Amine-functionalized mesoporous UiO-66 aerogel for CO2 adsorption

doi:10.1016/j.cjche.2021.10.010

中国化学工程学报 ›› 2023, Vol. 54 ›› Issue (2): 36-43.DOI: 10.1016/j.cjche.2021.10.010

• Full Length Article • 上一篇下一篇

Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption

Mengge Shang¹, Jing Zhang¹, Jinqiang Sun¹, Shimo Yu¹, Feng Hua¹, Xiaoxu Xuan², Xun Sun², Serguei Filatov³, Xibin Yi¹

1. Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China;
2. Key Laboratory of High Efficiency and Clean Mechanical Manufacture, Ministry of Education, National Demonstration Center for Experimental Mechanical Engineering Education at Shandong University, School of Mechanical Engineering, Shandong University, Jinan 250061, China;
3. Laboratory of Hydrogen Energy, Institute of Heat and Mass Transfer of the National Academy of Sciences of Belarus, Minsk 220072, Belarus

收稿日期:2021-07-18 修回日期:2021-10-26 出版日期:2023-02-28 发布日期:2023-05-11
通讯作者: Jing Zhang,E-mail:zhangjing@sdas.org;Xibin Yi,E-mail:yixb@sdas.org
基金资助:
This work is supported by the National Natural Science Foundation of China (21603125), Science-Education-Industry Integration Innovation Pilot Project of Qilu University of Technology (2020KJC-GH13), International Cooperation Project of Shandong Academy of Sciences (2019GHPY09), Natural Science Foundation of Shandong Province (ZR2019BEM025), Young doctor Cooperation Foundation of Qilu University of Technology (Shandong Academy of Sciences) (2019BSHZ0016).

Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption

Mengge Shang¹, Jing Zhang¹, Jinqiang Sun¹, Shimo Yu¹, Feng Hua¹, Xiaoxu Xuan², Xun Sun², Serguei Filatov³, Xibin Yi¹

1. Shandong Key Laboratory for Special Silicon-containing Material, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China;
2. Key Laboratory of High Efficiency and Clean Mechanical Manufacture, Ministry of Education, National Demonstration Center for Experimental Mechanical Engineering Education at Shandong University, School of Mechanical Engineering, Shandong University, Jinan 250061, China;
3. Laboratory of Hydrogen Energy, Institute of Heat and Mass Transfer of the National Academy of Sciences of Belarus, Minsk 220072, Belarus

Received:2021-07-18 Revised:2021-10-26 Online:2023-02-28 Published:2023-05-11
Contact: Jing Zhang,E-mail:zhangjing@sdas.org;Xibin Yi,E-mail:yixb@sdas.org
Supported by:
This work is supported by the National Natural Science Foundation of China (21603125), Science-Education-Industry Integration Innovation Pilot Project of Qilu University of Technology (2020KJC-GH13), International Cooperation Project of Shandong Academy of Sciences (2019GHPY09), Natural Science Foundation of Shandong Province (ZR2019BEM025), Young doctor Cooperation Foundation of Qilu University of Technology (Shandong Academy of Sciences) (2019BSHZ0016).

摘要/Abstract

摘要： A mesoporous UiO-66-NH₂ aerogel is prepared via a straightforward sol–gel method without using any binders or mechanical pressures, in which the amine groups are directly introduced into the matrix by using 2-aminoterephthalic acid. The novel UiO-66-NH₂ aerogel also exhibits high specific surface area and mesopore-dominated structure, implying its highly potential use in CO₂ adsorption. For ulteriorly investigating the effect of amine loading on the CO₂ adsorption ability, a series of UiO-66-NH₂ aerogel with different amino content is fabricated by changing the ligand/metal molar ratio. When the molar ratio is 1.45, the CO₂ adsorption capacity reaches the optimum value of 2.13 mmol·g^-1 at 25 ℃ and 0.1 MPa, which is 12.2% higher than that of pure UiO-66 aerogel. Additionally, UiO-66-NH₂-1.45 aerogel also has noticeable CO₂ selectivity against N₂ and CH₄ as well as good regeneration stability. Such results imply that it has good application prospect in the field of CO₂ adsorption, and also contains the potential to be applied in catalysis, separation and other fields.

关键词: UiO-66-NH₂ aerogel, Sol–gel method, Amine groups, Nanostructure, Carbon dioxide, Adsorption

Abstract: A mesoporous UiO-66-NH₂ aerogel is prepared via a straightforward sol–gel method without using any binders or mechanical pressures, in which the amine groups are directly introduced into the matrix by using 2-aminoterephthalic acid. The novel UiO-66-NH₂ aerogel also exhibits high specific surface area and mesopore-dominated structure, implying its highly potential use in CO₂ adsorption. For ulteriorly investigating the effect of amine loading on the CO₂ adsorption ability, a series of UiO-66-NH₂ aerogel with different amino content is fabricated by changing the ligand/metal molar ratio. When the molar ratio is 1.45, the CO₂ adsorption capacity reaches the optimum value of 2.13 mmol·g^-1 at 25 ℃ and 0.1 MPa, which is 12.2% higher than that of pure UiO-66 aerogel. Additionally, UiO-66-NH₂-1.45 aerogel also has noticeable CO₂ selectivity against N₂ and CH₄ as well as good regeneration stability. Such results imply that it has good application prospect in the field of CO₂ adsorption, and also contains the potential to be applied in catalysis, separation and other fields.

Key words: UiO-66-NH₂ aerogel, Sol–gel method, Amine groups, Nanostructure, Carbon dioxide, Adsorption

Mengge Shang, Jing Zhang, Jinqiang Sun, Shimo Yu, Feng Hua, Xiaoxu Xuan, Xun Sun, Serguei Filatov, Xibin Yi. Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption[J]. 中国化学工程学报, 2023, 54(2): 36-43.

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Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption

Amine-functionalized mesoporous UiO-66 aerogel for CO₂ adsorption

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