Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering

doi:10.1016/j.cjche.2022.11.011

中国化学工程学报 ›› 2023, Vol. 59 ›› Issue (7): 118-127.DOI: 10.1016/j.cjche.2022.11.011

• Full Length Article • 上一篇下一篇

Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering

Minjie Shi¹, Nianting Chen¹, Yue Zhao¹, Cheng Yang², Chao Yan¹

1. School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. China Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

收稿日期:2022-10-18 修回日期:2022-11-07 出版日期:2023-07-28 发布日期:2023-10-14
通讯作者: Chao Yan,E-mail:chaoyan@just.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (52002157 and 51873083) and the Natural Science Foundation of Jiangsu Province (BK20190976).

Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering

Minjie Shi¹, Nianting Chen¹, Yue Zhao¹, Cheng Yang², Chao Yan¹

1. School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. China Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Received:2022-10-18 Revised:2022-11-07 Online:2023-07-28 Published:2023-10-14
Contact: Chao Yan,E-mail:chaoyan@just.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (52002157 and 51873083) and the Natural Science Foundation of Jiangsu Province (BK20190976).

摘要/Abstract

摘要： Organic materials are of great interest in various applications owing to their intrinsic designability, molecular controllability, ease of synthesis, and ecological sustainability. In this work, a facile and mild wet-chemical strategy was carried out to construct a conjugated Ni-BTA coordination polymer via the π-d hybridization with 1,2,4,5-benzenetetramine (BTA) as π-conjugated ligands and Ni²⁺ as metallic centers, which exhibits a unique two-dimensional nanosheet-like structure with available active sites, sufficient electrochemical activity, and multi-electron redox capability. On the one hand, the as-prepared Ni-BTA coordination polymer as electrode material exhibits a rapid, reversible, and efficient energy storage behavior with a large reversible capacity of 198 mA·h·g^-1 at 1 A·g^-1 and a high-rate capability of 150 mA·h·g^-1 at 20 A·g^-1 in alkali-ion aqueous electrolyte, which are further demonstrated by the in-situ Raman investigation. On the other hand, the Ni-BTA coordination polymer as anti-corrosion additive was introduced into the epoxy resin to achieve a Ni-BTA epoxy coating, which shows a long-term anti-corrosion performance with a low corrosion rate of 4.62×10^-6 mm·a^-1 and a high corrosion inhibition efficiency of 99.86%, suggesting its great engineering potential as the bi-functional organic material for high-performance energy storage and corrosion protection.

关键词: Organic compounds, Nanostructure, Dual functionality, Energy storage, Corrosion protection

Abstract: Organic materials are of great interest in various applications owing to their intrinsic designability, molecular controllability, ease of synthesis, and ecological sustainability. In this work, a facile and mild wet-chemical strategy was carried out to construct a conjugated Ni-BTA coordination polymer via the π-d hybridization with 1,2,4,5-benzenetetramine (BTA) as π-conjugated ligands and Ni²⁺ as metallic centers, which exhibits a unique two-dimensional nanosheet-like structure with available active sites, sufficient electrochemical activity, and multi-electron redox capability. On the one hand, the as-prepared Ni-BTA coordination polymer as electrode material exhibits a rapid, reversible, and efficient energy storage behavior with a large reversible capacity of 198 mA·h·g^-1 at 1 A·g^-1 and a high-rate capability of 150 mA·h·g^-1 at 20 A·g^-1 in alkali-ion aqueous electrolyte, which are further demonstrated by the in-situ Raman investigation. On the other hand, the Ni-BTA coordination polymer as anti-corrosion additive was introduced into the epoxy resin to achieve a Ni-BTA epoxy coating, which shows a long-term anti-corrosion performance with a low corrosion rate of 4.62×10^-6 mm·a^-1 and a high corrosion inhibition efficiency of 99.86%, suggesting its great engineering potential as the bi-functional organic material for high-performance energy storage and corrosion protection.

Key words: Organic compounds, Nanostructure, Dual functionality, Energy storage, Corrosion protection

Minjie Shi, Nianting Chen, Yue Zhao, Cheng Yang, Chao Yan. Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering[J]. 中国化学工程学报, 2023, 59(7): 118-127.

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Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering

Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering

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