2011.02.029
[46] C. Zhou, Experimental and kinetic modelling study of H₂S oxidation, Proc. Combust. Inst. 34 (1) (2013) 625-632.Doi: 10.1016/j.proci.2012.05.083
[47] K. Sendt, Chemical kinetic modeling of the H/S system: H₂S thermolysis and H₂ sulfidation, Proc. Combust. Inst. 29 (2) (2002) 2439-2446.Doi: 10.1016/S1540-7489(02)80297-8
[48] T.Y. Cong,,, A detailed reaction mechanism for hydrogen production via hydrogen sulphide (H₂S) thermolysis and oxidation, Int. J. Hydrog. Energy 41 (16) (2016) 6662-6675.Doi: 10.1016/j.ijhydene.2016.03.053
[49] C. Wang, G. Zhang, Z. Wang, Q.S. Li, Y. Zhang, Direct ab initio dynamics study of the hydrogen abstraction reaction: H₂S+O→HS+OH, J. Mol. Struct. THEOCHEM 731 (1-3) (2005) 187-192.Doi: 10.1016/j.theochem.2005.02.075
[50] A. Goumri, D. Laakso, J.D.R. Rocha, C.E. Smith, P. Marshall, Computational studies of the potential energy surface for O(3P)+H₂S: characterization of transition states and the enthalpy of formation of HSO and HOS, J. Chem. Phys. 102 (1) (1995) 161-169.Doi: 10.1063/1.469387
[51] B.A. Ellingson, D.G. Truhlar, Explanation of the unusual temperature dependence of the atmospherically important OH + H₂S → H₂O + HS reaction and prediction of the rate constant at combustion temperatures, J. Am. Chem. Soc. 129 (42) (2007) 12765-12771.Doi: 10.1021/ja072538b
[52] Y.F. Xing, Large eddy simulation of a turbulent non-premixed flame based on the flamelet-generated manifolds approach and a reduced mechanism verification, Aerosp. Sci. Technol. 105 (2020) 105952.Doi: 10.1016/j.ast.2020.105952
[53] M. Abián, CS₂ and COS conversion under different combustion conditions, Combust. Flame 162 (5) (2015) 2119-2127.Doi: 10.1016/j.combustflame.2015.01.010
[54] J. Berner-Cambot, C. Vovelle, R. Delbourgo, Flame structures of H₂S—air diffusion flames, Symp. Int. Combust. 18 (1) (1981) 777-783.Doi: 10.1016/s0082-0784(81)80081-1
[55] N.O. Guldal,,, New catalysts for hydrogen production from H₂S: Preliminary results, Int. J. Hydrog. Energy 40 (24) (2015) 7452-7458.Doi: 10.1016/j.ijhydene.2015.02.107
[56] S. Ibrahim, A. Al Shoaibi, A.K. Gupta, Toluene destruction in thermal stage of Claus reactor with oxygen enriched air, Appl. Energy 115 (2014) 1-8.Doi: 10.1016/j.apenergy.2013.10.060
[57] S. Ibrahim, R.K. Rahman, A. Raj, Effects of H₂O in the feed of sulfur recovery unit on sulfur production and aromatics emission from Claus furnace, Ind. Eng. Chem. Res. 56 (41) (2017) 11713-11725.Doi: 10.1021/acs.iecr.7b02553
[58] Y. Murakami, M. Kosugi, K.J. Susa, T. Kobayashi, N. Fujii, Kinetics and mechanism for the oxidation of CS₂ and COS at high temperature, Bull. Chem. Soc. Jpn. 74 (7) (2001) 1233-1240.Doi: 10.1246/bcsj.74.1233
[59] P. Glarborg, B. Halaburt, P. Marshall, A. Guillory, J. Troe, M. Thellefsen, K. Christensen, Oxidation of reduced sulfur species: carbon disulfide, J. Phys. Chem. A 118 (34) (2014) 6798-6809.https://pubmed.ncbi.nlm.nih.gov/25116264/
[60] Y. Li, X.L. Yu, H.J. Li, Q.H. Guo, Z.H. Dai, G.S. Yu, F.C. Wang, Detailed kinetic modeling of homogeneous H₂S-CH₄ oxidation under ultra-rich condition for H₂ production, Appl. Energy 208 (2017) 905-919.Doi: 10.1016/j.apenergy.2017.09.059

Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling

Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling

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