Dopant-free small molecule hole transport materials based on triphenylamine derivatives for perovskite solar cells

doi:10.1016/j.cjche.2022.07.027

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 29-42.DOI: 10.1016/j.cjche.2022.07.027

Dopant-free small molecule hole transport materials based on triphenylamine derivatives for perovskite solar cells

Sihan Li¹, Yuxuan Yang¹, Kuo Su¹, Bao Zhang^1,2,3, Yaqing Feng^1,2,3

1 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China;
3 Jieyang Center of Guangdong Laboratory of Chemistry and Fine Chemicals, Guangdong 515557, China

收稿日期:2022-03-17 修回日期:2022-07-24 出版日期:2022-10-28 发布日期:2023-01-04
通讯作者: Bao Zhang,E-mail:baozhang@tju.edu.cn;Yaqing Feng,E-mail:yafeng@tju.edu.cn
基金资助:
This work was supported by the Fundamental Research Funds for the Central Universities and the National Key Research and Development Program of China (2020YFB0408002).

Dopant-free small molecule hole transport materials based on triphenylamine derivatives for perovskite solar cells

Sihan Li¹, Yuxuan Yang¹, Kuo Su¹, Bao Zhang^1,2,3, Yaqing Feng^1,2,3

1 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China;
3 Jieyang Center of Guangdong Laboratory of Chemistry and Fine Chemicals, Guangdong 515557, China

Received:2022-03-17 Revised:2022-07-24 Online:2022-10-28 Published:2023-01-04
Contact: Bao Zhang,E-mail:baozhang@tju.edu.cn;Yaqing Feng,E-mail:yafeng@tju.edu.cn
Supported by:
This work was supported by the Fundamental Research Funds for the Central Universities and the National Key Research and Development Program of China (2020YFB0408002).

摘要/Abstract

摘要： In the past decade, perovskite solar cells have become a promising candidate in the photovoltaic industry owing to their high power conversion efficiency that surpasses 25%. However, there are certain limitations that have hindered the development and full-scale practical application of these cells, including the high cost and degradation of perovskite caused by the dopants. Hence, there is an urgent need to develop dopant-free hole transport materials (HTMs). In recent years, HTMs based on triphenylamine (TPA-HTMs) are receiving growing interest owing to their high hole mobility, excellent film formation, and suitable energy levels. The literature here covers work relevant to TPA-HTMs in the last five years. They have been classified according to different core types. The correlations between performance and structure are summarized, and the future development trend of TPA-HTMs is highlighted.

关键词: Solar energy, Electronic materials, Organic compounds, Triphenylamine, Hole transport materials

Abstract: In the past decade, perovskite solar cells have become a promising candidate in the photovoltaic industry owing to their high power conversion efficiency that surpasses 25%. However, there are certain limitations that have hindered the development and full-scale practical application of these cells, including the high cost and degradation of perovskite caused by the dopants. Hence, there is an urgent need to develop dopant-free hole transport materials (HTMs). In recent years, HTMs based on triphenylamine (TPA-HTMs) are receiving growing interest owing to their high hole mobility, excellent film formation, and suitable energy levels. The literature here covers work relevant to TPA-HTMs in the last five years. They have been classified according to different core types. The correlations between performance and structure are summarized, and the future development trend of TPA-HTMs is highlighted.

Key words: Solar energy, Electronic materials, Organic compounds, Triphenylamine, Hole transport materials

Sihan Li, Yuxuan Yang, Kuo Su, Bao Zhang, Yaqing Feng. Dopant-free small molecule hole transport materials based on triphenylamine derivatives for perovskite solar cells[J]. 中国化学工程学报, 2022, 50(10): 29-42.

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Dopant-free small molecule hole transport materials based on triphenylamine derivatives for perovskite solar cells

Dopant-free small molecule hole transport materials based on triphenylamine derivatives for perovskite solar cells

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